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note
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18: C, 42.00; H, 2.65; N, 36.77. Found: C, 41.87; H, 2.54; N, 37.02.
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26
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34249987497
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note
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2 with anisotropic thermal parameters for all non-hydrogen atoms using the SHELXTL-PC [G.M. Sheldrick, 2000. SHELXTL. Version 6.12. Bruker AXS Inc., Madison, Wisconsin, USA] software package. In compound 1, the H atoms attached to C13 and C28 were located in a difference Fourier map and were refined with a DFIX restraint of C-H = 0.92 (1) Å. The other H atoms were placed in idealized positions and constrained to ride on their parent atoms, with C-H distances in the range of 0.93-0.96 Å and N-H distance of 0.86 Å. The N12 of the azido group found to be disordered; the occupancies of the disordered positions were initially refined and later fixed at 0.5 and 0.5. In compound 2, the H atom attached to the N atom of amide was located in a difference Fourier map and was refined with a DFIX restraint of N-H = 0.87 (1) Å. The other H atoms were placed in idealized positions and constrained to ride on their parent atoms, with C-H distances of 0.93 Å. The molecular graphics were created by using SHELXTL-PC.
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