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Volumn 46, Issue 12, 2007, Pages 4868-4875

A structural and theoretical investigation of equatorial cis and trans uranyl phosphinimine and uranyl phosphine oxide complexes UO2Cl 2(Cy3PNH)2 and UO2Cl 2(Cy3PO)2

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; ORGANOMETALLIC COMPOUND; PHOSPHINE DERIVATIVE; URANIUM;

EID: 34347203729     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic062031m     Document Type: Article
Times cited : (33)

References (33)
  • 14
    • 33845883717 scopus 로고    scopus 로고
    • Vrije Universiteit: Amsterdam, The Netherlands
    • ADF2004.01; SCM, Theoretical Chemistry, Vrije Universiteit: Amsterdam, The Netherlands, 2004. http://www.scm.com.
    • (2004) 01; SCM, Theoretical Chemistry
    • ADF1
  • 26
    • 34347248243 scopus 로고    scopus 로고
    • 31P NMR spectroscopy because of possible contamination of the instrument.
    • 31P NMR spectroscopy because of possible contamination of the instrument.
  • 32
    • 33750241454 scopus 로고    scopus 로고
    • We do not know why there should be such large differences between theory and experiment for just these bonds but note that our extensive previous experience suggests that the energy required to contract/ elongate bonds in the vicinity of their equilibrium value is typically very small, and, hence, it may well be that forces external to the molecules in the solid state cause the U-N and U-O bonds to adopt lengths slightly different from their ideal gas-phase values. See: Kaltsoyannis, N, Mountford, P. J. Chem. Soc, Dalton Trans. 1999, 781
    • We do not know why there should be such large differences between theory and experiment for just these bonds but note that our extensive previous experience suggests that the energy required to contract/ elongate bonds in the vicinity of their equilibrium value is typically very small, and, hence, it may well be that forces external to the molecules in the solid state cause the U-N and U-O bonds to adopt lengths slightly different from their ideal gas-phase values. See: Kaltsoyannis, N.; Mountford, P. J. Chem. Soc., Dalton Trans. 1999, 781.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.