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We do not know why there should be such large differences between theory and experiment for just these bonds but note that our extensive previous experience suggests that the energy required to contract/ elongate bonds in the vicinity of their equilibrium value is typically very small, and, hence, it may well be that forces external to the molecules in the solid state cause the U-N and U-O bonds to adopt lengths slightly different from their ideal gas-phase values. See: Kaltsoyannis, N, Mountford, P. J. Chem. Soc, Dalton Trans. 1999, 781
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We do not know why there should be such large differences between theory and experiment for just these bonds but note that our extensive previous experience suggests that the energy required to contract/ elongate bonds in the vicinity of their equilibrium value is typically very small, and, hence, it may well be that forces external to the molecules in the solid state cause the U-N and U-O bonds to adopt lengths slightly different from their ideal gas-phase values. See: Kaltsoyannis, N.; Mountford, P. J. Chem. Soc., Dalton Trans. 1999, 781.
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