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Volumn 48, Issue 35, 2007, Pages 6221-6224

Synthetic study on 13-oxyingenol: construction of the full carbon framework

Author keywords

13 Oxyingenol; Anti HIV activity; Ring closing olefin metathesis

Indexed keywords

13 OXYINGENOL; ALKENE; CARBON; DITERPENOID; EUPHORBIA EXTRACT; UNCLASSIFIED DRUG;

EID: 34547423361     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.06.135     Document Type: Article
Times cited : (17)

References (22)
  • 13
    • 34547441536 scopus 로고    scopus 로고
    • note
    • The stereochemistry of 7 was determined as follows. Diol 7 was converted into acetate A, the NOESY spectrum of which indicated the important correlation to determine the stereochemistry of the diol moiety.{A figure is presented}.
  • 15
    • 34547470622 scopus 로고    scopus 로고
    • note
    • The stereochemistry of 10 was determined by the NOESY correlation and coupling constant.{A figure is presented}
  • 18
    • 34547475672 scopus 로고    scopus 로고
    • Elsinger, F. Org. Synth. Coll. Vol. 5, 76-80.
  • 20
    • 34547461844 scopus 로고    scopus 로고
    • note
    • 6a we achieved the construction of inside-outside framework of ingenol by using ring-closing olefin metathesis in 87%. The siloxy-tether group in this study does not participate in the olefin metathesis.{A figure is presented}
  • 22
    • 34547427540 scopus 로고    scopus 로고
    • note
    • We achieved the introduction of α methyl group in C-11 by removal of the siloxy-tether group in a preliminary work.{A figure is presented}


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.