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34250797747
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note
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3, benzene as eluent) and UV-vis spectroscopy. The resulting solution was diluted with THF (25 mL), rinsed through a glass filter, and the solvent was removed under reduced pressure. The residue was washed with boiling 80% aqueous MeOH (3 × 50 mL), filtered, and dried in a vacuum desiccator. The resulting powder was dissolved in THF and chromatographed on a column (2.5 × 40 cm, Bio-Beads S-X1, THF as eluent), to afford a grey-greenish (for Ln = Eu), or green-colored (for Ln = Lu) fraction. To achieve the extra purity, preparative TLC on silica gel using benzene/hexane (2/1) as eluent was employed. The yields and spectral data for compounds 4 and 5 are given in Table 1.
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34250859271
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note
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3, benzene as eluent) and UV-vis spectroscopy. Work-up was performed in accordance with Ref. 16. The yields and spectral data for compounds 8 and 9 are given in Table 1.
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