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Volumn 129, Issue 24, 2007, Pages 7570-7577

Cocktails of Tb3+ and Eu3+ complexes: A general platform for the design of ratiometric optical probes

Author keywords

[No Author keywords available]

Indexed keywords

ENZYME ACTIVITY; LUMINESCENCE; MICROARRAYS; PHOTONS; SENSORS; STOICHIOMETRY;

EID: 34250893065     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja070867y     Document Type: Article
Times cited : (162)

References (63)
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    • 3+ complexes have been prepared as statistical mixtures, and energy transfer has been estimated to be efficient: Piguet, C.; Bünzli, J. -C. G. Chem. Soc. Rev. 1999, 28, 347-358.
    • 3+ complexes have been prepared as statistical mixtures, and energy transfer has been estimated to be efficient: Piguet, C.; Bünzli, J. -C. G. Chem. Soc. Rev. 1999, 28, 347-358.
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    • See Supporting Information for detailed synthetic procedures and characterization
    • See Supporting Information for detailed synthetic procedures and characterization.
  • 49
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    • While the acyclic DTPA chelate is not ideal for many applications due to its kinetic lability, it is more than sufficient for exploratory photophysical studies and was chosen in the interest of synthetic brevity
    • While the acyclic DTPA chelate is not ideal for many applications due to its kinetic lability, it is more than sufficient for exploratory photophysical studies and was chosen in the interest of synthetic brevity.
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    • The Tb/Eu emission ratio is defined as the integrated Tb luminescence divided by the integrated Eu luminescence; photophysical parameters for all compounds can be found in the Supporting Information
    • The Tb/Eu emission ratio is defined as the integrated Tb luminescence divided by the integrated Eu luminescence; photophysical parameters for all compounds can be found in the Supporting Information.
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    • See Supporting Information for the preparation of this compound
    • See Supporting Information for the preparation of this compound.
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    • See a recent review and references therein
    • See a recent review and references therein: Lutz, J.-F. Angew. Chem., Int. Ed. 2007, 46, 1018-1025.
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  • 53
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    • Although ester 19 does not sensitize Tb luminescence at all, residual ligand fluorescence occuring between 530 and 560 nm causes this number to be nonzero
    • Although ester 19 does not sensitize Tb luminescence at all, residual ligand fluorescence occuring between 530 and 560 nm causes this number to be nonzero.
  • 54
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    • See Supporting Information for further discussion of this point
    • Richardson, F. Chem. Rev. 1982, 82, 541-552. See Supporting Information for further discussion of this point.
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    • See Supporting Information for details of the HPLC experiment
    • See Supporting Information for details of the HPLC experiment.
  • 61
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    • This resistance to polarity-induced luminescence change is not a property of the cs124 chromophore; Tb:cs124 complexes exhibit polarity-dependent emission similar to that of 40bTb
    • This resistance to polarity-induced luminescence change is not a property of the cs124 chromophore; Tb:cs124 complexes exhibit polarity-dependent emission similar to that of 40bTb.


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