Weak ferromagnetism in 1D coordination polymers: Syntheses, crystal structures, spectroscopic and magnetic properties of [Cu(L)(Memal)]n (Memal2- = the dianion of methylmalonic acid, L = 1,10-phenanthroline, 2,2′-bipyridine)

Polyhedron

Volumn 26, Issue 12, 2007, Pages 2536-2542

  Gkioni, Catherine ^a   Boudalis, Athanassios K ^a   Sanakis, Yiannis ^a   Raptopoulou, Catherine P ^a  

^a INSTITUTE OF MATERIALS SCIENCE   (Greece)

Author keywords

1,10 Phenanthroline; 2,2 Bipyridine; Copper(II) complexes; EPR spectroscopy; Magnetic properties; Methylmalonato complexes

Indexed keywords

COORDINATION REACTIONS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FERROMAGNETISM; MAGNETIC SUSCEPTIBILITY; MOLAR RATIO; SYNTHESIS (CHEMICAL);

1,10-PHENANTHROLINE; 1D COORDINATION POLYMER; 2,2′-BIPYRIDINE; BIPYRIDINES; COPPER(II) COMPLEX; EPR SPECTROSCOPY; METHYLMALONATO COMPLEX; METHYLMALONIC ACID; PHENANTHROLINES; WEAK FERROMAGNETISM;

COPPER COMPOUNDS;

EID: 34347326259     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2006.12.033     Document Type: Article

References (55)

1. See for example:. Gutschke S.O.H., Price D.J., Powell A.K., and Wood P.T. Angew. Chem. Int. Ed. 40 (2001) 1920
2. Barthelet K., Marrot J., Riou D., and Férey G. Angew. Chem. Int. Ed. 41 (2002) 281
3. Barthelet K., Riou D., and Férey G. Chem. Commun. (2002) 1492
4. Riou-Cavellec M., Albinet C., Livage C., Guillou N., Noguès M., Grenèche J.M., and Férey G. Solid State Sci. 4 (2002) 267
5. See for example:. Bordiga S., Lamberti C., Ricchiardi G., Regli L., Damin A., Lillerud K.-P., Bjorgen M., and Zecchina A. Chem. Commun. (2004) 2300
6. Shi J.-M., Xu W., Liu Q.-Y., Liu F.-L., Huang Z.-J., Lei H., Yu W.-T., and Fang Q. Chem. Commun. (2002) 756
7. Coronado E., Clemente-León M., Galán-Mascarós J.R., Giménez-Saiz C., Gómez-García C.J., and Martínez-Ferrero E. J. Chem. Soc. Dalton Trans. (2000) 3955
8. Evans O.R., and Win W. Chem. Mater. 13 (2001) 3009
9. Bie H.-Y., Yu J.-H., Zhao K., Lu J., Duan L.-M., and Xu J.-Q. J. Mol. Struc. 741 (2005) 77
10. See for example:. Eddaoudi M., Kim J., Rosi N., Vodak D., Wachter J.B., O'Keeffe M., and Yaghi O.M. Science 295 (2002) 469
11. Rosi N.L., Eddaoudi M., O'Keeffe J.Kim.M., and Yaghi O.M. Cryst. Eng. Comm. 4 (2002) 401
12. Yaghi O.M., Li G., and Li H. Nature 378 (1995) 703
13. Eddaoudi M., Moler D.B., Li H., Chen B., Reineke T.M., O'Keeffe M., and Yaghi O.M. Acc. Chem. Res. 34 (2001) 319 and references therein
14. For an excellent review see:. Rao C.N.R., Natarajan S., and Vaidhyanathan R. Angew. Chem. Int. Ed. 43 (2004) 1466
15. Caneschi A., Gatteschi D., Lalioti N., Sangregorio C., Sessoli R., Venturi G., Vindigni A., Rettori A., Pini M.G., and Novak M.A. Angew. Chem., Int. Ed. 40 (2001) 1760
16. See for example:. Coulon C., Clérac R., Lecren L., Wernsdorfer W., and Miyasaka H. Phys. Rev. B69 (2004) 132408
17. Bogani L., Caneschi A., Gatteschi D., Massi M., Novak M.A., Pini M.G., Rettori A., Sessoli R., and Vindigni A. Phys. Rev. Lett. 92 (2004) 207204
18. Rodríguez-Martín Y., Sanchiz J., Ruiz-Pérez C., Lloret F., and Julve M. Cryst. Eng. Comm. 4 (2002) 631
19. Ruiz-Pérez C., Hernández-Molina M., Sanchiz J., López T., Lloret F., and Julve M. Inorg. Chim. Acta 298 (2000) 245
20. Ghosal D., Maji T.K., Mallah T., Lu T.-H., Mostafa G., and Chaudhuri N.R. Inorg. Chim. Acta 358 (2005) 1027
21. Ruiz-Pérez C., Sanchiz J., Hernández-Molina M., Lloret F., and Julve M. Inorg. Chim. Acta 298 (2000) 202
22. Zheng Y.-Q., and Xie H.-Z. J. Coord. Chem. 57 (2004) 1537
23. Saadeh S.F., Trojan K.L., Kampf J.W., Hatfield W.E., and Pecoraro V.L. Inorg. Chem. 32 (1993) 3034
24. Kwik W.-L., Ang K.-P., Chan H.S.-O., Chebolu V., and Koch S.A. J. Chem. Soc. Dalton Trans. (1986) 2519
25. Gasque L., Moreno-Esparza R., Mollins E., Briansó-Penalva J., Rutz-Ramírez L., and Medina-Dickinson G. Acta Cryst. C55 (1999) 158
26. Suresh E., and Bhadbhade M.M. Acta Cryst. C53 (1997) 193
27. Sain S., Maji T.K., Mostafa G., Lu T.-H., and Chaudhuri N.R. Inorg. Chim. Acta 351 (2003) 12
28. Rodríguez-Marti{dotless}́n Y., Sanchiz J., Ruiz-Pérez C., Lloret F., and Julve M. Inorg. Chim. Acta 326 (2001) 20
29. Zhang Q.-Z., Lu C.-Z., and Yang W.-B. J. Coord. Chem. 58 (2005) 1759
30. Rodri{dotless}́guez-Marti{dotless}́n Y., Hernández-Molina M., Delgado F.S., Pasán J., Ruiz-Pérez C., Sanchiz J., Lloret F., and Julve M. Cryst. Eng. Comm. 4 (2002) 440
31. Ruiz-Pérez C., Hernández-Molina M., Lorenzo-Luis P., Lloret F., Cano J., and Julve M. Inorg. Chem. 39 (2000) 3845
32. Rodríguez-Martín Y., Ruiz-Pérez C., Sanchiz J., Lloret F., and Julve M. Inorg. Chim. Acta 318 (2001) 159
33. Bie H.-Y., Yu J.-H., Zhao K., Lu J., Duan L.-M., and Xu J.-Q. J. Molec. Struc. 741 (2005) 77
34. Sain S., Maji T.K., Mostafa G., Lu T.-H., and Chaudhuri N.R. New J. Chem. 27 (2003) 185
35. Delgado F.S., Sanchiz J., Ruiz-Pérez C., Lloret F., and Julve M. Inorg. Chem. 42 (2003) 5938
36. Liu T.-F., Sun H.L., Gao S., Zhang S.-W., and Lau T.C. Inorg. Chem. 42 (2003) 4792
37. Zhang X., Lu C., Zhang Q., Lu S., Yang W., Liu J., and Zhuang H. Eur. J. Inorg. Chem. (2003) 1181
38. Sheldrick G.M. SHELXS-86: Structure Solving Program (1986), University of Göttingen, Germany
39. Sheldrick G.M. SHELXL-97: Crystal Structure Refinement (1997), University of Göttingen, Germany
40. Bellamy L.J. The Infra-red Spectra of Complex Molecules (1975), Chapman and Hall, London
41. Zhang Y., Collison D., Livens F.R., Helliwell M., Heatley F., Powell A.K., Wocadlo S., and Eccles H. Polyhedron 21 (2002) 81
42. Ruiz-Pérez C., Sanchiz J., Hernández-Molina M., Lloret F., and Julve M. Inorg. Chem. 39 (2000) 1363
43. Chattopadhyay D., Chattopadhyay S.K., Lowe P.R., Schwalde C.H., Mazumder S.K., Rana A., and Ghosh S. J. Chem. Soc. Dalton Trans. (1993) 913
44. Shen H.-Y., Bu W.-M., Liao D.-Z., Jiang Z.-H., Yan S.-P., and Wang G.-L. Inorg. Chem. Commun. 3 (2000) 497
45. Curry M.E., Eggleston D.S., and Hodgson D.J. J. Am. Chem. Soc. 107 (1985) 8234
46. Baker Jr. G.A., Rushbrooke G.S., and Gilbert H.E. Phys. Rev. A 135 (1964) 1272
47. The calculation of the magnetization was accomplished with use of the MAGPACK program package (ISOMAG):. Borrás-Almenar J.J., Clemente-Juan J.M., Coronado E., and Tsukerblat B.S. Inorg. Chem. 38 (1999) 6081
48. Borrás-Almenar J.J., Clemente-Juan J.M., Coronado E., and Tsukerblat B.S. J. Comput. Chem. 22 (2001) 985
49. Pasán J., Delgado F.S., Rodri{dotless}́guez-Martín Y., Hernández-Molina M., Ruiz-Pérez C., Sanchiz J., Lloret F., and Julve M. Polyhedron 22 (2003) 2143
50. Pasán a.) J., Sanchiz J., Ruiz-Pérez C., Lloret F., and Julve M. Eur. J. Inorg. Chem. (2004) 4081
51. Sanchiz J., Rodriguez-Martin Y., Ruiz-Perez C., Mederos A., Lloret F., and Julve M. New. J. Chem. 26 (2002) 1624
52. Rodriguez-Martin Y., Hernández-Molina M., Delgado F.S., Pasán J., Ruiz-Perez C., Sanchiz J., Lloret F., and Julve M. Cryst Eng Comm. 4 (2002) 522 and references therein
53. Hathaway J., and Billing D.E. Coord. Chem. Rev. 5 (1970) 143
54. Anderson P.W. J. Phys. Soc. Jpn. 9 (1954) 316
55. Fitting of the EPR spectra was done by software provided to us by Prof. M. Hendrich, Dept of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania, USA.