A new method to improve surface morphology of Ni-Fe-Mo-Co alloy electrode and its catalytic activity for HER

Rare Metals

Volumn 26, Issue 3, 2007, Pages 205-212

  LUO, Beiping ^a,b   REN, Buye ^c   XU, You ^a   ZHENG, Yajie ^b  

^a HUNAN INSTITUTE OF SCIENCE AND TECHNOLOGY   (China)

^b CENTRAL SOUTH UNIVERSITY   (China)

^c SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

catalytic activity; electrodeposition; hydrogen evolution; Ni Fe Mo Co alloy; surface treatment

Indexed keywords

CATALYST ACTIVITY; CURRENT DENSITY; ELECTRODEPOSITION; ELECTRODES; ELECTROLYSIS; LEACHING; PORE SIZE; SURFACE TREATMENT;

ELECTROLYSIS TESTS; NANOMETER RANGE; PRE-ELECTROLYZING; PRETREATMENT METHOD;

NICKEL ALLOYS;

EID: 34347342572     PISSN: 10010521     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1001-0521(07)60202-2     Document Type: Article

References (18)

1. Huot J.Y., Trudeau M.L., and Schulz R. Low hydrogen overpotential nanocrystalline Ni-Mo cathodes for alkaline water electrolysis. J. Electrochem. Soc. 138 5 (1991) 1316
2. Hu W.K., Zhang Y.S., Song D.Y., Zhou Z.X., and Wang Y. Electrode properties of amorphous nickel-iron-molybdenum alloy as a hydrogen electrocatalyst in alkaline solution. Mater. Chem. Phys. 41 2 (1995) 141
3. Birry L., and Lasia A. Studies of the hydrogen evolution reaction on Raney nickel-molybdenum electrodes. J. Appl. Electrochem. 32 (2004) 1
4. Crnkovic F.C., Machado S.A.S., and Avaca L.A. Electrochemical and morphological studies of electrodeposited Ni-Fe-Mo-Zn alloys tailored for water electrolysis. Int. J. Hydrogen Energy 29 3 (2004) 249
5. Raj I.A., and Vasu K.I. Transition metal-based cathodes or hydrogen evolution in alkaline solution: electrocatalysis on nickel-based ternary electrolytic codeposits. J. Appl. ElectroChem. 22 5 (1992) 471
6. Ramesh L., Sheshadri B.S., and Mayanna S.M. Electrolytic preparation and characterization of Ni-Mo-Fe alloys: cathode materials for alkaline water electrolysis. Int. J. Energy Res. 23 10 (1999) 919
7. Hu C.C., and Weng C.Y. Hydrogen evolution activity on nickel-molybdenum deposits using experimental strategies. J. Appl. Electrochem. 30 (2000) 499
8. Ohmori T., Go H., Nakayama A., Mametsuka H., and Suzuki E. Influence of sputtering parameters on hydrogen evolution overvoltage in sputter-deposited Co-Mo alloy electrode. Mater. Lett. 47 3 (2001) 103
9. De Giz M.J., Tremiliosi-Filho G., Fonzalez E.R., Srinivasan S., and Appleby A.J. The hydrogen evolution reaction on amorphous nickel and cobalt alloys. Int. J. Hydrogen Energy 20 6 (1995) 423
10. 70 alloy electrodes. Mater. Charact. 55 1 (2005) 83
11. Suffredini H.B., Cerne J.L., Crnkovic F.C., Machado S.A.S., and Avaca L.A. Recent developments in electrode materials for water electrolysis. Int. J. Hydrogen Energy 25 5 (2000) 415
12. Losiewicz B., Budniok A., Rówiński E., Lagiewka E., and Lasia A. The structure, morphology and electrochemical impedance study of the hydrogen evolution reaction on the modified nickel electrodes. Int. J. Hydrogen Energy 29 2 (2004) 145
13. Elezović N.R., Jović V.D., and Krstajić N.V. Kinetic of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution. Electrochim. Acta 50 28 (2005) 5594
14. Huang L., Yang F.Z., Sun S.G., and Xu S.K. Studies on structure and electrocatalytic hydrogen evolution of nanocrystalline Ni-Mo-Fe alloy electrodeposit electrodes. Chin. J. Chem. 21 4 (2003) 382
15. Han Q., Chen J.S., Liu K.R., Li X., and Wei X.J. Hydrogen evolution reaction of the electrodeposited amorphous Ni-S-Co alloy in alkaline medium. Acta Metall. Sin. 40 3 (2004) 331
16. Yang J., Zhang C.Z., and Wu Z.D. Preparation and catalytic property of amorphous Ni-Mo-Co alloy electrode. Chin. J. Appl. Chem. 17 5 (2000) 475
17. Huang L., Yang F.Z., Xu S.K., and Zhou S.M. Structure of nanocrystalline Ni-Mo-Co alloy and electrocatalytic hydrogen evolution on electrode thereof. Chin. J. Appl. Chem. 18 10 (2001) 767
18. Luciana S.S., Sergio H.D., Claudia E.B.M., and Lucia H.M. Characterisation of electrochemically deposited Ni-Mo alloy coatings. Electrochem. Commun. 6 6 (2004) 543