Phenylcalcium iodides with silyl substituents in para-position

Inorganic Chemistry Communications

Volumn 10, Issue 8, 2007, Pages 853-855

  Langer, Jens ^a   Görls, Helmar ^a   Westerhausen, Matthias ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

Author keywords

Calcium; Direct synthesis; Grignard reagents; Organocalcium compounds; Phenylcalcium iodide

Indexed keywords

EID: 34447577863     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.03.032     Document Type: Article

References (15)

1. Fischer R., Görls H., and Westerhausen M. Inorg. Chem. Commun. 8 (2005) 1159-1161
2. Fischer R., Gärtner M., Görls H., and Westerhausen M. Angew. Chem. 118 (2006) 624-627
3. Fischer R., Gärtner M., Görls H., and Westerhausen M. Angew. Chem. Int. Ed. 45 (2006) 609-612
4. Fischer R., Gärtner M., Görls H., and Westerhausen M. Organometallics 25 (2006) 3496-3500
5. Gärtner M., Görls H., and Westerhausen M. Synthesis (2007) 725-730
6. Fischer R., Gärtner M., Görls H., Yu L., Reiher M., and Westerhausen M. Angew. Chem. 119 (2007) 1642-1647
7. Fischer R., Gärtner M., Görls H., Yu L., Reiher M., and Westerhausen M. Angew. Chem. Int. Ed. 46 (2007) 1618-1623
8. -3, Flack parameter -0.03(3).
9. -3, Flack parameter -0.03(3).
10. 8]THF): δ = 124.7 (Si-C), 128.0 (6 × m-CH Ph), 129.5 (3 × p-CH Ph), 133.1 (2 × CH), 135.1 (3 × i-C Ph), 137.2 (6 × o-CH Ph), 141.2 (2 × CH), 194.5 (Ca-C).
11. -1, 30448 measured data, 3716 data with I > 2σ(I), 6951 unique data.
12. Westerhausen M., Gärtner M., Fischer R., and Langer J. Angew. Chem. 119 (2007) 1994-2001
13. Westerhausen M., Gärtner M., Fischer R., and Langer J. Angew. Chem. Int. Ed. 46 (2007) 1950-1956
14. Zobel B., and Jurkschat K. Main Group Met. Chem. 21 (1998) 765-767
15. See also:. Altmann R., Gausset O., Hummeltenberg R., Jurkschat K., Kuhn S., Schurmann M., and Zobel B. In: Auner N., and Weis J. (Eds). Organosilicon Chemistry IV: From Molecules to Materials (2000), Wiley-VCH, Weinheim 394-398