Infrared microspectroscopic study of the thermo-oxidative degradation of hydroxy-terminated polybutadiene/isophorone diisocyanate polyurethane rubber

Polymer Degradation and Stability

Volumn 92, Issue 8, 2007, Pages 1446-1454

  Nagle, Dylan J ^a   Celina, Mathew ^b   Rintoul, Llewellyn ^a   Fredericks, Peter M ^a  

^a QUEENSLAND UNIVERSITY OF TECHNOLOGY   (Australia)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

Butadiene; FTIR; Microspectroscopy; Oxidation; Polyurethane

Indexed keywords

ALCOHOLS; DEGRADATION; ESTERS; INFRARED SPECTROSCOPY; ISOMERS; POLYURETHANES; THERMOOXIDATION;

MICROSPECTROSCOPIC STUDY; MICROTOMED SAMPLES;

RUBBER;

EID: 34547484927     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2007.05.010     Document Type: Article

References (45)

1. Wright P., and Cumming A.P.C. Solid polyurethane elastomers (1969), Maclaren and Sons Ltd, London, UK
2. Szycher M. Szycher's handbook of polyurethanes (1999), CRC Press, FL, USA
3. Hepburn C. Polyurethane elastomers (1982), Elsevier Science Publishing Co., NY, USA
4. Burel F., Feldman A., and Bunel C. Hydrogenated hydroxy-functionalized polyisoprene (H-HTPI) and isocyanurate of isophorone diisocyanates (I-IPDI): reaction kinetics study using FTIR spectroscopy. Polymer 46 (2005) 15
5. Dannoux A., Esnouf S., Begue J., Amekraz B., and Moulin C. Degradation kinetics of poly(ether-urethane) Estane™ induced by electron irradiation. Nucl Instrum Methods B 236 (2005) 488
6. Ri Zhang D., Wha Oh S., Pyo Hong Y., and Kang Y.S. Synthesis and characterization of a new adhesion-activator for polymer surface. Int J Adhes Adhes 25 (2005) 371
7. Chen Y., Zhou S., Yang H., Gu G., and Wu L. Preparation and characterization of nanocomposite polyurethane. J Colloid Interface Sci 279 (2004) 370
8. Sari B., Talu M., Yildirim F., and Balci E.K. Synthesis and characterization of polyurethane/polythiophene conducting copolymer by electrochemical method. Appl Surf Sci 205 (2003) 27
9. Subramanian K. Hydroxyl-terminated poly (azidomethyl ethylene oxide-b-butadiene-b-azidomethyl ethylene oxide)-synthesis, characterization and its potential as a propellant binder. Eur Polym J 35 (1999) 1403
10. Huang S.-L., Chao M.-S., Ruaan R.-C., and Lai J.-Y. Microphase separated structure and protein adsorption of polyurethanes with butadiene soft segment. Eur Polym J 36 (2000) 285
11. Myer Y.P., Chen Z.J., and Frisch H.L. Resonance Raman spectroscopic study of an iodine-doped pseudo-interpenetrating polymer network of natural rubber-poly(carbonate urethane). Polymer 38 (1997) 729
12. Edwards H.G.M., and Farwell D.W. Fourier transform-Raman spectroscopy of amber. Spectrochim Acta Part A 52 (1996) 1119
13. Hatchett D.W., Kodippili G., Kinyanjui J.M., Benincasa F., and Sapochak L. FTIR analysis of thermally processed PU foam. Polym Degrad Stab 87 (2005) 555
14. van der Ven L.G.J., Leuverink R., Henderiks H., and van Overbeek R. Durability prediction of p-urethane clearcoats. Prog Org Coat 48 (2003) 214
15. Lattimer R.P., and Williams R.C. Low-temperature pyrolysis products from a polyether-based urethane. J Anal Appl Pyrol 63 (2002) 85
16. Wilhelm C., and Gardette J.-L. Infrared analysis of the photochemical behaviour of segmented polyurethanes: 1. Aliphatic poly(ester-urethane). Polymer 38 (1997) 4019
17. Wilhelm C., and Gardette J.-L. Infrared analysis of the photochemical behaviour of segmented polyurethanes: aliphatic poly(ether-urethane)s. Polymer 39 (1998) 5973
18. Wilhelm C., Rivaton A., and Gardette J.-L. Infrared analysis of the photochemical behaviour of segmented polyurethanes: 3. Aromatic diisocyanate based polymers. Polymer 39 (1998) 1223
19. Allen N.S., Barcelona A., Edge M., Wilkinson A., Merchan C.G., and Ruiz Santa Quiteria V. Thermal and photooxidation of high styrene-butadiene copolymer (SBC). Polym Degrad Stab 86 (2004) 11
20. Haska S.B., Bayramli E., Pekel F., and Ozkar S. Mechanical properties of HTPB-IPDI-based elastomers. J Polym Sci 64 (1997) 2347
21. Celina M., Graham A.C., Gillen K.T., Assink R.A., and Minier L.M. Thermal degradation studies of a polyurethane propellant binder. Rubber Chem Technol 73 (2000) 678
22. Judge M.D. An investigation of composite propellant accelerated ageing mechanisms and kinetics. Propell Explos, Pyrot 28 (2003) 114
23. Ahlblad G., Reitberger T., Terselius B., and Stenberg B. Thermal oxidation of hydroxyl-terminated polybutadiene rubber I. Chemiluminescence studies. Polym Degrad Stab 65 (1999) 179
24. Ahlblad G., Reitberger T., Terselius B., and Stenberg B. Thermal oxidation of hydroxyl-terminated polybutadiene rubber II. Oxidation depth profiles studied by imaging chemiluminescence. Polym Degrad Stab 65 (1999) 185
25. Sinturel C., and Billingham N.C. A theoretical model for diffusion-limited oxidation applied to oxidation profiles monitored by chemiluminescence in hydroxy-terminated polybutadiene. Polym Int 49 (2000) 937
26. Celina M., Wise J., Ottesen D.K., Gillen K.T., and Clough R.L. Correlation of chemical and mechanical property changes during oxidative degradation of neoprene. Polym Degrad Stab 68 (2000) 171
27. Harris D.J., Assink R.A., and Celina M. NMR analysis of oxidatively aged HTPB/IPDI polyurethane rubber: degradation products, dynamics and heterogeneity. Macromolecules 34 (2001) 6695
28. Assink R.A., Celina M., and Gillen K.T. Monitoring the condition of thermally aged polymers by NMR relaxation measurements. Polym News 28 (2003) 102
29. Mowery D.M., Assink R.A., and Celina M. Sensitivity of proton NMR relaxation times in a HTPB based polyurethane elastomer to thermo-oxidative aging. Polymer 46 (2005) 10919
30. Skutnik J.M., Assink R.A., and Celina M. High-sensitivity chemical derivatization NMR analysis for condition monitoring of aged elastomers. Polymer 45 (2004) 7463
31. Celina M., Skutnik Elliott J.M., Winters S.T., Assink R.A., and Minier L.M. Correlation of antioxidant depletion and mechanical performance during thermal degradation of an HTPB elastomer. Polym Degrad Stab 91 (2006) 1870
32. Celina M., Trujillo A.B., Gillen K.T., and Minier L.M. Chemiluminescence as a condition monitoring method for thermal aging and lifetime prediction of an HTPB elastomer. Polym Degrad Stab 91 (2006) 2365
33. Foldes E., and Lohmeijer J. Relationship between chemical structure and performance of primary antioxidants in PBD. Polym Degrad Stab 66 (1999) 31
34. Adam C., Lacoste J., and Lemaire J. Photo-oxidation of elastomeric materials. Part 1-photo-oxidation of polybutadienes. Polym Degrad Stab 24 (1989) 185
35. Gillen K.T., and Clough R.L. Rigorous experimental confirmation of a theoretical model for diffusion-limited oxidation. Polymer 33 (1992) 4358
36. Cunliffe A.V., and Davis A. Photo-oxidation of thick polymer samples-Part II: the influence of oxygen diffusion on the natural and artificial weathering of polyolefins. Polym Degrad Stab 4 (1982) 17
37. Audouin L., Langlois V., Verdu J., and de Bruijn J. Role of oxygen diffusion in polymer aging: kinetic and mechanical aspects. J Mater Sci 29 (1994) 569
38. Wise J., Gillen K.T., and Clough R.L. Quantitative model for the time development of diffusion-limited oxidation profiles. Polymer 38 (1997) 1929
39. Lin-Vien D., Colthup N.B., Fateley W.G., and Grasselli J.G. The handbook of infrared and Raman characteristic frequencies of organic molecules (1991), Academic Press, USA
40. Romanova V., Begishev V., Karmanov V., Kondyurin A., and Maitz M.F. Fourier transform Raman and Fourier transform infrared spectra of cross-linked polyurethaneurea films synthesized from solutions. J Raman Spectrosc 33 (2002) 769
41. Queiroz D.P., and Norberta de Pinho M. Structural characteristics and gas permeation properties of polydimethylsiloxane/poly(propylene oxide) urethane/urea bi-soft segment membranes. Polymer 46 (2005) 2346
42. Schoonover J.R., Dattelbaum D.M., Osborn J.C., Bridgewater J.S., Kenney I., and John W. Pressure-dependent Fourier transform infrared spectroscopy of a poly (ester urethane). Spectrochim Acta A 59 (2003) 309
43. Han Q., and Urban M.W. Surface/interfacial changes during polyurethane crosslinking: a spectroscopic study. V. J Appl Polym Sci 81 (2001) 2045
44. Auten K.L., and Petrovic Z.S. Synthesis, structural characterization, and properties of polyurethane elastomers containing various degrees of unsaturation in the chain extenders. J Polym Sci Pol Chem 40 (2002) 1316
45. Guilment J., and Bokobza L. Determination of polybutadiene microstructures and styrene-butadiene copolymers composition by vibrational techniques combined with chemometric treatment. Vib Spectrosc 26 (2001) 133