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Crystal data for 1·1.75MeCN·0.25H 2O: C99.5H85.75N5.75O 15.25P4V4,Mr=1933.63, 0.11 × 0.11 x 0.06 mm3, green plate, triclinic, space group P1̄, a=18.652(4, b=20.154(2, c=26.782(5) Å, a=72.45(3, β=85.23(3, γ=82.78(3)°, V=9512(3) Å3, Z=4, T=150(2) K, λ(synchroton)=0.69040 Å, ρcalcd=1.35 gcm -3, 74340 reflections collected, 33461 unique (R int=0.0604, R(F)=0.0647 and wR2=0.1840 using 26920 reflections with I>2σI, Crystal data for 2·3MeCN: C65H98N10O 19P6V5Cl2, M r=1834.95, 0.23 × 0.15 × 0.08 mm3, green block, monoclinic, s
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int=0.000), R(F)=0.1256, wR2=0.3107 using 4435 reflections with I > 2σ(I). CCDC 639860-CCDC 639864 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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G. M. Sheldrick, SHELX-97, Program for X-ray Crystal Structure Solution and Refinement; Göttingen University: Göttingen, Germany, 1997.
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G. M. Sheldrick, SHELX-97, Program for X-ray Crystal Structure Solution and Refinement; Göttingen University: Göttingen, Germany, 1997.
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