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Volumn 111, Issue 24, 2007, Pages 6955-6961

Kinetics of formation and dissociation of aquocobalt(III) complexes with some carboxylic acids in acid perchlorate solution

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLIC ACIDS; COMPLEXATION; CONCENTRATION (PROCESS); IONIC STRENGTH; LIGANDS; REACTION KINETICS;

EID: 34547237579     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp070848a     Document Type: Article
Times cited : (2)

References (50)
  • 18
    • 84906374829 scopus 로고    scopus 로고
    • obsd was approximately constant.
    • obsd was approximately constant.
  • 19
    • 0242591392 scopus 로고
    • Kinetics of the formation of the monoazide complex of iron(III)
    • Seewald, D.; Sutin, N. Kinetics of the formation of the monoazide complex of iron(III). Inorg. Chem. 1963, 2, 643.
    • (1963) Inorg. Chem , vol.2 , pp. 643
    • Seewald, D.1    Sutin, N.2
  • 28
    • 84906374830 scopus 로고    scopus 로고
    • 25
    • 25
  • 32
    • 84906388759 scopus 로고    scopus 로고
    • This is the origin of the kinetic indistinguishability of the reaction pair Coaq3, L- → products and CoOH aq2, HL → products. As noted in the text, the acid dissociation constant of Coaq3+ is estimated to be K h, 2 ± 1) × 10-3 at 25°C, with ΔHh ≈ 40 kj mol-11 and ΔSh ≈ 80 JK mol-1 ref 6
    • -1 (ref 6).
  • 35
    • 84906374831 scopus 로고    scopus 로고
    • 35
    • 35
  • 40
    • 33646891887 scopus 로고    scopus 로고
    • Grant, M. W.; Dodgen, H. W.; Hunt, J. P. J Am. Chem. Soc. 1971, 93, 6828.
    • Grant, M. W.; Dodgen, H. W.; Hunt, J. P. J Am. Chem. Soc. 1971, 93, 6828.
  • 49
    • 84906388755 scopus 로고
    • Sillèn, L. G, Martell, A. E, Eds, The Chemical Society: London, special publication no. 17; p
    • Stability Constants of Metal-ion Complexes; Sillèn, L. G., Martell, A. E., Eds.; The Chemical Society: London, 1964; special publication no. 17; p 389.
    • (1964) Stability Constants of Metal-ion Complexes , pp. 389


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.