Morphology, crystalline structure and thermal properties of PEO/MEEP blends

European Polymer Journal

Volumn 43, Issue 8, 2007, Pages 3283-3291

  Silva, V P R ^a   Silva, G G ^a   Caliman, V ^a   Rieumont, J ^a,b   de Miranda Pinto, C O B ^a   Archanjo, B S ^a   Neves, B R A ^a  

^a FEDERAL UNIVERSITY OF MINAS GERAIS   (Brazil)

^b Universidad de La   (Cuba)

Author keywords

AFM (atomic force microscopy); Crystalline structure; Polymer blends; Self concentration model; TMDSC (temperature modulated differential scanning calorimetry)

Indexed keywords

ATOMIC FORCE MICROSCOPY; CRYSTAL STRUCTURE; DIFFERENTIAL SCANNING CALORIMETRY; THERMODYNAMIC PROPERTIES; X RAY DIFFRACTION;

COMPOSITION DEPENDENCE; SELF CONCENTRATION MODELS; SEMICRYSTALLINE BLENDS; TEMPERATURE MODULATED DIFFERENTIAL SCANNING CALORIMETRY;

POLYMER BLENDS;

EID: 34547395463     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2007.06.008     Document Type: Article

References (25)

1. Allcock H.R., and Kugel R.L. Synthesis of high polymeric alkoxy- and aryloxphosphonitriles. J Am Chem Soc 87 (1965) 4216-4217
2. Allcock H.R., Austin P.E., Neenan T.X., Sisko J.T., Blonsky P.M., and Shriver D.F. Polyphosphazenes with etheric side groups - prospective biomedical and solid electrolyte polymers. Macromolecules 19 (1986) 1508-1512
3. Allcock H.R., Napierala M.E., Cameron C.G., and Oconnor S.J.M. Synthesis and characterization of ionically conducting alkoxy ether alkoxy mixed-substituent poly(organophosphazenes) and their use as solid solvents for ionic conduction. Macromolecules 29 (1996) 1951-1956
4. Allcock H.R., Oconnor S.J.M., Olmeijer D.L., Napierala M.E., and Cameron C.G. Polyphosphazenes bearing branched and linear oligoethyleneoxy side groups as solid solvents for ionic conduction. Macromolecules 29 (1996) 7544-7552
5. Allcock H.R. A perspective of polyphosphazene research. J Inorg Organomet Polym Mater 16 (2006) 277-294
6. Blonsky P.M., Shriver D.F., Austin P., and Allcock H.R. Complex-formation and ionic-conductivity of polyphosphazene solid electrolytes. Solid State Ionics 18-19 (1986) 258-264
7. Abraham K.M., Alamgir M., and Reynolds R.K. Polyphosphazene-poly(olefin oxide) mixed polymer electrolytes 1. Conductivity and thermal studies of MEEP/PEO-(LIX)N. J Electrochem Soc 136 (1989) 3576-3582
8. Adamic K.J., Greenbaum S.G., Abraham K.M., Alamgir M., Wintersgill M.C., and Fontanella J.J. Li-7 NMR-study of polymer electrolytes based on composites of poly(bis(methoxyethoxy)ethoxy)phosphazene and poly(ethylene oxide). Chem Mater 3 (1991) 534-538
9. Minto F., Gleria M., Pegoretti A., and Fambri L. Blending, grafting, and cross-linking processes between poly(ethylene oxide) and a (4-benzoylphenoxy)(similar to 0.5)(methoxyethoxyethoxy)(similar to 0.5)phosphazene copolymer. Macromolecules 33 (2000) 1173-1180
10. Gill P.S., Sauerbrunn S.R., and Reading M. Modulated differential scanning calorimetry. J Therm Anal 40 (1993) 931-939
11. Reading M., Elliott D., and Hill V.L. A new approach to the calorimetric investigation of physical and chemical-transitions. J Therm Anal 40 (1993) 949-955
12. Wunderlich B. The tribulations and successes on the road from DSC to TMDSC in the 20th century the prospects for the 21st century. J Therm Anal Calorim 78 (2004) 7-31
13. Song M., Hammiche A., Pollock H.M., Hourston D.J., and Reading M. Modulated differential scanning calorimetry. 4. Miscibility and glass transition behaviour in poly(methyl methacrylate) and poly(epichlorohydrin) blends. Polymer 37 (1996) 5661-5665
14. Lodge T.P., Wood E.R., and Haley J.C. Two calorimetric glass transitions do not necessarily indicate immiscibility: the case of PEO/PMMA. J Polym Sci Part B - Polym Phys 44 (2006) 756-763
15. Lodge T.P., and McLeish T.C.B. Self-concentrations and effective glass transition temperatures in polymer blends. Macromolecules 33 (2000) 5278-5284
16. Silva G.G., Machado J.C., Song M., and Hourston D.J. Nanoheterogeneities in PEO/PMMA blends: a modulated differential scanning calorimetry approach. J Appl Polym Sci 77 (2000) 2034-2043
17. Grishchenko A.E., Pavlov G.M., Fomin G.A., Mikhailova N.A., Ryumtsev E.I., and Tur D.R. Macromolecular conformations of poly (fluoroalkoxyphosphazenes) and structure and optical properties of the related films. Polym Sci Ser A 43 (2001) 1246-1250
18. Pereira R.P., and Rocco A.M. Nanostructure and crystallisation kinetics of poly(ethylene oxide)/poly(4-vinylphenol-co-2-hydroxyethyl methacrylate) blends. Polymer 46 (2005) 12493-12502
19. Zhang H.L., Ren M.Q., Chen Q.Y., Sun S.L., Sun X.H., Zhang H.X., and Mo Z.S. Miscibility and crystallization behavior of PBT/epoxy blends. J Polym Sci Part B - Polym Phys 44 (2006) 1320-1330
20. Wunderlich B. Thermal analysis (1990), Academic Press, San Diego
21. 2)M-O-)N. 10. Crystal-structure of poly(ethylene oxide). Macromolecules 6 (1973) 672-675
22. Bortel E., Hodorowicz S., and Lamot R. Relation between crystallinity degree and stability in solid-state of high molecular-weight poly(ethylene oxide)s. Makromol Chem - Macromol Chem Phys 180 (1979) 2491-2498
23. Deng Y.J., Dixon J.B., and White G.N. Bonding mechanisms and conformation of poly(ethylene oxide)-based surfactants in interlayer of smectite. Colloid Polym Sci 284 (2006) 347-356
24. Beekmans L.G.M., van der Meer D.W., and Vancso G.J. Crystal melting and its kinetics on poly(ethylene oxide) by in situ atomic force microscopy. Polymer 43 (2002) 1887-1895
25. Chen E.Q., Jing A.J., Weng X., Huang P., Lee S.W., Cheng S.Z.D., Hsiao B.S., and Yeh F.J. In situ observation of low molecular weight poly(ethylene oxide) crystal melting, recrystallization. Polymer 44 (2003) 6051-6058