Polyynes formation from electric arc in liquid argon in presence of methane

Fullerenes Nanotubes and Carbon Nanostructures

Volumn 15, Issue 4, 2007, Pages 291-301

  Cataldo, Franco ^a  

^a Soc Lupi Chem Research Institute   (Italy)

Author keywords

Carbon arc; HPLC; Liquid argon; Liquid chromatography; Methane; Polyynes

Indexed keywords

ABSORPTION SPECTROSCOPY; ARGON; ELECTRIC ARCS; ELECTRON TRAPS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; METHANE;

CARBON ARC; ELECTRONIC ABSORPTION SPECTROSCOPY; LIQUID ARGON; POLYYNES;

CONJUGATED POLYMERS;

EID: 34547267463     PISSN: 1536383X     EISSN: 15364046     Source Type: Journal    
DOI: 10.1080/15363830701423690     Document Type: Article

References (19)

1. Cataldo, F. (2006) Polyynes: Synthesis, Properties and Applications; CRC Press (Taylor & Francis Publishers): Boca Raton, Florida.
2. Muthakarn, P., Sano, N., Charinpanitkul, T., Tanthapanichakoon, W., and Kanki, T. (2006) Characterization of carbon nanoparticles synthesized by submerged arc in alcohols, alkanes and aromatics. J. Phys. Chem., B110: 18299-18303.
3. Cataldo, F. (2004) Synthesis of polyynes in a submerged electric arc in organic solvents. Carbon, 42: 129-142.
4. Cataldo, F. (2006) Monocyanopolyynes from carbon arc in ammonia: about the relative abundance of polyyne series formed in a carbon arc and those detected in the circumstellar shells of AGB stars. Int. J. Astrobiol., 5: 37-45.
5. Cataldo, F. (2004) Polyynes: a new class of carbon allotropes. About the formation of dicyanopolyynes from an electric arc between graphite electrodes in liquid nitrogen. Polyhedron, 23: 1889-1896.
6. Cataldo, F. (2004) Cyanopolyynes: carbon chains formation in a carbon arc mimicking the formation of carbon chains in the circumstellar medium. Int. J. Astrobiol., 3: 237-246.
7. x formation by arcing carbon disulphide with the submerged carbon arc. J. Inorg. Organomet. Polym. Mater., 16: 15-24.
8. Wakabayashi, T. and Kraetschmer, W. (2006) Carbon chain molecules in cryogenic matrices. In Polyynes: Synthesis, Properties and Applications; Cataldo, F. (ed.); CRC Press (Taylor & Francis Publishers): Boca Raton, Florida, 1-14.
9. Cataldo, F. (2004) Polyynes production in a solvent-submerged electric arc between graphite electrodes. Part 1: synthesis and spectroscopy, Fullerenes, Nanot. Carbon Nanostruct., 12: 603-617.
10. Eastmond, R., Johnson, T.R., and Walton, D.M.R. (1972) Silylation as a protective method for terminal alkynes in oxidative couplings. A general synthesis of the parent polyynes. Tetrahedron, 28: 4601-4612.
11. Kloster-Jensen, E., Haink, HJ., and Christen, H. (1974) The electronic spectra of unsubstituted mono- to penta-acetylene in the gas phase and in solution in the range 1100 to 4000. A. Helv. Chim. Acta, 56: 1731-1744.
12. Gillam, A.E. and Stern, E.S. (1954) An Introduction to Electronic Absorption Spectroscopy in Organic Chemistry; Edward Arnold Publishers: London.
13. Howard, J.B. and Richter, H. (2000) Formation of polycyclic aromatic hydrocarbon and their growth to soot - a review of chemical reaction pathways. Progr. Energy Comb. Sci., 26: 565-608.
14. Gerasimov, Ya. (ed.). (1978) Physical Chemistry; Mir Publishers: Moscow; Vol. 2, 234-235.
15. Yeremin, E.N. (1979) The Foundations of Chemical Kinetics; Mir Publishers: Moscow, pp. 81-84 and 302-309.
16. Venugopalan, M. (1971) Reactions Under Plasma Conditions; Wiley-Interscience: New York, 268-269.
17. Van Krevelen, D.W. (1990) Properties of Polymers. Their correlation with chemical structure; their numerical estimation and prediction from additive group contributions. 3rd Edn.; Elsevier, Amsterdam. Chapter 20.
18. Cataldo, F. (1997) On the enthalpy of formation of the most known carbon allotropes. Fullerene Sci. Technol., 5: 1615-1620.
19. Lebedev, B.V. (2000) Thermodynamics of carbyne. Russian Chem. Bull., 49: 965-975.