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Volumn 48, Issue 30, 2007, Pages 5269-5273

The development of highly selective approaches to sandwich-type heteroleptic double- and triple-decker lutetium(III) and europium(III) phthalocyanine complexes

Author keywords

Double decker complexes; Rare earth phthalocyanines; Selective synthesis; Triple decker complexes

Indexed keywords

EUROPIUM; LANTHANIDE; LUTETIUM; PHTHALOCYANINE DERIVATIVE;

EID: 34250877736     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.05.128     Document Type: Article
Times cited : (37)

References (30)
  • 1
    • 0000469270 scopus 로고    scopus 로고
    • Kadish K.M., Smith K.M., and Guilard R. (Eds), Academic Press, San Diego, USA
    • Buchler J.W., and Ng D.K.P. In: Kadish K.M., Smith K.M., and Guilard R. (Eds). The Porphyrin Handbook Vol. 3 (2000), Academic Press, San Diego, USA 245-294
    • (2000) The Porphyrin Handbook , vol.3 , pp. 245-294
    • Buchler, J.W.1    Ng, D.K.P.2
  • 2
    • 84940953078 scopus 로고    scopus 로고
    • Kadish K.M., Smith K.M., and Guilard R. (Eds), Academic Press, San Diego, USA
    • Weiss R., and Fischer J. In: Kadish K.M., Smith K.M., and Guilard R. (Eds). The Porphyrin Handbook Vol. 16 (2003), Academic Press, San Diego, USA 171-246
    • (2003) The Porphyrin Handbook , vol.16 , pp. 171-246
    • Weiss, R.1    Fischer, J.2
  • 27
    • 34250797747 scopus 로고    scopus 로고
    • note
    • 3, benzene as eluent) and UV-vis spectroscopy. The resulting solution was diluted with THF (25 mL), rinsed through a glass filter, and the solvent was removed under reduced pressure. The residue was washed with boiling 80% aqueous MeOH (3 × 50 mL), filtered, and dried in a vacuum desiccator. The resulting powder was dissolved in THF and chromatographed on a column (2.5 × 40 cm, Bio-Beads S-X1, THF as eluent), to afford a grey-greenish (for Ln = Eu), or green-colored (for Ln = Lu) fraction. To achieve the extra purity, preparative TLC on silica gel using benzene/hexane (2/1) as eluent was employed. The yields and spectral data for compounds 4 and 5 are given in Table 1.
  • 29
    • 34250859271 scopus 로고    scopus 로고
    • note
    • 3, benzene as eluent) and UV-vis spectroscopy. Work-up was performed in accordance with Ref. 16. The yields and spectral data for compounds 8 and 9 are given in Table 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.