Micellization in aqueous solution of an ethylene oxide-propylene oxide triblock copolymer, investigated with 1H NMR spectroscopy, pulsed-field gradient NMR, and NMR relaxation

Journal of Colloid and Interface Science

Volumn 312, Issue 2, 2007, Pages 390-396

  Ma, Junhe ^a   Guo, Chen ^a   Tang, Yalin ^b   Xiang, Junfeng ^b   Chen, Shu ^a   Wang, Jing ^a   Liu, Huizhou ^a  

^a INSTITUTE OF PROCESS ENGINEERING   (China)

^b INSTITUTE OF CHEMISTRY   (China)

Author keywords

1H NMR; Diffusion NMR; Micellization; NMR relaxation; PEO PPO PEO triblock copolymer

Indexed keywords

CONCENTRATION-DEPENDENT AGGREGATION PROCESS; HALF-HEIGHT WIDTH; POLAR ENVIRONMENT; SPIN-LATTICE RELAXATION TIME;

CHEMICAL SHIFT; ENTHALPY; HYDROPHOBICITY; MATHEMATICAL MODELS; MICELLIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYPROPYLENE OXIDES; RELAXATION TIME; THERMODYNAMICS;

BLOCK COPOLYMERS;

COPOLYMER; DEUTERIUM OXIDE; ETHYLENE OXIDE; POLOXAMER; POLY(ETHYLENE OXIDE); POLY(PROPYLENE OXIDE); PROPYLENE OXIDE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION KINETICS; DIFFUSION; ENTHALPY; ENTROPY; HYDRODYNAMICS; HYDROPHOBICITY; MICELLIZATION; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; TEMPERATURE;

DEUTERIUM OXIDE; DIFFUSION; MAGNETIC RESONANCE SPECTROSCOPY; MICELLES; POLOXAMER; POLYETHYLENES; POLYPROPYLENES; THERMODYNAMICS; WATER;

EID: 34250731382     PISSN: 00219797     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcis.2007.03.013     Document Type: Article

References (42)

1. Alexandridis P., and Lindman B. Amphiphilic Block Copolymers: Self Assembly and Applications (1997), Elsevier, Amsterdam
2. Alexandridis P., and Hatton T.A. Colloids Surf. A 96 (1995) 1-46
3. Mortensen K. Colloids Surf. A 183 (2001) 277-292
4. Nakashima K., and Bahadur P. Adv. Colloid Interface Sci. 123-126 (2006) 75-96
5. Alexandridis P., and Holzwarth J.F. Curr. Opin. Colloid Interface Sci. 5 (2000) 312-313
6. Yang L., Alexandridis P., Steytler D.C., Kositza M., and Holzwarth J.F. Langmuir 16 (2000) 8555-8561
7. Hurter P.N., and Hatton T.A. Langmuir 8 (1992) 1291-1299
8. Guo C., Wang J., Liu H.Z., and Chen J.Y. Langmuir 15 (1999) 2703-2708
9. Su Y.L., Wang J., and Liu H.Z. Macromolecules 35 (2002) 6426-6431
10. Su Y.L., Wang J., and Liu H.Z. J. Phys. Chem. B 35 (2002) 6426-6431
11. Brown W., Schillen K., Almgren M., Hvidt S., and Bahadur P. J. Phys. Chem. 95 (1991) 1850-1858
12. Mortensen K., and Pedersen J.S. Macromolecules 26 (1993) 805-812
13. Su Y., Wang J., and Liu H. J. Phys. Chem. B 106 (2002) 11823-11828
14. Su Y.L., Wei H.Z., and Liu X.F. J. Colloid Interface Sci. 264 (2003) 526-531
15. Alexandridis P., Holzwarth J.F., and Hatton T.A. Macromolecules 27 (1994) 2414-2425
16. Söderman O., and Stilbs P. Prog. Nucl. Magn. Reson. Spectrosc. 26 (1994) 445-482
17. Luchetti L. Langmuir 16 (2000) 161-165
18. Popova M.V., Tchernyshev Y.S., and Michel D. Langmuir 20 (2004) 632-636
19. Lesemann M., Thirumoorthy K., Kim Y.J., Jonas J., and Paulaitis M.E. Langmuir 14 (1998) 5339-5341
20. Wanka G., Hoffmann H., and Ulbricht W. Macromolecules 27 (1994) 4145-4159
21. Nivaggioli T., Tsao B., Alexandridis P., and Hatton T.A. Langmuir 11 (1995) 119-126
22. Zeghal M., and Auvray L. Eur. Phys. J. E 14 (2004) 259-268
23. Fleischer G., Bloss P., and Hergeth W.-D. Colloid Polym. Sci. 271 (1993) 217-222
24. Momot K.I., Kuchel P.W., Chapman B.E., Deo P., and Whittaker D. Langmuir 19 (2003) 2088-2095
25. Momot K.I., and Kuchel P.W. Concepts Magn. Reson. 19A (2003) 51-64
26. Momot K.I., and Kuchel P.W. Concepts Magn. Reson. 28A (2006) 249-269
27. Lovino A., Mesa C.L., Capitani D., and Segre A.L. Colloid Polym. Sci. 281 (2003) 1136-1141
28. Podo P., Ray A., and Nemethy G. J. Am. Chem. Soc. 95 (1973) 6164-6171
29. Cau F., and Lacelle S. Macromolecules 29 (1996) 170-178
30. Wu D.H., Chen A.D., and Johnson C.S. J. Magn. Reson. Ser. A 115 (1995) 260-264
31. Ma J.H., Guo C., Tang Y.L., Wang J., Zheng L.L., Liang X.F., Chen S., and Liu H.Z. J. Colloid Interface Sci. 299 (2006) 953-961
32. Kjelander R., and Florin E. J. Chem. Soc. Faraday Trans. 1 77 (1981) 2053-2077
33. Friebolin H.P. Basic One- and Two-Dimensional NMR Spectroscopy (1991), VCH, New York
34. Waldeck A.R., Kuchel P.W., Lennon A.J., and Chapman B.E. Prog. Nucl. Magn. Reson. Spectrosc. 30 (1997) 39-68
35. Nolan S.L., Philips R.J., Cotts P.M., and Dungan S.R. J. Colloid Interface Sci. 191 (1997) 291-302
36. Zhou Z., and Chu B. J. Colloid Interface Sci. 126 (1988) 171-180
37. Mortensen K., and Pedersen J.S. Macromolecules 26 (1993) 805-812
38. Liu K.J., and Ullman R. J. Chem. Phys. 48 (1968) 1158-1168
39. Wang R.B., Knoll H., Rittig F., and Körger J. Langmuir 17 (2001) 7464-7467
40. Astafieva I., Zhong X.F., and Eisenberg A. Macromolecules 26 (1993) 7339-7352
41. Su Y.L., Wei X.F., and Liu H.Z. Langmuir 19 (2003) 1995-3000
42. Alexandridis P., Athanassiou V., and Hatton T.A. Langmuir 11 (1995) 2442-2450