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See the following for recent reviews: a) W. Zhang, J. S. Moore, Angew. Chem. Int. Ed. 2006, 45, 4416-4439;
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b) M. Venturi, F. Marchioni, B. F. Ribera, V. Balzani, D. M. Opris, A. D. Schlüter, ChemPhysChem 2006, 7, 229-239;
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II complexes of a shape-persistent macrocyclic ligand: Synthesis photophysical properties, and electrochemical characterization
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Ed, K. Gloe, Springer, Dordrecht
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II complexes of a shape-persistent macrocyclic ligand: Synthesis photophysical properties, and electrochemical characterization" in Macrocyclic Chemistry - Current Trends and Future Perspectives (Ed.: K. Gloe), Springer, Dordrecht, 2005, pp. 219-234.
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34250678983
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The present design of shape-persistent macrocycles carrying coumarins 2 and 343 towards molecular switch applications was developed jointly by Prof. M. Venturi and Prof. V. Balzani, Bologna, Italy.
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The present design of shape-persistent macrocycles carrying coumarins 2 and 343 towards molecular switch applications was developed jointly by Prof. M. Venturi and Prof. V. Balzani, Bologna, Italy.
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Two different terms are used in the literature for the Sonogashira reaction carried out in the absence of cuprous iodide, namely, the copper-free Sonogashira reaction and Heck alkynylation. For a comment on this matter, see T. Ljungdahl, K. Pettersson, B. Albinsson, J. Martensson, J. Org. Chem. 2006, 71, 1677-1687. We tend to agree with this comment but as the first name is used much more often in the literature we will use it here as well
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Two different terms are used in the literature for the Sonogashira reaction carried out in the absence of cuprous iodide, namely, the "copper-free" Sonogashira reaction and "Heck alkynylation." For a comment on this matter, see T. Ljungdahl, K. Pettersson, B. Albinsson, J. Martensson, J. Org. Chem. 2006, 71, 1677-1687. We tend to agree with this comment but as the first name is used much more often in the literature we will use it here as well.
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0347985383
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For negative effects of the presence of cuprous iodide, see
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For negative effects of the presence of cuprous iodide, see: D. Gelman, S. L. Buchwald, Angew. Chem. Int. Ed. 2003, 42, 5993-5996.
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Gelman, D.1
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34250649360
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We are confident that virtually all the low-molar-mass organic material is soluble and thus detected under the applied conditions except for the poorly soluble cyclic compound 3. There is some uncertainty as to whether all higher molar mass oligomers are actually detected this way
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We are confident that virtually all the low-molar-mass organic material is soluble and thus detected under the applied conditions except for the poorly soluble cyclic compound 3. There is some uncertainty as to whether all higher molar mass oligomers are actually detected this way.
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36
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22144481320
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For the few cases with higher yields see, for example:, Note that in cyclization reactions in which acetylenes are coupled under oxidative acetylene homocoupling conditions, the yields tend to be higher
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For the few cases with higher yields see, for example: K. Sugiura, Y. Takihara, M. Yamaguchi, J. Org. Chem. 2005, 70, 5698-5708. Note that in cyclization reactions in which acetylenes are coupled under oxidative acetylene homocoupling conditions, the yields tend to be higher.
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