New Raman method for aqueous solutions: ξ-function dispersion evidence for strong F --water H-bonds in aqueous CsF and KF solutions

Journal of Chemical Physics

Volumn 123, Issue 7, 2005, Pages

  Walrafen, George E ^a  

^a UNIVERSITY OF KANSAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLUORIDE IONS; STOICHIOMETRIC MOL FRACTION; THE RAMAN Ξ-FUNCTION DISPERSION METHOD;

CORRELATION METHODS; ELECTROLYTES; GIBBS FREE ENERGY; HYDROGEN BONDS; WATER;

DISPERSIONS;

EID: 34547648060     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1992472     Document Type: Article

References (29)

1. D. E. Hare and C. M. Sorensen, J. Chem. Phys. 93, 6954 (1990).
2. G. E. Walrafen, J. Chem. Phys. 120, 4868 (2004).
3. G. E. Walrafen, J. Chem. Phys. 121, 2727 (2004).
4. G. E. Walrafen, J. Chem. Phys. 122, 094510 (2005).
5. A. V. Iogansen and M. Sh. Rozenberg, Opt. Spektrosk. 44, 49 (1978).
6. E.U. Franck and H. Lindner, doctoral dissertation of the latter, University of Karlsruhe, 1970.
7. W. B. Monosmith and G. E. Walrafen, J. Chem. Phys. 81, 669 (1984).
8. J. D. Worley and I. M. Klotz, J. Chem. Phys. 45, 2868 (1966).
9. G. E. Walrafen, J. Chem. Phys. 48, 244 (1968).
10. G. E. Walrafen, M. R. Fisher, M. S. Hokmabadi, and W.-H. Yang, J. Chem. Phys. 85, 6970 (1986).
11. I. Beta (private communication); Beta has used data from Ref. 10 above plus a ΔH of 2.4 kcal/mol H-bond to obtain 1% agreement between the heat capacity calculated from Raman data and the measured value.
12. A. Tokmakoff (private communication).
13. S. Woutersen and H. J. Bakker, Nature (London) 401, 507 (1999).
14. A. Seidell, Solubilities of Inorganic and Metal Organic Compounds (Van Nostrand, New York, 1940);
15. N.A. Lange, Handbook of Chemistry, 10th ed. (McGraw Hill, New York, 1966);
16. CRC Handbook of Physics and Chemistry, edited by, R. C. Weast, (CRC, Boca Raton, FL, 1986).
17. G. E. Walrafen, J. Chem. Phys. 55, 768 (1971).
18. G. E. Walrafen, J. Chem. Phys. 52, 4176 (1970).
19. G. E. Walrafen and E. Pugh, J. Solution Chem. 33, 81 (2004).
20. W.A. P. Luck, Habilitationsschrift, Spektrokopische Bestimmungen der Wasserstoff-brückenbindungen in Nahen IR (University of Heidelberg, Heidelberg 1968).
21. J. M. Heuft and E. M. Meijer, J. Chem. Phys. 122, 094501 (2005).
22. O. M. Cabarcos, C. J. Weinheimer, J. M. Lisy, and S. S. Xantheas, J. Chem. Phys. 110, 5 (1999).
23. J.M. Lisy (private communication).
24. Y. Hu, Y. Lu, S. Veeramasuneni, and J. D. Miller, J. Colloid Interface Sci. 190, 224 (1997).
25. A. Preisinger, M. Zottl, K. Mereiter, W. Mikend, S. Steinböck, P. Dufek, K. Schwarz, and P. Blaha, Inorg. Chem. 33, 4774 (1994).
26. G. Chiari and G. Ferraris, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B34, 355 (1978).
27. W.F. Kuhs and M.S. Lehmann, in Water and Aqueous Solutions, edited by, G. W. Neilson, and, J. E. Enderby, (Adam Hilger, Bristol, UK, 1986).
28. W. R. Busing and D. F. Hornig, J. Phys. Chem. 65, 284 (1961);
29. J. W. Schultz and D. F. Hornig, J. Phys. Chem. 65, 2131 (1961).