Intramolecular reactivity of trans [4+4] photodimers of 2-pyridones

Synthesis

Volumn , Issue 15, 2007, Pages 2351-2359

  Chen, Peiling ^a   Carroll, Patrick J ^b   Sieburth, Scott McN ^a  

^a Temple University   (United States)

^b UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

Cycloadditions; Dimerizations; Ketones; Photochemistry; Pyridines

Indexed keywords

AZETIDINIUM ION; LACTAM BRIDGES; NUCLEOPHILIC ATTACK; PHOTODIMERS;

ALKYLATION; CRYSTAL STRUCTURE; HALOGENATION; ISOMERS; PHOTOCHEMICAL REACTIONS;

DIMERS;

2 PYRIDONE DERIVATIVE; ALKADIENE; AMIDE; CYCLOOCTA 1,5 DIENE; DIAMIDE; DIMER; HALIDE; ION; LACTAM; NITROGEN; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; BROMINATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHLORINATION; CYCLOADDITION; DEALKYLATION; DIMERIZATION; HALOGENATION; NUCLEAR MAGNETIC RESONANCE; PHOTOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 34547756366     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-983793     Document Type: Article

References (15)

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10. See ref. 6
11. 2 = 0.1980.
12. This structure was calculated by initially building a structure with a carbon atom in place of the positively charged nitrogen, and minimizing the structure using molecular mechanics. The resulting structure was then modified by replacing the carbon with a positively charged nitrogen and minimizing the structure using PM3 (MOPAC). The calculation was performed using WebMO (www.webmo.net). Images were generated with PyMOL (pymol.sourceforge.net).
13. 2 = 0.0794.
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