A readily prepared, highly reusable and active polymer-supported molybdenum carbonyl Schiff base complex as epoxidation catalyst

Inorganic Chemistry Communications

Volumn 10, Issue 8, 2007, Pages 914-917

  Grivani, Gholamhossein ^a   Tangestaninejad, Shahram ^b   Halili, Akbar ^a  

^a DAMGHAN UNIVERSITY   (Iran)

^b UNIVERSITY OF ISFAHAN   (Iran)

Author keywords

Epoxidation; Molybdenum carbonyl; Polymer support; Schiff base complex

Indexed keywords

EID: 34447573819     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.01.016     Document Type: Article

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18. 3 and stirred for 6 h at 155 °C. Then the resin was collected on a glass filter, washed with DMSO, hot water, 2:1 mixture of dioxane/water then rinsed with dioxane, ethanol, methylene chloride and then dried at 100 °C under vacuum.
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21. 6 (12.5 mmol) and refluxed for 1 h then 2 g of resin 2 was added to this solution and refluxed for 45 min. The beads was filtered and washed thoroughly with THF and dried in vacuo.
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23. 4, 0.5 mmol alkene, 1.5 mmol tert-butylhydroperoxide, 0.03 g (0.01 mmol/Mo) catalyst and was refluxed. The progress of reaction was monitored by GLC.