Enantioselective and diastereoselective separation of synthetic pyrethroid insecticides on a novel chiral stationary phase by high-performance liquid chromatography

Chirality

Volumn 19, Issue 7, 2007, Pages 574-580

  Tan, Xulin ^a   Hou, Shicong ^a   Wang, Min ^a  

^a CHINA AGRICULTURAL UNIVERSITY   (China)

Author keywords

Chiral HPLC; Chiral stationary phase; Enantioselective and diastereoselective separation; Pyrethroid insecticides

Indexed keywords

AMIDE; BENZENE DERIVATIVE; CIPERMETHRIN; CYFLUTHRIN; DICHLOROETHANE; FENVALERATE; HEXANE; INSECTICIDE; PROPANOL; PYRETHROID; SILICON DIOXIDE;

ARTICLE; CHEMICAL ANALYSIS; CHIRALITY; DIASTEREOISOMER; ENANTIOSELECTIVITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PRIORITY JOURNAL;

CHROMATOGRAPHY, HIGH PRESSURE LIQUID; INSECTICIDES; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; PYRETHRINS; STEREOISOMERISM;

EID: 34250876827     PISSN: 08990042     EISSN: 1520636X     Source Type: Journal    
DOI: 10.1002/chir.20423     Document Type: Article

References (14)

1. Chamberlain K, Matsuo N, Kaneko H, Khambay BPS. Pyrethroids. In: Kurihara N, Miyamoto J, editors. Chirality in agrochemicals. Chichester, UK: Wiley; 1998. p 9-84.
2. Bicker W, Lämmerhofer M, Lindner W. Direct high-performance liquid chromatographic method for enantioselective and diastereoselective determination of selected pyrethroic acids. J Chromatogr A 2004;1035:37-46.
3. Oi N, Kitahara H, Aoki F, Kisu N. Direct separation of carboxylic acid enantiomers by high-performance liquid chromatography with amide and urea derivatives bonded to silica gel as chiral stationary phases. J Chromatogr A 1995;689:195-201.
4. Chapman RA. Chiral-phase high-performance liquid chromatographic separation of enantiomers of pyrethroid insecticide esters derived from α-cyano-3-phenoxybenzyl alcohol. J Chromatogr 1983;258:175-182.
5. Cayley GR, Simpson BW. Separation of pyrethroid enantiomers by chiral high-performance liquid chromatography. J Chromatogr 1986; 356:123-134.
6. Lisseter SG, Hambling SG. Chiral high-performance liquid chromatography of synthetic pyrethroid insecticides. J Chromatogr 1991;539: 207-210.
7. Oi N, Kitahara H, Kira R. Enantiomer separation of pyrethroid insecticides by high-performance liquid chromatography with chiral stationary phases. J Chromatogr 1990;515:441-450.
8. Liu WP, Gan J, Qin SJ. Separation and aquatic toxicity of enantiomers of synthetic pyrethroid insecticides. Chirality 2005;17:S127-S133.
9. Malyshev OR, Vinogradov MG. Convenient synthesis of π-acceptor chiral stationary phases for high-performance liquid chromatography from halogen-substituted 3,5-dinitrobenzoylamides. J Chromatogr A 1999;859:143-151.
10. Gazic I, Kontrec D, Lesac A, Vinkovic V. The enantiomeric recognition of dihydropyrimidonic compounds by chiral selectors derived from 4- or 2-chloro-3,5-dinitrobenzoic acid. Tetrahedron: Asymmetry 2005;16:1175-1182.
11. Siret L, Tambute A, Caude M, Rosset R. (S)-thio-DNBTYR-A and (S)-thio-DNBTYR-E as chiral stationary phases for analytical and preparative purposes. Application to the enantiomeric resolution of alkyl N-arylsulphinamoyl esters. J Chromatogr 1990;498:67-79.
12. Caude M, Tambute A, Siret L. Chiral stationary phases derived from tyrosine. J Chromatogr 1991;550:357-382.
13. Liu WP, Gan J. Separation and analysis of diastereomers and enantiomers of cypermethrin and cyfluthrin by gas chromatography. J Agric Food Chem 2004;52:755-761.
14. Benny K. Liquid chromatographic determination of pyrethroids as active ingredients in pesticide formulations. J AOAC Int 1994;77:810-814.