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T. Komuro, T. Matsuo, H. Kawaguchi, K. Tatsumi, Chem. Commun. 2002, 988-989.
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0001186789
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a) D. M. Giolando, T. B. Rauchfuss, G. M. Clark, Inorg. Chem. 1987, 26, 3080-3082;
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85153176296
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There are only few reports on dialkyl- or diarylsilanedithiols. Dimethylsilanedithiol has been characterized only by IR spectroscopy due to its extreme instability: G. Gattow, H. P. Dewald, Z. Anorg. Atlg. Chem. 1991, 604, 63-67.
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There are only few reports on dialkyl- or diarylsilanedithiols. Dimethylsilanedithiol has been characterized only by IR spectroscopy due to its extreme instability: G. Gattow, H. P. Dewald, Z. Anorg. Atlg. Chem. 1991, 604, 63-67.
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13
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0035931521
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As for diphenylsilanedithiol, only the boiling point has been reported
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As for diphenylsilanedithiol, only the boiling point has been reported: Y. Cai, B. P. Roberts, Tetrahedron Lett. 2001, 42, 763-766.
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85153258470
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Syntheses and some reactions of several dialkoxysilanedithiols have been reported: A) W Wojnowski, M. Wojnowska
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Syntheses and some reactions of several dialkoxysilanedithiols have been reported: a) W Wojnowski, M. Wojnowska, Z. Anorg. Allg. Chem. 1972, 389, 302-306;
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a) N. Tokitoh, M. Ito, R. Okazaki, Organometallics 1995, 14, 4460-4462;
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a) V. Jancik, Y. Peng, H. W. Roesky, J. Li, D. Neculai, A. M. Neculai, R. Herbst-Irmer, J. Am. Chem. Soc. 2003, 125, 1452-1453;
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b) V. Jancik, H. W. Roesky, D. Neculai, A. M. Neculai, R. Herbst-Irmer, Angew. Chem. Int. Ed. 2004, 43, 6192-6196.
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b) T. Matsumoto, Y. Nakaya, K. Tatsumi, Organometallics 2006, 25, 4835-4845.
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[6-8]
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[6-8]
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25
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0000119625
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a) N. Tokitoh, H. Suzuki, R. Okazaki, J. Am. Chem. Soc. 1993, 115, 10428-10429;
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b) H. Suzuki, N. Tokitoh, R. Okazaki, Bull. Chem. Soc. Jpn. 1995, 68, 2471-2481.
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5: N. Takeda, T. Tanabe, N. Tokitoh, Bull. Chem. Soc. Jpn. 2006, 79, 1573-1579.
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5: N. Takeda, T. Tanabe, N. Tokitoh, Bull. Chem. Soc. Jpn. 2006, 79, 1573-1579.
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85153327032
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Crystal data for 1: The intensity data were collected with a Rigaku/MSC Mercury CCD diffractometer with graphite-monochromated Mo-Kα radiation (λ, 0.71070 Å, The structures were solved by direct methods (SIR-97) and refined by full-matrix least-squares procedures on F2 for all reflections (SHELXL-97, Formula C36H72S2Si7, MW, 765.69; triclinic; space group P1, 2, a, 9.2535(4, b, 15.9925(5, c, 15.8055(7) Å; α, 82.9726(15, β, 81.7950(17, γ, 81.365(4)°; V, 2276.62(16) Å3; Z, 2; μ, 0.324 mm-1; D calcd, 1.117 g cm-3; 2θmax, 51.0°; T, 103(2) K; R1 [I>2σ (I, 0.0563; wR2 all data, 0.1350; GOF, 1.049 for 8315 reflections and 427 paramet
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2 (all data) = 0.1350; GOF = 1.049 for 8315 reflections and 427 parameters. CCDC-627421 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif. Crystal data for 3 and 7 are given in the Supporting Information. CCDC-627422 (3) and -627425 (7) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
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85153265897
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We have already reported the synthesis of the stable silanethione and silaneselone, Tbt(Tip)Si=Ch (Ch, S, Se; Tip, 2,4,6-triisopropylphenyl, They should be related compounds to compounds 1, 3, and 7, since the hydrolyzed products of the silanethione and silaneselone are Tbt(Tip)Si(OH)(SH) and Tbt(Tip)Si(OH)SeH, which have already been reported. For reviews on heavy ketones, see: R. Okazaki, N. Tokitoh, Acc. Chem. Res. 2000, 33, 625-630
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We have already reported the synthesis of the stable silanethione and silaneselone, Tbt(Tip)Si=Ch (Ch = S, Se; Tip = 2,4,6-triisopropylphenyl). They should be related compounds to compounds 1, 3, and 7, since the hydrolyzed products of the silanethione and silaneselone are Tbt(Tip)Si(OH)(SH) and Tbt(Tip)Si(OH)(SeH), which have already been reported. For reviews on heavy ketones, see: R. Okazaki, N. Tokitoh, Acc. Chem. Res. 2000, 33, 625-630.
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-1(KBr): D. Sellmann, P. Lechner, F. Knoch, M. Moll, J. Am. Chem. Soc. 1992, 114, 922-930.
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-1(KBr): D. Sellmann, P. Lechner, F. Knoch, M. Moll, J. Am. Chem. Soc. 1992, 114, 922-930.
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85153273999
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For the experimental procedure, spectral and crystal data for 9a, see the Supporting Information. CCDC-627423 (9a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
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For the experimental procedure, spectral and crystal data for 9a, see the Supporting Information. CCDC-627423 (9a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
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Crystal data for 9b (9b·hexane, Formula C 78H114P2PtS2Si7, MW, 1569.47; triclinic; space group P1, 2, a, 13.7853(8, b, 16.8910(9, c, 21.0444(17) Å; a, 113.276(7, β, 102.504(4, γ, 92.842(3)°; V, 4344.4(5) Å3; Z, 2; μ, 1.833 mm-1; D calcd, 1.200 Mg/m3; 2θmax, 50.0°; T, 173(2) K; R1 [I>2σ (I, 0.0511; wR2 (all data, 0.1272; GOF, 1.078 for 15211 reflections and 870 parameters. CCDC-627424 (9b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via
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2 (all data) = 0.1272; GOF = 1.078 for 15211 reflections and 870 parameters. CCDC-627424 (9b) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
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A. B. Pangborn, M. A. Giardello, R. H. Grubbs, R. K. Rosen, F. J. Timmers, Organometallics 1996, 15, 1518-1520.
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(1996)
Organometallics
, vol.15
, pp. 1518-1520
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Pangborn, A.B.1
Giardello, M.A.2
Grubbs, R.H.3
Rosen, R.K.4
Timmers, F.J.5
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