Agitation effects in a gas-liquid-liquid reactor system: Methyl ethyl ketazine production

International Journal of Chemical Reactor Engineering

Volumn 5, Issue , 2007, Pages

  Kaur, Raminder ^a   Machiraju, Ramakrishna ^a   Nigam, K D P ^b  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

^b INDIAN INSTITUTE OF TECHNOLOGY DELHI   (India)

Author keywords

Agitation; Gas liquid liquid system; Methyl ethyl ketazine

Indexed keywords

AROMATIC COMPOUNDS; CHEMICAL REACTORS; DIFFUSION;

AGITATION; DIFFUSION CONTROL; GAS-LIQUID-LIQUID SYSTEM; METHYL ETHYL KETAZINE;

REACTION KINETICS;

EID: 34547508641     PISSN: 21945748     EISSN: 15426580     Source Type: Journal    
DOI: 10.2202/1542-6580.1401     Document Type: Article

References (46)

1. Beenackers, A.A.C.M. and W.P.M. van Swaaij, "Mass transfer in gas-liquid slurry reactors: a critical review", Chem. Eng. Sci. (1993), 48(18), 3109-3139.
2. Brilman, D. W. F., "Mass transfer and chemical reaction in gas-liquid-liquid systems", Thesis, University of Twente, (1998), The Netherlands.
3. Brilman, D. W. F., Goldschmidt M. J. V., Versteeg G. F. and van Swaaij W. P. M, "Heterogeneous mass transfer models for gas absorption in multiphase systems", Chem. Eng. Sci., (2000), 55(15), 2793-2812.
4. Bruining, W. J., Joosten G. E. H., Beenackers A. A. C. M.and Hofman H., "Enhancement of gas-liquid mass transfer by a dispersed second liquid phase", Chem. Eng. Sci.,(1986), 41(7), 1873-1877.
5. Carpenter,K.J., "Fluid processing in agitated vessel" Chem. Engg. Res. Des., (1986),64(1), 3-10.
6. Cents, A. H. G., Brilman D. W. F. and Versteeg G. F., "Gas absorption in an agitated gas-liquid-liquid system", Chem. Eng. Sci., (2001),56(3),1075-1083.
7. Chaudhari R.V., Bhattacharya A. and Bhanage B.M.,"Catalysis with soluble complexes in gas-liquid-liquid systems", Catalysis Today, (1995), 24(1-2), 123-133.
8. Cooper C.M., Fernstrom G.A. and Miller S.A.,"Performance of agitated gas- liquid contractors" Ind. Eng. Chem. Des. Develop.,(1944),36(6), 504-509.
9. Cornil, B, "Bulk and fine chemicals via aqueous biphasic catalysis", Journal of Molecular Catalysis A: Chemical, (1999),143(1-3), 1-10.
10. Eichenhofer, K. W. and Schliebs R., "Production of ketazines" US Pat 3965097,(Jun 22, 1976).
11. Eichenhofer, K. W. and Schliebs R., " Working up synthesis solution obtained in the production of hydrazine" US Pat 4005179, (Jan 25, 1977).
12. Falbe J., 'New synthesis with carbon monoxide; Ch. V.: Koch Reactions (H. Bahrmann)' (1980), Springer-Verlag, Berlin.
13. Herrmann W.A. and Kohlpaintner C.W., "Water soluble ligands, metal complexes and catalysts: synergism of homogeneous and heterogeneous catalysis", Angew. Chem. (Int.Ed.Engl), (1993), 32, 1524-1544.
14. Holstvoogd R. D., van Swaaij W. P. M. and van Dierendonck L. L., "The absorption of gases in aqueous activated carbon slurries enhanced by adsorbing or catalytic particles" Chem. Eng. Sci., (1988), 43(8), 2181-2187.
15. Ikuhisa K., Minora T. and Shiyouichi N.," Preparation of ketazine" JP58010547 (Jan 21, 1983).
16. Karve S. and Juvekar V.A., "Gas absorption into slurries containing fine catalyst particles", Chem. Eng. Sci.,(1990), 45(3), 587-594.
17. Kaur, R., M. Ramakrishna and K.D.P. Nigam, "Kinetics studies of ketazine formation; Effect of temperature and catalyst concentration", The Can J. Chem. Engg., (Communicated).
18. Kaur, R., M. Ramakrishna and K.D.P. Nigam, "Effect of gas flow rates in gas-liquid-liquid reactors: A case study of effect of ammonia flow rate on ketazine formation" CITICOMS 2007, The International Conference on Modeling and Simulation to be held at Coimbatore from 27th to 29th August, 2007 (accepted).
19. Kazuhiko H., Nobuyuki N., Riyouji I., Tatsu T. and Yuuichi K.,"Continuous manufacture of hydrazine", JP58120507, (Jul 18, 1983).
20. Kirk, R. E. and Othmer D.E., "Hydrazine and its derivatives", Encyclopedia of chemical technology, 13, 5th edition, (2004), Mc-Graw Hill, New York, 562-607.
21. Littel, R. J., Versteeg G. F. and van Swaaij W. P. M., "Physical absorption of CO2 and propene into toluene/water emulsions", A.I.Ch.E. J., (1994),40(10),1629-1638.
22. Marrucci, G. and L. Nicodemo,"Coalescence of gas bubbles in aqueous solutions of inorganic electrolytes", Chem. Engg. Sci., (1967), 22(9),1257-1265.
23. Mehra, A.,"Intensification of multiphase reactions through the use of a microphase - I. Theoretical", Chem. Eng. Sci.,(1988), 43(4), 899-912.
24. Miller, F.D. and Rushton J.H., "A mass velocity theory for liquid agitation" Ind. Eng. Chem. Des. Develop.,(1944), 36(6), 499-503.
25. Nagata S., "Mixing : Principles and applications" John Wiley and Sons, (1975), 372.
26. Nagy, E., and Moser A.,"Three-phase mass transfer: improved pseudo-homogeneous model", A.I.Ch.E. J. (1995), 41(1), 23-34.
27. Nienow, A.W., M. Konno and W. Bujalski, "Studies on three phase mixing :a review and recent results", Chem. Engg. Res. Des., (1986), 64(1), 35-42.
28. Parker, N.H., "Mixing" Chem Eng., (1964),71(12), 165-216.
29. Poncin, S, C. Nguyen, N. Midoux and J. Breysse, "Hydrodynamics and volumetric gas-liquid mass transfer coefficient of a stirred vessel equipped with a gas-inducing impeller"Chem. Engg. Sci., (2002), 57(16), 3299-3306.
30. Quillen, C.S.,"Mixing : the universal operation" Chem. Engg.,(1964),61(6), 177-218.
31. Rols, J. L., Condoret J. S., Fonade C. and Goma G., "Mechanism of enhanced oxygen transfer in fermentation using emulsified oxygen-vectors", Biotechnol. Bioeng., (1990), 35(4), 427-435.
32. Schirmann J.P., Combroux J. and Delavarenne S. Y., "Method for preparing azines and hydrazones " US Pat 3972878, (Aug 3,1976).
33. Schirmann J.P, Combroux J. and Delavarenne, S. Y., "Preparation of concentrated aqueous solution of hydrazine hydrate", US. Pat 4724133, (Feb 9, 1988).
34. Schirmann J.P., "Method of preparing hydrazine hydrate", US. Pat. 6482383 (Nov 19, 2002).
35. Schirmann J.P., "Method of preparing hydrazine hydrate", US Pat 6517798, (Feb 11, 2003).
36. Tsukasa M. and Hidetoshi K., "Preparation of ketazines". JP54066612, (May 29,1979).
37. Van Ede, C. J., van Houten R. and Beenackers A. A. C. M., "Enhancement of gas to water mass transfer rates by a dispersed organic phase", Chem. Eng. Sci., (1995),50(18), 2911-2922.
38. Wang, M.L. and Tseng Y.H, "Phase-transfer catalytic reaction of dibromo-o-xylene and 1-butanol in two-phase solution",Journal of Molecular Catalysis A: Chemical, (2002), 179(1-2), 17-26.
39. Warmeoskerken M.M.C.G., J. Speur and J.M. Smith., "Gas-Liquid Dispersion With Pitched Blade Turbines." Chem. Engg Commun., (1984), 25(1-6), 11-29.
40. Westerterp, K. R., L.L. Van Dierendonck and J.A.De Kraa, "Interfacial area in agitated gas liquid contactors", Chem. Engg. Sci., (1963), 18(3), 157-158.
41. Xu B. A., D. E. Giles and I. M. Ritchie, "Reactions of lime with carbonate-containing solutions" , Hydrometallurgy, (1998),48(2), 205-224.
42. Yasuhisa K., Nobuhiro N. and Kiyoshi Y., "Synthetic process of ketazine and synthetic process of hydrazine hydrate"EP0758642, (Feb19, 1997).
43. Yasuhisa K., Minora K. and Shoichi N.,"Process of preparing a ketazine from a ketone", EP0070155, (Jan 19, 1983).
44. Yoshida, F., Yamane T. and Y. Miyamoto, "Oxygen absorption into oil-in-water emulsions. A study on hydrocarbon fermentors", Ind. Eng. Chem. Des. Develop., (1970),9(4), 570-577.
45. Zhang G.D., Cai W.F., Xu C. J. and Zhou M., "A general enhancement factor model of the physical absorption of gases in multiphase systems", Chem. Eng. Sci., (2006),61(2), 558-568.
46. Zhao, S., D. Lu, and Min R.," Method for preparation of azine", CN1068107,(Jan 20, 1993).