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The mode Grüneisen parameters γ were determined by the relationship of γi =d ln (νi) d ln(V), where ν and V are the vibrational frequency and volume, respectively. For actual calculation, the pressure dependence of the cell volume reported in Ref. was used.
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The present gap energy is lower than that in the previous paper (Ref.). This disagreement seems to arise from the sample thickness; the previous sample was 0.5 μm thick, in contrast to the present sample of 2 μm. We believe that the thicker sample provides the more accurate results because the more steeply rising feature is obtained in the absorption edge.
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The present gap energy is lower than that in the previous paper (Ref.). This disagreement seems to arise from the sample thickness; the previous sample was 0.5 μm thick, in contrast to the present sample of 2 μm. We believe that the thicker sample provides the more accurate results because the more steeply rising feature is obtained in the absorption edge.
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