메뉴 건너뛰기




Volumn 10, Issue 7, 2007, Pages 843-848

Copper(II) azide complexes of [Cu(acac)(N3)(dpyam)] and [Cu(μ-N3-κN1)(C2N3- κN1)(dpyam)]2: Synthesis, crystal structure and magnetism

Author keywords

Azide bridges; Copper(II); Crystal structure; Di 2 pyridylamine; Dicyanamide; Magnetism

Indexed keywords


EID: 34250000855     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.03.033     Document Type: Article
Times cited : (23)

References (37)
  • 25
    • 34250020067 scopus 로고    scopus 로고
    • note
    • 18: C, 42.00; H, 2.65; N, 36.77. Found: C, 41.87; H, 2.54; N, 37.02.
  • 26
    • 34249987497 scopus 로고    scopus 로고
    • note
    • 2 with anisotropic thermal parameters for all non-hydrogen atoms using the SHELXTL-PC [G.M. Sheldrick, 2000. SHELXTL. Version 6.12. Bruker AXS Inc., Madison, Wisconsin, USA] software package. In compound 1, the H atoms attached to C13 and C28 were located in a difference Fourier map and were refined with a DFIX restraint of C-H = 0.92 (1) Å. The other H atoms were placed in idealized positions and constrained to ride on their parent atoms, with C-H distances in the range of 0.93-0.96 Å and N-H distance of 0.86 Å. The N12 of the azido group found to be disordered; the occupancies of the disordered positions were initially refined and later fixed at 0.5 and 0.5. In compound 2, the H atom attached to the N atom of amide was located in a difference Fourier map and was refined with a DFIX restraint of N-H = 0.87 (1) Å. The other H atoms were placed in idealized positions and constrained to ride on their parent atoms, with C-H distances of 0.93 Å. The molecular graphics were created by using SHELXTL-PC.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.