Triplet reactivity and regio/stereoselectivity in the macrocyclization of diastereomeric ketoprofen-quencher conjugates via remote hydrogen abstractions

Journal of the American Chemical Society

Volumn 129, Issue 23, 2007, Pages 7407-7420

  Abad, Sergio ^a   Boscá, Francisco ^a   Domingo, Luis R ^b   Gil, Salvador ^b   Pischel, Uwe ^a   Miranda, Miguel A ^a  

^a CSIC   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RATE CONSTANTS; REGIOSELECTIVITY; SINGLE CRYSTALS; STEREOSELECTIVITY;

HYDROGEN TRANSFER; ISOPROPYLBENZENE RESIDUE; MACROCYCLIZATION;

AROMATIC COMPOUNDS;

CUMENE; HYDROGEN; KETOPROFEN; TETRAHYDROFURAN;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CHROMATOPHORE; CRYSTAL STRUCTURE; CYCLIZATION; DIASTEREOISOMER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUCLEAR OVERHAUSER EFFECT; PHOTOCHEMICAL QUENCHING; PHOTOLYSIS; PHOTOREACTIVITY; PROTON TRANSPORT; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 34250860197     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0712827     Document Type: Article

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