New syntheses of retinal and its acyclic analog γ-retinal by an extended aldol reaction with a C6 building block that incorporates a C5 unit after decarboxylation. A formal route to lycopene and β-carotene

Helvetica Chimica Acta

Volumn 90, Issue 3, 2007, Pages 512-520

  Valla, Alain ^a   Valla, Benoist ^a   Le Guillou, Régis ^a   Cartier, Dominique ^a   Dufossé, Laurent ^b   Labia, Roger ^a  

^a INSTITUT DE CHIMIE DES SUBSTANCES NATURELLES   (France)

^b UNIVERSITÉ DE LA RÉUNION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALDOL REACTION; DECARBOXYLATION; LYCOPENE;

ALCOHOLS; CARBON; SYNTHESIS (CHEMICAL);

ALDEHYDES;

2 CYANO 3,7 DIMETHYL 9 (2,6,6 TRIMETHYLCYCLOHEX 1 EN 1 YL)NONA 2,4,6,8 TETRANOIC ACID; 2 CYANO 3,7,11 TRIMETHYLDODECA 2,4,6,10 TETRAENOIC ACID; 2 CYANO 3,7,11,15 TETRAMETHYLHEXADECA 2,4,6,8,10,14 HEXADIENOIC ACID; 3 METHYL 5 (2,6,6 TRIMETHYLCYCLOHEX 1 EN 1 YL)PENTA 2,4 DIENENITRILE; 3 METHYL 5 (2,6,6 TRIMETHYLCYCLOHEXA 1 EN 1 YL)PENTA 2,4 DIENAL; 3,7 DIMETHYL 9 (2,6,6 TRIMETHYLCYCLOHEX 1 EN 1 YL)NONA2,4,6,8 TETRAENAL; 3,7,11 TRIMETHYLDODECA 2,4,6,10 TETRAENAL; 3,7,11 TRIMETHYLDODECA 2,4,6,10 TETRAENENITRILE; BETA CAROTENE; BETA IONONE; GAMMA RETINAL; LYCOPENE; METHYL 2 CYANO 3 METHYLBUTANOATE; RETINAL; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DECARBOXYLATION; PRIORITY JOURNAL; SYNTHESIS;

EID: 34250634509     PISSN: 0018019X     EISSN: None     Source Type: Journal    
DOI: 10.1002/hlca.200790053     Document Type: Article

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