Mechanistic studies of Ce(IV)-mediated oxidation of β-dicarbonyls: Solvent-dependent behavior of radical cation intermediates

Journal of Organic Chemistry

Volumn 72, Issue 15, 2007, Pages 5486-5492

  Jiao, Jingliang ^a   Zhang, Yang ^a   Devery III, James J ^a   Xu, Luna ^a   Deng, Jennifer ^a   Flowers II, Robert A ^a  

^a LEHIGH UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; CERIUM; DATA ACQUISITION; OXIDATION; POSITIVE IONS; SOLVENTS;

RADICAL CATIONS; SUBSTRATE OXIDATION; TRANSITION STATE;

KETONES;

1,3 DIKETONE; ACETONITRILE; CARBONYL DERIVATIVE; CATION; CERIUM; DICHLOROMETHANE; METHANOL;

ARTICLE; CHEMICAL REACTION KINETICS; OXIDATION; PROTON TRANSPORT; REACTION ANALYSIS; REACTION TIME; THERMAL ANALYSIS;

CATIONS; CERIUM; KETONES; KINETICS; OXIDATION-REDUCTION; SOLVENTS;

EID: 34547115437     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0625406     Document Type: Article

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