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Volumn , Issue 9, 2007, Pages 1225-1228

First structural characterization of silanedithiol and its application toward the synthesis of silanedithiolato complexes

Author keywords

Group 10 transition metal complexes; Silanedithiol; Silanedithiolato complexes; Silaneselenol; X ray crystallography

Indexed keywords

HYDROGEN BONDS; METAL COMPLEXES; SYNTHESIS (CHEMICAL); TRANSITION METALS;

EID: 34250744620     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200601226     Document Type: Article
Times cited : (16)

References (34)
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    • For reviews, see; a
    • For reviews, see; a) D. Coucouvanis, Acc. Chem. Res. 1991, 24, 1-8;
    • (1991) Acc. Chem. Res , vol.24 , pp. 1-8
    • Coucouvanis, D.1
  • 12
    • 85153176296 scopus 로고    scopus 로고
    • There are only few reports on dialkyl- or diarylsilanedithiols. Dimethylsilanedithiol has been characterized only by IR spectroscopy due to its extreme instability: G. Gattow, H. P. Dewald, Z. Anorg. Atlg. Chem. 1991, 604, 63-67.
    • There are only few reports on dialkyl- or diarylsilanedithiols. Dimethylsilanedithiol has been characterized only by IR spectroscopy due to its extreme instability: G. Gattow, H. P. Dewald, Z. Anorg. Atlg. Chem. 1991, 604, 63-67.
  • 13
    • 0035931521 scopus 로고    scopus 로고
    • As for diphenylsilanedithiol, only the boiling point has been reported
    • As for diphenylsilanedithiol, only the boiling point has been reported: Y. Cai, B. P. Roberts, Tetrahedron Lett. 2001, 42, 763-766.
    • (2001) Tetrahedron Lett , vol.42 , pp. 763-766
    • Cai, Y.1    Roberts, B.P.2
  • 14
    • 85153258470 scopus 로고
    • Syntheses and some reactions of several dialkoxysilanedithiols have been reported: A) W Wojnowski, M. Wojnowska
    • Syntheses and some reactions of several dialkoxysilanedithiols have been reported: a) W Wojnowski, M. Wojnowska, Z. Anorg. Allg. Chem. 1972, 389, 302-306;
    • (1972) Z. Anorg. Allg. Chem , vol.389 , pp. 302-306
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    • 5: N. Takeda, T. Tanabe, N. Tokitoh, Bull. Chem. Soc. Jpn. 2006, 79, 1573-1579.
    • 5: N. Takeda, T. Tanabe, N. Tokitoh, Bull. Chem. Soc. Jpn. 2006, 79, 1573-1579.
  • 28
    • 85153327032 scopus 로고    scopus 로고
    • Crystal data for 1: The intensity data were collected with a Rigaku/MSC Mercury CCD diffractometer with graphite-monochromated Mo-Kα radiation (λ, 0.71070 Å, The structures were solved by direct methods (SIR-97) and refined by full-matrix least-squares procedures on F2 for all reflections (SHELXL-97, Formula C36H72S2Si7, MW, 765.69; triclinic; space group P1, 2, a, 9.2535(4, b, 15.9925(5, c, 15.8055(7) Å; α, 82.9726(15, β, 81.7950(17, γ, 81.365(4)°; V, 2276.62(16) Å3; Z, 2; μ, 0.324 mm-1; D calcd, 1.117 g cm-3; 2θmax, 51.0°; T, 103(2) K; R1 [I>2σ (I, 0.0563; wR2 all data, 0.1350; GOF, 1.049 for 8315 reflections and 427 paramet
    • 2 (all data) = 0.1350; GOF = 1.049 for 8315 reflections and 427 parameters. CCDC-627421 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif. Crystal data for 3 and 7 are given in the Supporting Information. CCDC-627422 (3) and -627425 (7) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
  • 29
    • 85153265897 scopus 로고    scopus 로고
    • We have already reported the synthesis of the stable silanethione and silaneselone, Tbt(Tip)Si=Ch (Ch, S, Se; Tip, 2,4,6-triisopropylphenyl, They should be related compounds to compounds 1, 3, and 7, since the hydrolyzed products of the silanethione and silaneselone are Tbt(Tip)Si(OH)(SH) and Tbt(Tip)Si(OH)SeH, which have already been reported. For reviews on heavy ketones, see: R. Okazaki, N. Tokitoh, Acc. Chem. Res. 2000, 33, 625-630
    • We have already reported the synthesis of the stable silanethione and silaneselone, Tbt(Tip)Si=Ch (Ch = S, Se; Tip = 2,4,6-triisopropylphenyl). They should be related compounds to compounds 1, 3, and 7, since the hydrolyzed products of the silanethione and silaneselone are Tbt(Tip)Si(OH)(SH) and Tbt(Tip)Si(OH)(SeH), which have already been reported. For reviews on heavy ketones, see: R. Okazaki, N. Tokitoh, Acc. Chem. Res. 2000, 33, 625-630.
  • 31
    • 85153276079 scopus 로고    scopus 로고
    • -1(KBr): D. Sellmann, P. Lechner, F. Knoch, M. Moll, J. Am. Chem. Soc. 1992, 114, 922-930.
    • -1(KBr): D. Sellmann, P. Lechner, F. Knoch, M. Moll, J. Am. Chem. Soc. 1992, 114, 922-930.
  • 32
    • 85153273999 scopus 로고    scopus 로고
    • For the experimental procedure, spectral and crystal data for 9a, see the Supporting Information. CCDC-627423 (9a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
    • For the experimental procedure, spectral and crystal data for 9a, see the Supporting Information. CCDC-627423 (9a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
  • 33
    • 85153221389 scopus 로고    scopus 로고
    • Crystal data for 9b (9b·hexane, Formula C 78H114P2PtS2Si7, MW, 1569.47; triclinic; space group P1, 2, a, 13.7853(8, b, 16.8910(9, c, 21.0444(17) Å; a, 113.276(7, β, 102.504(4, γ, 92.842(3)°; V, 4344.4(5) Å3; Z, 2; μ, 1.833 mm-1; D calcd, 1.200 Mg/m3; 2θmax, 50.0°; T, 173(2) K; R1 [I>2σ (I, 0.0511; wR2 (all data, 0.1272; GOF, 1.078 for 15211 reflections and 870 parameters. CCDC-627424 (9b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via
    • 2 (all data) = 0.1272; GOF = 1.078 for 15211 reflections and 870 parameters. CCDC-627424 (9b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.