Proton conductivity in the dry membrane of poly(sulfonic acid) and polyamine layer-by-layer complex

Chemical Communications

Volumn , Issue 28, 2007, Pages 2989-2991

  Tago, Takahiro ^a   Shibata, Hirokazu ^a   Nishide, Hiroyuki ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLAMINE DERIVATIVE; GOLD; SULFONIC ACID DERIVATIVE;

ARTICLE; COMPLEX FORMATION; ELECTRODE; MEMBRANE; PROTON TRANSPORT; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 34447344049     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b703947f     Document Type: Article

References (28)

1. M. Doyle and G. Rajendran, in Handbook of Fuel Cells: Fundamentals, Technology, and Applications, ed., W. Vielstichm,,, A. Lamm, and, H. A. Gasteiger,, John Wiley & Sons, New York, 2003, vol. 3, p. 351
2. M. A. Hickner H. Ghassemi Y. S. Kim B. R. Einsla J. E. McGrath Chem. Rev. 2004 104 4587
3. R. Beckerbauer, US Pat., 3,714,245, 1973
4. K. A. Mauritz R. B. Moore Chem. Rev. 2004 104 4535
5. K. Miyatake H. Zhou H. Uchida M. Watanabe Chem. Commun. 2003 368
6. K. Saito T. Masuyama H. Nishide Bull. Chem. Soc. Jpn. 2005 78 1699
7. K. Saito T. Tazaki R. Matsubara H. Nishide Ind. Eng. Chem. Res. 2005 44 8626
8. N. Asano M. Aoki S. Suzuki K. Miyatake H. Uchida M. Watanabe J. Am. Chem. Soc. 2006 128 1762
9. A. Bozkurt O. Ekinci W. H. Meyer J. Appl. Polym. Sci. 2003 90 3347
10. K. D. Kreuer S. J. Paddison E. Spohr M. Schuster Chem. Rev. 2004 104 4637
11. W. Ogihara H. Kosukegawa H. Ohno Chem. Commun. 2006 3637
12. K. D. Kreuer A. Fuchs M. Ise M. Spaeth J. Maier Electrochim. Acta 1998 43 1281
13. J. J. Fontanella M. C. Wintersgill J. S. Wainright R. F. Savinell M. Litt Electrochim. Acta 1998 43 1289
14. Y. L. Ma J. S. Wainright M. H. Litt R. F. Savinell J. Electrochem. Soc. 2004 151 A8
15. E. Tsuchida K. Abe Adv. Polym. Sci. 1982 45 1
16. B. Phillip W. Dawydoff K. J. Linow Z. Chem. 1982 22 1
17. J. Smid and D. Fish, in Encyclopedia of Polymer Science and Engineering, ed., H. F. Mark,,, N. M. Bikales,,, C. G. Overberger, and, G. Menges,, John Wiley & Sons, New York, 2nd edn, 1988, vol. 11, pp. 720
18. R. K. Iler J. Colloid Interface Sci. 1966 21 569
19. Y. Lvov K. Ariga I. Ichinose T. Kunitake J. Am. Chem. Soc. 1995 117 6117
20. G. Decher Science 1997 277 1232
21. M.-K. Park S. Deng R. C. Advincula J. Am. Chem. Soc. 2004 126 13723
22. D. M. DeLongchamp P. T. Hammond Langmuir 2004 20 5403
23. G. M. Lowman H. Tokuhisa J. L. Lutkenhaus P. T. Hammond Langmuir 2004 20 9791
24. T. Tago H. Shibata H. Nishide Macromol. Symp. 2006 235 19
25. The proton conductivity of the 100 bilayered PSS-PAA complex membrane with a thickness of 100 nm on a gold substrate was first vertically checked to the substrate by carefully depositing gold or aluminum on the membrane. However, the measured resistance was zero due to penetration of the deposited metal through the thin organic membrane
26. Before the proton conductivity measurement, the membrane was kept in a temperature-controlled chamber at 170°C with relative humidity of 0% for one day. The conductivity measurement was carried out in the same chamber
27. d10%) or the thermal degradation temperature of the PSS-PAA membrane itself was 380°C, which was 115°C higher than that of PSS. This significantly high thermostability of the layer-by-layer membrane suggests an effective network formation through the polymer complex formation
28. -1 (30-170°C). It is suggested that a good membrane formability in the layer-by-layer complexation realized the proton conductivity