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Volumn , Issue 12, 2007, Pages 1957-1959

A formal stereoselective synthesis of (-)-maurenone

Author keywords

Desymmetrization; Polyketide; Sharpless asymmetric epoxidation

Indexed keywords

EPOXIDE; MAURENONE; NATURAL PRODUCT; UNCLASSIFIED DRUG;

EID: 34547637454     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-984497     Document Type: Article
Times cited : (10)

References (18)
  • 18
    • 34547623698 scopus 로고    scopus 로고
    • The spectral and physical data of aldehyde 3 and ketone 4 matched in all respects with reported data (ref. 6, Selected Physical Data Compound 3: clear oil; Rf, 0.43 (Et2O-hexane, 10:90, α]D20 +51.6 (c 1.0 CHCl3, 6 Compound 4: colorless oil; Rf, 0.50 (EtOAc-hexane, 10:90, α]D20 +30.5 (c 1.0 CHCl 3).6 Compound 5: colorless oil; Rf, 0.40 (EtOAc-hexane, 10:90, α]D20 +19.4 (c 1.0 CHCl3, 1H NMR (300 MHz, CDCl3, δ, 3.65 (dd, 1 H, J, 12.0, 4.5 Hz, 3.53 (dd, 1 H, J, 12.0, 8.3 Hz, 2.95 (t, 1 H, J, 6.0 Hz, 1.95 (dd, 1 H, J, 8.3, 5.3 Hz, 1.55 (m, 2 H, 1.29 (s, 3 H, 1.05 (t, 3 H, J, 7.5 Hz, 13C NMR 75 MHz, CDCl3, δ, 65.6, 61.4, 61.1, 21.4, 13.9, 10.3. LC-MS
    • +]: 285.1820; found: 285.1823.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.