Thermodynamic aspects of hydrodesulfurization and hydrodenitrogenation

Petroleum Science and Technology

Volumn 25, Issue 7, 2007, Pages 841-852

  Ali, S A ^a  

^a KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS   (Saudi Arabia)

Author keywords

Hydrodenitrogenation; Hydrodesulfurization; Hydrotreating reactions; Reaction equilibria; Reaction thermodynamics

Indexed keywords

NITROGEN COMPOUNDS; REACTION KINETICS; THERMODYNAMICS;

HYDRODENITROGENATION; HYDROTREATING REACTIONS; REACTION EQUILIBRIA; REACTION THERMODYNAMICS;

HYDRODESULFURIZATION;

EID: 34547494346     PISSN: 10916466     EISSN: 15322459     Source Type: Journal    
DOI: 10.1080/10916460500526973     Document Type: Article

References (28)

1. Ali, S. A. (1997). Reaction kinetics and thermodynamics of hydrogenation of petroleum light and middle distillates. Ph.D. thesis, Hokkaido University, Sapporo, Japan.
2. Ali, S. A. (2007). Thermodynamic aspects of aromatic hydrogenation, petroleum science and technology. Petroleum Science and Technology, in press.
3. Ali, S. A., and Anabtawi, J. A. (1995). Olefins can limit desulfurization of reformer feedstock. Oil and Gas Journal, July:48-54.
4. Anabtawi, J. A., Alam, K., Ali, M. A., Ali, S. A., and Siddiqui, M. A. B. (1995). Performance evaluation of HDS catalysts by distribution of sulfur compounds in naphtha. Fuel 74:1254.
5. Benson, S. W., Cruikshank, F. R., Golden, D. M., Haughen, G. R., O'Neal, H. E., Rodgers, A. S., Shaw, R., and Walsh, R. (1969). Additivity rules for the estimation of thermochemical properties. Chem. Rev. 69:279-324.
6. Bhinde, M. V. (1979). Quinoline hydrodenitrogenation kinetics and reduction inhibition. Ph.D. dissertation, University of Delaware, Newark, DE.
7. Cocchetto, J., and Satterfield, C. N. (1976). Thermodynamic equilibria of selected heterocyclic nitrogen compounds with their hydrogenated products. Ind. Eng. Chem. Pro. Des. Dev. 15:272.
8. Cocchetto, J. F., and Satterfield, C. N. (1981). Chemical equilibria among quinoline and its reaction products in hydrodenitrogenation. Ind. Engg. Chem. Pro. Des. Dev. 20:49-53.
9. Gates, B. C., Katzer, J. R., and Schuit, G. C. A. (1979). Chemistry of Catalytic Processes. New York: McGraw Hill.
10. Girgis, M. J., and Gates, B. C. (1991). Reactivities, reaction networks, and kinetics in high-pressure catalytic hydroprocessing. Ind. Engg. Chem. Res. 30:2021-2058.
11. Givens, E. N., and Venuto, P. B. (1970). Hydrogenolysis of benzo[b]thiophenes and related. Preprint Am. Chem. Soc., Div. Pet. Chem. 15:A183-A195.
12. Hanlon, R. J. (1989). Effects of PH2S, PH2, and PH2S/PH2 on the hydro-denitrogenation of pyridine. Energy and Fuels 1:424-430.
13. Ho, T. C. (1988). Catalysis reviews. Hydrodenitrogenation catalysis. Science and Engineering 30:117-160.
14. Joback, K. G. (1984). A unified approach to physical property estimation using multivariate statistical techniques. Sc.D. thesis, MIT, Cambridge, MA.
15. Mounce, E., and Rubin, R. S. (1971). Chem. Engg. Prog. 87:81.
16. Ried, R. C., Prausnitz, J. M., and Poling, B. M. (1987). The Properties of Gases and Liquids. New York: McGraw Hill.
17. Satterfield, C. N., Modell, M., Hites, R. A., and Declerck, C. J. (1978). Intermediate reactions in catalytic hydrodenitrogenation of quinoline. Ind. Engg. Chem. Proc. Des. Dev. 17:142-149.
18. Satterfield, C. N., and Cocchetto, J. F. (1975). Interactions between catalytic hydrodesulfurization of thiophene and hydrodenitrogenation of pyridine. AIChE Journal 21:107-115.
19. Satterfield, C. N., and Cocchetto, J. F. (1981). Reaction network and kinetics of the vapor-phase catalytic hydrodenitrogenation of quinoline. Ind. Eng. Chem. Prod. Des. Dev. 20:53-62.
20. Smith, H. A., and Emmet, P. H. (Ed.). (1957). Catalysis 5:231. New York: Reinhold.
21. Sonnemans, J., Goudrian, F., and Mars, P. (1972). Pyridine on molybdenum oxide containing catalysts. Fifth Intl. Congress Catalysis, Palm Beach, FL, Paper 76.
22. Speight, J. G. (1981). The Desulfurization of Heavy Oil and Residua. New York: Marcel Dekker.
23. Stein, S. F., Golden, D. M., and Benson, S. W. (1977). Predictive schemes for thermochemical properties of poly cyclic aromatic hydrocarbons. J. Phys. Chem. 81:314-317.
24. Streitwiser, A., and Heathcock, C. (1976). Introduction to Organic Chemistry. New York: McMillan.
25. van Krevelen, D. W., and Chermin, H. A. G. (1951). Estimation of the free enthalpy (Gibbs free energy), of formation of organic compounds from group contributions. Chem. Engg. Sci. 1:66-80.
26. Vrinat, M. L. (1983). The kinetics of the hydrodesulfurization process - A review. Applied Catalysis 6:137.
27. Wiser, W H., Singh, S., Qader, S. A., and Hill, G. R. (1970). Catalytic hydrogenation of multiring aromatic coal tar constituents. Ind. Engg. Chem. Prod. Res. Dev. 9:350-357.
28. Yoneda, Y (1979). An estimation of the thermodynamic properties of organic compounds in the ideal gas state. I. Acyclic compounds and cyclic compounds with a ring of cyclopentane, cyclohexane, benzene, or naphthalene. Bull. Chem. Soc. Japan 52:1297-1314.