Direct polymerization of isoprene and α-pinene on acidic aerosols

Geophysical Research Letters

Volumn 34, Issue 5, 2007, Pages

  Liggio, John ^a   Li, Shao Meng ^a   Brook, Jeffrey R ^a   Mihele, Cristian ^a  

^a ENVIRONMENT CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC HUMIDITY; CATALYSIS; MASS SPECTROMETRY; OXYGENATION; POLYMERIZATION; POLYMERS;

ACIDIC SULFATE AEROSOLS; ISOPRENE; PARTITION COEFFICIENTS;

ATMOSPHERIC AEROSOLS;

ACIDITY; AEROSOL; CHEMICAL COMPOSITION; HYDROPHOBICITY; ISOPRENE; MASS SPECTROMETRY; OXYGENATION; PARTITION COEFFICIENT; POLYMER; POLYMERIZATION; RELATIVE HUMIDITY;

EID: 34249866575     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2006GL028468     Document Type: Article

References (21)

1. Boge, O., Y. Miao, A. Plewka, and H. Herrmann (2006), Formation of secondary organic particle phase compounds from isoprene gas-phase oxidation products: An aerosol chamber and field study, Atmos. Environ., 40, 2501-2509.
2. Chandramouli, B., M. Jang, and M. Kamens Richard (2003), Gas-particle partitioning of semivolatile organic compounds (SOCs) on mixtures of aerosols in a smog chamber, Environ. Sci. Technol., 37, 4113-4121.
3. Claeys, M., et al. (2004), Formation of secondary organic aerosols through photooxidation of isoprene, Science, 303, 1173-1176.
4. 2O at 298.15 K, J. Phys. Chem. A, 102, 2155-2171.
5. Drewnick, F., S. S. Hings, P. F. DeCarlo, J. T. Jayne, M. Gonin, K. Fuhrer, S. Weimer, J. L. Jimenez, K. L. Demerjian, S. Borrmann, and D. R. Worsnop (2005), A new Time-of-Flight Aerosol Mass Spectrometer (ToF-AMS)-Instrument description and first field deployment, Aerosol Sci. Technol., 39, 637-658.
6. Ferek, R. J., A. L. Lazrus, P. L. Haagenson, and J. W. Winchester (1983), Strong and weak acidity of aerosols collected over the northeastern United States, Environ. Sci. Technol., 17, 315-324.
7. Ganor, E. (1999), A method for identifying sulfuric acid in single cloud and fog droplets, Atmos. Environ., 33, 4235-4242.
8. Harrison, D., et al. (2001), Ambient isoprene and monoterpene concentrations in a Greek fir (Abies Borisii-regis) forest. Reconciliation with emissions measurements and effects on measured OH concentrations, Atmos. Environ., 35, 4699-4711.
9. Heald, C. L., D. J. Jacob, R. J. Park, L. M. Russell, B. J. Huebert, J. H. Seinfeld, H. Liao, and R. J. Weber (2005), A large organic aerosol source in the free troposphere missing from current models, Geophys. Res. Lett., 32, L18809, doi:10.1029/2005GL023831.
10. Hindman, E. E., R. D. Borys, D. H. Lowenthal, and N. Phillip (2006), Long-term, wintertime aerosol, cloud and precipitation measurements in the northern Colorado Rocky Mountains, USA, Atmos. Res., 82, 194-202.
11. Jimenez, J. L., et al. (2003), Ambient aerosol sampling using the Aerodyne Aerosol Mass Spectrometer, J. Geophys. Res., 108(D7), 8425, doi:10.1029/2001JD001213.
12. Kroll, J. H., N. L. Ng, S. M. Murphy, V. Varutbangkul, R. C. Flagan, and J. H. Seinfeld (2005), Chamber studies of secondary organic aerosol growth by reactive uptake of simple carbonyl compounds, J. Geophys. Res., 110, D23207, doi:10.1029/2005JD006004.
13. Kroll, J. H., N. L. Ng, S. M. Murphy, R. C. Flagan, and J. H. Seinfeld (2006), Secondary organic aerosol formation from isoprene photooxidation, Environ. Sci. Technol., 40, 1869-1877.
14. Li, S.-M., A. M. Macdonald, J. W. Strapp, Y.-N. Lee, and X.-L. Zhou (1997), Chemical and physical characterization of atmospheric aerosols over southern California, J. Geophys. Res., 102(D17), 21,341-21,353.
15. Liggio, J., and S.-M. Li (2006), Reactive uptake of pinonaldehyde on acidic aerosols, J. Geophys. Res., 111, D24303, doi:10.1029/ 2005JD006978.
16. Limbeck, A., M. Kulmala, and H. Puxbaum (2003), Secondary organic aerosol formation in the atmosphere via heterogeneous reaction of gaseous isoprene on acidic particles, Geophys. Res. Lett., 30(19), 1996, doi:10.1029/2003GL017738.
17. Manas, C. (2006), Introduction to Polymer Science and Chemistry: A Problem Solving Approach, pp. 10-11, CRC Press, Boca Raton, Fla.
18. Odian, G. G. (2004), Principles of Polymerization, pp. 409-409, John Wiley, Hoboken, N. J.
19. Pankow, J. F. (1994), An absorption model of gas/particle partitioning of organic compounds in the atmosphere, Atmos. Environ., 28, 185-188.
20. Steinbacher, M., J. Dommen, C. Ammann, C. Spirig, A. Neftel, and A. S. H. Prevot (2004), Performance characteristics of a proton-transfer-reaction mass spectrometer (PTR-MS) derived from laboratory and field measurement, Int. J. Mass Spectrom., 239, 117-128.
21. Wade, L. G. (2003), Organic Chemistry, Prentice-Hall, Upper Saddle River, N. J.