Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex

Inorganic Chemistry

Volumn 46, Issue 13, 2007, Pages 5143-5145

  Melfi, Patricia J ^a,b   Sung, Kuk Kim ^a   Jeong, Tae Lee ^a   Bolze, Frédéric ^a   Seidel, Daniel ^a   Lynch, Vincent M ^a   Veauthier, Jacqueline M ^b   Gaunt, Andrew J ^b   Neu, Mary P ^b   Ou, Zhongping ^c   Kadish, Karl M ^c   Fukuzumi, Shunichi ^d   Ohkubo, Kei ^d   Sessler, Jonathan L ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^b LOS ALAMOS NATIONAL LABORATORY   (United States)

^c University of Houston   (United States)

^d JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34447312852     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic700781t     Document Type: Article

References (22)

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18. This is ascribed to the presence of small amounts of radical impurities, perhaps produced as the result of facile one-electron reduction of the compound in solution. Consistent with this, a small (<1%) but detectable peak was seen in the ESR spectrum of 5.
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20. The line width becomes significantly broader with increasing temperature.
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