Intramolecular rearrangement of 1,3-bistriflate ester of thiacalix[4]arene to 1,2-counterpart: an efficient di-O-protection method for the stereoselective synthesis of anti-1,2-diethers

Tetrahedron Letters

Volumn 48, Issue 36, 2007, Pages 6281-6285

  Serizawa, Ryuichi ^a   Tanaka, Shinya ^a   Morohashi, Naoya ^a   Narumi, Fumitaka ^b   Hattori, Tetsutaro ^a  

^a TOHOKU UNIVERSITY   (Japan)

^b ISHINOMAKI SENSHU UNIVERSITY   (Japan)

Author keywords

anti Selective 1,2 dialkylation; Intramolecular ester exchange; Thiacalix 4 arene

Indexed keywords

1,2 DIETHER DERIVATIVE; 1,3 BISTRIFLATE ESTER; CALIXARENE; ESTER DERIVATIVE; ETHER DERIVATIVE; HALIDE; HYDROXYL GROUP; MOLECULAR SCAFFOLD; OXYGEN; THIACALIX[4]ARENE; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; INTRAMOLECULAR REARRANGEMENT; MITSUNOBU REACTION; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS; TECHNIQUE;

EID: 34547687993     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.07.025     Document Type: Article

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