Temperature dependence of acidity constants, a tool to affect separation selectivity in capillary electrophoresis

Journal of Chromatography A

Volumn 1155, Issue 2, 2007, Pages 142-145

  Reijenga, Jetse C ^a   Gagliardi, Leonardo G ^b   Kenndler, Ernst ^b  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b UNIVERSITY OF VIENNA   (Austria)

Author keywords

Acidity; Capillary electrophoresis; Degree of ionisation; Dissociation enthalpy; Effective mobility; Ionisation constant; pKa value; Temperature

Indexed keywords

CAPILLARY ELECTROPHORESIS; COMPLEXATION; IONIC STRENGTH; MIXTURES; SEPARATION;

DEGREE OF IONIZATION; DISSOCIATION ENTHALPY; EFFECTIVE MOBILITY; IONISATION CONSTANT;

ACIDITY;

AMINE; BUFFER; CARBOXYLIC ACID; ELECTROLYTE; INORGANIC ACID; PHENOL DERIVATIVE;

ACIDITY; ANALYTICAL PARAMETERS; ARTICLE; CAPILLARY ELECTROPHORESIS; COMPLEX FORMATION; ENTHALPY; EQUILIBRIUM CONSTANT; IONIC STRENGTH; IONIZATION; PH; PRIORITY JOURNAL; SEPARATION TECHNIQUE; TEMPERATURE DEPENDENCE; TEMPERATURE SENSITIVITY; THERMODYNAMICS;

BUFFERS; ELECTROPHORESIS, CAPILLARY; HYDROGEN-ION CONCENTRATION; OSMOLAR CONCENTRATION; TEMPERATURE;

EID: 34250213275     PISSN: 00219673     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chroma.2006.09.084     Document Type: Article

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