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Crystal data and structure refinement for 2b1: C 36H24O6·CH2Cl2, Mr, 637.51 g mol-1, crystal dimensions: 0.25 x 0.30 x 0.50 mm3, T, 180 K, trigonal, space group R3, a, 21.479(5, b, 21.479(5, c, 6.560(5) Å, α, 90, β, 90, γ, 180°, V, 2621(2) Å3, Z, 3, ρ, 1.21 g cm3, μ, 0.228 mm-1, 27 634 reflections measured, 1952 unique (R(int, 0.0200, θmax, 32.20°, index ranges: -31 ≤ h ≤ 31, 31 ≤ k ≤ 31, 9 ≤ l ≤ 9, σ(I) limit, 2.00, 70 refined parameters, 747 reflections used (I > 2σI, R1, 0.0720, wR2, 0.0834, Δρmin, 0.42 e Å-3, Δρmax, 0
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-3, GOF = 1.127. CCDC-632362 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/data_request/cif.
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18
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33845377321
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19
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34447253611
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for n = 4, 6, 7, and 8, see: L. T. Scott, private communication;
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34447286281
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1 under Hay oxidative-coupling conditions afforded a completely insoluble black solid.
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1 under Hay oxidative-coupling conditions afforded a completely insoluble black solid.
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