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One way of synthesizing metallic nanoparticles via microemulsions is to prepare two microemulsions of equal size, one containing a metal salt and the other one the reducing agent. Mixing these two microemulsions immediately leads to the reduction of the metal salt and thus to the formation of the respective metallic nanoparticles. The reason why the final nanoparticle size nearly equals the initial droplet size is the fact that the exchange of reactants is faster than the structural changes of the microemulsion ∼1 μs, It is only in this case that the microstructure can be replicated
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One way of synthesizing metallic nanoparticles via microemulsions is to prepare two microemulsions of equal size, one containing a metal salt and the other one the reducing agent. Mixing these two microemulsions immediately leads to the reduction of the metal salt and thus to the formation of the respective metallic nanoparticles. The reason why the final nanoparticle size nearly equals the initial droplet size is the fact that the exchange of reactants is faster than the structural changes of the microemulsion (∼1 μs). It is only in this case that the microstructure can be replicated.
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A similar phenomenon has been observed with amphiphilic block copolymers, the presence of which induces a phase separation if the polymer block(s) are larger than the domain size(s) of the microemulsion (Frank, C.; Strey, R.; Schmidt, C.; Stubenrauch, C. J. Colloid Interface Sci. 2007, 312, 76).
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A similar phenomenon has been observed with amphiphilic block copolymers, the presence of which induces a phase separation if the polymer block(s) are larger than the domain size(s) of the microemulsion (Frank, C.; Strey, R.; Schmidt, C.; Stubenrauch, C. J. Colloid Interface Sci. 2007, 312, 76).
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A similar phenomenon has been observed in mixtures of DNA and calcium zwitterionic lipids in which the presence of the stiff DNA strands induces the formation of a highly ordered rectangular columnar phase McManus, J. J, Raedler, J. O, Dawson, K. A. J. Am. Chem. Soc. 2004, 126, 15966
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A similar phenomenon has been observed in mixtures of DNA and calcium zwitterionic lipids in which the presence of the stiff DNA strands induces the formation of a highly ordered rectangular columnar phase (McManus, J. J.; Raedler, J. O.; Dawson, K. A. J. Am. Chem. Soc. 2004, 126, 15966).
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