Multiple-frequency EPR spectra of two aqueous Gd 3+ polyamino polypyridine carboxylate complexes: A study of high field effects

Journal of Physical Chemistry A

Volumn 111, Issue 25, 2007, Pages 5399-5407

  Borel, Alain ^a,d   Laus, Sabrina ^a   Ozarowski, Andrzej ^b   Gateau, Christelle ^c   Nonat, Aline ^c   Mazzanti, Marinella ^c   Helm, Lothar ^a  

^a EPFL   (Switzerland)

^b FLORIDA STATE UNIVERSITY   (United States)

^c CEA GRENOBLE   (France)

^d INSTITUTE OF CHEMICAL SCIENCES AND ENGINEERING   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON SPIN PROPERTIES; ELECTRON SPIN RELAXATION; POLYAMINO POLYPYRIDINE CARBOXYLATE COMPLEXES;

ELECTRONIC STRUCTURE; GADOLINIUM; MAGNETIC FIELDS; MAGNETIC RESONANCE IMAGING; MOLECULAR STRUCTURE; PARAMAGNETIC RESONANCE; POSITIVE IONS; SPECTROMETERS;

METAL COMPLEXES;

CARBOXYLIC ACID; CATION; CONTRAST MEDIUM; GADOLINIUM; ORGANOMETALLIC COMPOUND; POLYAMINE; PYRIDINE; PYRIDINE DERIVATIVE; WATER;

ALGORITHM; ARTICLE; CHEMISTRY; ELECTRON SPIN RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLUTION AND SOLUBILITY; TEMPERATURE;

ALGORITHMS; CARBOXYLIC ACIDS; CATIONS; CONTRAST MEDIA; ELECTRON SPIN RESONANCE SPECTROSCOPY; GADOLINIUM; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLIC COMPOUNDS; POLYAMINES; PYRIDINES; SOLUTIONS; TEMPERATURE; WATER;

EID: 34547305463     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp066921z     Document Type: Article

References (50)

1. Caravan, P.; Ellison, J. J.; McMurry, T. J.; Lauffer, R. B. Chem. Rev. 1999, 99, 2293.
2. Merbach, A. E.; Tóth, É. The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging; John Wiley & Sons, Ltd.: Chichester, U.K., 2001.
3. Powell, D. H.; Merbaeh, A. E.; Gonzalez, G.; Brücher, E.; Micskei, K.; Ottaviani, M. F.; Köhler, K.; von Zelewsky, A.; Grinberg, O. Y.; Lebedev, Y. S. Helv. Chim. Acta 1993, 76, 2129.
4. Sur, S. K.; Bryant, R. G. J. Phys. Chem. 1995, 99, 6301.
5. Clarkson, R. B.; Smirnov, A. I.; Smirnova, T. I.; Kang, H.; Belford, R. L.; Earle, K.; Freed, J. H. Mol. Phys. 1998, 95, 1325,
6. Borel, A.; Tóth, É.; Helm, L.; Jánossy, A.; Merbach, A. E. Phys. Chem. Chem. Phys. 2000, 2, 1311.
7. Rast, S.; Borel, A.; Helm, L.; Belorizky, E.; Fries, P. H.; Merbach, A. E. J. Am. Chem. Soc. 2001, 123, 2637.
8. Tóth, É.; Pubanz, D.; Vauthey, S.; Helm, L.; Merbach, A. E. Chem-Eur. J. 1996, 2, 1607.
9. Dunand, F. A.; Toth, E.; Hollister, R.; Merbach, A. E. J. Biol. Inorg. Chem. 2001, 6, 247,
10. Nicolle, G. M.; Toth, E.; Eisenwiener, K. P.; Macke, H. R.; Merbach, A. E. J. Biol. Inorg. Chem. 2002, 7, 757.
11. Nicolle, G. M.; Toth, E.; Schmitt-Willich, H.; Raduchel, B.; Merbach, A. E. Chem.-Eur. J. 2002, 8, 1040.
12. Nicolle, G. M.; Tóth, É.; Eisenwiener, K.-P.; Macke, H. R.; Merbach, A. E. J. Biol. Inorg. Chem. 2002, 7, 757.
13. Caravan, P.; Cloutier, N. J.; Greenfield, M. T.; McDermid, S. A.; Dunham, S. U.; Bulte, J. W. M.; Amedio, J. C.; Looby, R. J.; Supkowski, R. M.; Horrocks, W. D.; McMurry, T. J.; Lauffer, R. B. J. Am. Chem. Soc. 2002, 124, 3152.
14. Caravan, P.; Greenfield, M. T.; Li, X. D.; Sherry, A. D. Inorg. Chem. 2001, 40, 6580.
15. Aime, S.; Barge, A.; Borel, A.; Botta, M.; Chemerisov, S.; Merbach, A. E.; Müller, U.; Pubanz, D. Inorg. Chem. 1997, 36, 5104.
16. Bretonniere, Y.; Mazzanti, M.; Pecaut, J.; Dunand, F. A.; Merbach, A. E. Inorg. Chem. 2001, 40, 6737.
17. Bretonniere, Y.; Mazzanti, M.; Pecaut, J.; Dunand, F. A.; Merbach, A. E. Chem. Commun. 2001, 621.
18. Gateau, C.; Mazzanti, M.; Pécaut, J.; Dunand, F. A.; Merbach, A. E. J. Chem. Soc., Dalton Trans. 2003, 12, 2428.
19. Borel, A.; Kang, H.; Gateau, C.; Mazzanti, M.; Clarkson, R. B.; Belford, R. L. J. Phys. Chem. A 2006, 110, 12434.
20. Fries, P. H.; Gateau, C.; Mazzanti, M. J. Am. Chem. Soc. 2005, 127, 15801.
21. Chatterton, N.; Gateau, C.; Mazzanti, M.; Pécaut, I.; Borel, A.; Helm, L.; Merbach, A. E. Dalton Trans. 2005, 1129
22. Chatterton, N.; Bretonniere, Y.; Pécaut, J.; Mazzanti, M. Angew. Chem., Int. Ed. 2005, 44, 7595.
23. Nonat, A.; Gateau, C.; Fries, P. H.; Mazzanti, M. Chem.-Eur. J. 2006, 12, 7133.
24. Amman, C.; Meier, P.; Merbach, A. E. J. Magn. Reson. 1982, 46, 319.
25. Schmalbein, D.; Maresch, G. G.; Kamlovski, A.; Hofer, P. Appl. Magn. Reson. 1999, 16, 185.
26. Smith, G. M.; Lesurf, J. C. G.; Mitchell, R. H.; Riedi, P. C. Rev. Sci. Instrum. 1998, 69, 3924.
27. Helm, L.; Borel, A. NMRICMA, 2.7 ed.; ICMA: Lausanne, 2000.
28. Rast, S.; Fries, P. H.; Belorizky, E. J. Chim. Phys. 1999, 96, 1543.
29. Rast, S.; Fries, P. H.; Belorizky, E. J. Chem. Phys. 2000, 113, 8724.
30. Connolly, M. L. J. Appl. Crystallogr. 1983, 16, 548.
31. Brunisholz, G.; Randin, M. Helv. Chim. Acta 1959, 42, 1927.
32. Hugi, A. D.; Helm, L.; Merbach, A. E. Helv. Chim. Acta 1985, 68, 508.
33. Void, R. L.; Waugh, J. S.; Klein, M. P.; Phelps, D. E. J. Chem. Phys. 1968, 48, 3831.
34. Meiboom, S.; Gill, D. Rev. Sci. Instrum. 1958, 29, 688.
35. Geraldes, C. F. G. C.; Brown, R. D., III; Brucher, E.; Koenig, S. H.; Sherry, A. D.; Spiller, M. Magn. Reson. Med. 1992, 27, 284.
36. Borel, A.; Helm, L.; Merbach, A. E.; Atsarksin, V. A.; Demidov, V. V.; Odintsov, B. M.; Belford, R. L.; Clarkson, R. B. J. Phys. Chem. A 2002, 106, 6229.
37. Belorizky, E.; Fries, P. H. Phys. Chem. Chem. Phys. 2004, 6, 2341.
38. Benmelouka, M.; Borel, A.; Moriggi, L.; Helm, L.; Merbach, E. J. Phys. Chem. B 2007, 111, 832.
39. Misra, S. K. Transition Ion Data Tabulation: Gd3+ 4f7. In Handbook of Electron Spin Resonance; Poole, C. P. J., Farach, H. A., Eds.; Springer: New York, 1999; Vol. 2, p 257.
40. Redfield, A. G. The Theory of Relaxation Processes. In Advances in Magnetic Resonance; Waugh, J. S., Ed.; Academic Press Inc.: New York, 1965; Vol. 1, p 1.
41. Aime, S.; Barge, A.; Benetello, F.; Bombierei, G.; Botta, M.; Uggeri, F. Inorg. Chem. 1997, 36, 3287.
42. Powell, D. H.; Ni Dubhghaill, O. M.; Pubanz, D.; Helm, L.; Lebedev, Y. S.; Schlaepfer, W.; Merbach, A. E. J. Am. Chem. Soc. 1996, 118, 9333.
43. Rast, S.; Fries, P. H.; Belorizky, E.; Borel, A.; Helm, L.; Merbach, A. E. J. Chem. Phys. 2001, 115, 7554.
44. Zhou, X.; Westlund, P.-O. Spectrochim. Acta, Part A 2005, 62, 335.
45. Borel, A.; Clarkson, R. B.; Belford, R. L. J. Chem. Phys. 2007, 126, 054510/1.
46. Curl, R. F. J. Mol. Phys. 1965, 9, 585.
47. Nyberg, G. Mol. Phys. 1967, 12, 69.
48. Freed, J. H.; Fraenkel, G. K. J. Chem. Phys. 1963, 39, 326.
49. Hudson, A.; Lewis, J. W. E. Trans. Faraday Soc. 1970, 66, 1297.
50. Borel, A.; Helm, L.; Merbach, A. E. Molecular Dynamics of Gd-(III) Complexes in Aqueous Solution by HF EPR. In Very High Frequency (VHF) ESR/EPR; Grinberg, O. Y., Berliner, L. J., Eds.; Kluwer: New York, 2004; p 207.