-
5
-
-
0035801679
-
-
a) H. J. Martin, M. Drescher, H. Kahlig, S. Schneider, J. Mulzer, Angew. Chem., Int. Ed. 2001, 40, 3186.
-
(2001)
Angew. Chem., Int. Ed
, vol.40
, pp. 3186
-
-
Martin, H.J.1
Drescher, M.2
Kahlig, H.3
Schneider, S.4
Mulzer, J.5
-
6
-
-
4544340564
-
-
b) M. P. Green, S. Pichlmair, M. M. B. Marques, H. J. Martin, O. Diwald, T. Berger, J. Mulzer, Org. Lett. 2004, 6, 3131.
-
(2004)
Org. Lett
, vol.6
, pp. 3131
-
-
Green, M.P.1
Pichlmair, S.2
Marques, M.M.B.3
Martin, H.J.4
Diwald, O.5
Berger, T.6
Mulzer, J.7
-
7
-
-
4344629172
-
-
c) J. Mulzer, S. Pichlmair, M. P. Green, M. M. B. Marques, H. J. Martin, Proc. Natl. Acad. Sci. U.S.A. 2004, 101, 11980.
-
(2004)
Proc. Natl. Acad. Sci. U.S.A
, vol.101
, pp. 11980
-
-
Mulzer, J.1
Pichlmair, S.2
Green, M.P.3
Marques, M.M.B.4
Martin, H.J.5
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13
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8844220443
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-
a) Y. Yuan, H. Men, C. Lee, J. Am. Chem. Soc. 2004, 126, 14720.
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 14720
-
-
Yuan, Y.1
Men, H.2
Lee, C.3
-
14
-
-
18744380352
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-
b) A. B. Smith, III, E. F. Mesaros, E. A. Meyer, J. Am. Chem. Soc. 2005, 127, 6948.
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 6948
-
-
Smith III, A.B.1
Mesaros, E.F.2
Meyer, E.A.3
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15
-
-
33646154015
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c) A. B. Smith, III, E. F. Mesaros, E. A. Meyer, J. Am. Chem. Soc. 2006, 128, 5292.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 5292
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Smith III, A.B.1
Mesaros, E.F.2
Meyer, E.A.3
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34347203852
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12: Rf, 0.41 (SiO2, hexane:EtOAc, 7:1, α]15D, 106° (c 0.53, CHCl3, IR (CHCl3) 2960, 2930, 2860, 1460, 1410, 1380, 1050, 840cm-1; 1HNMR (500 MHz, C6D6) δ 6.14 (d, J, 11.2 Hz, 1H, 5.11 (d, 7, 8.8 Hz, 1H, 4.20 (d, J, 17.1 Hz, 1H, 4.09 (d, J, 17.1 Hz, 1H, 3.80 (s, 3H, 3.79 (d, J, 11.7 Hz, 1H, 3.61 (s, 3H, 3.50 (dd, J, 6.8, 6.8 Hz, 1H, 3.45 (s, 3H, 3.38 (dd, J, 10.2, 4.9Hz, 1H, 3.21 (m, 1H, 2.69 (m, 1H, 2.39 (m, 1H, 2.28 (dd, J, 13.7, 11.7Hz, 1H, 2.22 (s, 3H, 1.97 (s, 3H, 1.94 (m, 1H, 1.71 (br. d, J, 14.7Hz, 1H, 1.60 (s, 3H, 1.58 (m, 2H, 1.52-1.47 (m, 2H, 1.32 (m, 2H, 1.27 (d, J, 6.8 Hz, 3H, 1.02 (s, 9H, 0.96 (d, J, 6.3 Hz, 3H, 0.93 (d, J, 6.8 Hz, 3H, 0.69 (d, J, 6.8 Hz, 1H, 0.17 (s, 3H, 0.12 (s, 3H, 13CNMR (151MHz, C6D6) δ 199.3, 154.1, 152.0, 150.1, 145.7, 138.2, 135.3, 134.2, 131.6, 129.5, 125.6, 82.1, 7
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+ 665.4213, found 665.4210.
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19
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34347222293
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Smith succeeded in isomerizing this Z-alkene to the E geometry via a multi-step procedure, leading to the completion of total synthesis
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Smith succeeded in isomerizing this Z-alkene to the E geometry via a multi-step procedure, leading to the completion of total synthesis.
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