Decontamination of sulfur mustard on manganese oxide nanostructures

AIChE Journal

Volumn 53, Issue 6, 2007, Pages 1562-1567

  Prasad, G K ^a   Mahato, T H ^a   Singh, Beer ^a   Pandey, P ^a   Rao, A N ^a   Ganesan, K ^a   Vijayraghavan, R ^a  

^a DEFENCE RESEARCH AND DEVELOPMENT ESTABLISHMENT   (India)

Author keywords

Detoxification; Nanosheets and nanotubes; Nanostructures; Sulfur mustard

Indexed keywords

ADSORBENTS; DECONTAMINATION; DETOXIFICATION; HYDROLYSIS; NANOSTRUCTURES; OXIDATION;

MANGANESE OXIDE NANOSHEETS; REACTIVE SORBENTS; SULFUR MUSTARD;

SULFUR;

ADSORBENTS; DECONTAMINATION; DETOXIFICATION; HYDROLYSIS; NANOSTRUCTURES; OXIDATION; SULFUR;

BRASSICA;

EID: 34250221119     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.11182     Document Type: Article

References (25)

1. 3. Formation of aluminiumphosphates. J Am Chem Soc. 2001;123:1636-1644.
2. Yang Y-C, Baker JA, Ward JR. Decontamination of chemical warfare agents. Chem Rev. 1992;92:1729-1743.
3. Yang Y-C. Chemical reactions for neutralizing chemical warfare agents. Chem Ind. 1995;9:334-337.
4. Ekerdt JG, Klabunde KJ, Shapley JR, White JM, Yates JT. Surface chemistry of organophosphorous compounds. J Phys Chem. 1988;92:6182-6188.
5. 2 surfaces. Langmuir. 1999;15:4789-4795.
6. Wagner GW, Bartram PW, Koper O, Klabunde KJ. Reactions of VX, GD and HD with nanosize MgO. J Phys Chem B. 1999;103:3225-3228.
7. Wagner GW, Bartram PW. Interaction of VX, G and HD simulants with self decontaminating sorbents. A solid state NMR study. ERDEC-TR-375, Aberdeen Proving Ground, MD, 1996.
8. Stark JV, Park DG, Lagadic I, Klabunde KJ. Nanoscale metal oxide particle/clusters as chemical reagents. Unique surface chemistry on magnesium oxide as shown by enhanced adsorption of acid gases (sulfur oxide and carbon dioxide) and pressure dependence. Chem Mater. 1996;8:1904-1912.
9. Bartram PW, Wagner GW. Decontamination of chemical warfare agents using activated aluminium oxide. US Patent No. 5689038, Nov 18, 1997.
10. Klabunde KJ, Stark J, Koper O, Mohs C, Park DO, Decker S, Jiang Y Lagadic, Zhang D. Nanocrystals as stoichiometric reagents with unique surface chemistry. J Phys Chem. 1996;100:12142.
11. Sides GD, Mason DW, Seiders RP. Interaction of the agents HD, GD and VX with alumina. In Proceedings of the 1983 scientific conference on chemical defense research, CRDC-SP-84014; Aberdeed Proving Ground, MD, 1984:285-291.
12. 13C NMR study. J Mol Catal A: Chem. 1996;111:175-180.
13. 31P MAS NMR study of the hydrolysis of O,S-diethyl phenyl phosphonothioate on reactive sorbents. J Mol Catal A:Chem. 1995;99:175-181.
14. Wagner GW, Koper O, Lucas E, Decker S, Klabunde KJ. Reactions of VX, GD and HD with nanosize CaO: Autocatalytic dehydrohalogenation of HD. J Phys Chem B. 2000;104:5118-5123.
15. Ma R, Bando Y, Sasaki T. Directly rolling nanosheets into nanotubes. J Phys Chem. 2004;108:2115-2119.
16. Kasuga T, Hiramatsu M, Hoson A, Sekino T, Nihara K. Formation of titanium oxide nanotube. Langmuir. 1998;14:3160-3163.
17. Kasuga T, Hiramatsu M, Hoson A, Sekino T, Nihara K. Titanate nanotubes prepared by chemical processing. Adv Mater. 1999;11:1307.
18. Chen Q, Zhou W, Du G, Peng L-M. Titanate nanotubes made via single alkali treatment. Adv Mater. 2002;14:1208-1211.
19. Kleinhammes A, Wagner GW, Kulkarni H, Jia Y, Zhang Qi, Qin L-C, Wu Y. Decontamination of 2-chloroethyl ethyl sulfide using titanate nanoscrolls. Chem Phys Lett. 2005;411:81-85.
20. Franke S. Lehrbuch der Militarchemie, Vol. 1, Militarverlag der DDR, Berlin, 1977.
21. 4 for rechargeable lithium battery cathode. Electrochim Acta. 2000;46:31-37.
22. Hinshelwood CN. The Kinetics of Chemical Change. London: Oxford University Press, 1940:206-209.
23. Laidler KJ. Chemical Kinetics. New York: McGraw-Hill, 1950.
24. Maron SH, Prutton CF. Principles of Physical Chemistry, 4th ed. New Delhi, India: Amerind Publishing, 1972:548-592.
25. Yang YC, Szafraniec LL, Beaudry WT, Richard JW. Kinetics and mechanism of the hydrolysis of 2 chloro ethyl sulfides. J Org Chem. 1988;53:3293-3297.