Chemical composition, statistical analysis of the unit cell, and electrostatic modeling of the structure of Al-saturated chlorite from metamorphosed rocks

American Mineralogist

Volumn 92, Issue 5-6, 2007, Pages 954-965

  Lee, Sang Soo ^a   Guggenheim, Stephen ^a   Dyar, M Darby ^b   Guidotti, Charles V ^c  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

^b MOUNT HOLYOKE COLLEGE   (United States)

^c UNIVERSITY OF MAINE   (United States)

Author keywords

Al saturated chlorite; Electrostatic modeling; Gandolfi powder pattern simulations; Layer charge; Mg,Fe effects on chlorite unit cell; M ssbauer spectroscopy

Indexed keywords

ALUMINUM; ALUMINUM ALLOYS; BINARY ALLOYS; CELLS; CHLORINE COMPOUNDS; CYTOLOGY; DIFFRACTION; DIFFRACTOMETERS; ELECTRON PROBE MICROANALYSIS; ELECTROSTATICS; IRON ALLOYS; IRON METALLOGRAPHY; MAGNESIUM ALLOYS; MAGNESIUM METALLOGRAPHY; MOLYBDENUM METALLOGRAPHY; SINGLE CRYSTALS;

ELECTROSTATIC MODELING; FE EFFECTS; LAYER CHARGE; POWDER PATTERNS; SSBAUER SPECTROSCOPIES;

ALUMINUM METALLOGRAPHY;

CHEMICAL COMPOSITION; CHLORITE; CRYSTAL STRUCTURE; ELECTRON PROBE ANALYSIS; METAMORPHIC ROCK; MODELING; MOSSBAUER SPECTROSCOPY; STATISTICAL ANALYSIS;

EID: 34249852536     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2007.2309     Document Type: Article

References (46)

1. Bailey, S.W. (1972) Determination of chlorite composition by X-ray spacings and intensities. Clays and Clay Minerals, 20, 381-388.
2. Bailey, S.W. (1988) Chlorites: Structure and crystal chemistry. In S.W. Bailey, Ed., Hydrous Phyllosilicates, 19, p. 347-403. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
3. Bailey, S.W. and Brown, B.E. (1962) Chlorite structural variations. Special Paper, Geological Society of America, pp. 130.
4. 2O assemblages. American Mineralogist, 81, 676-684.
5. Brigatti, M.F. and Casari, L. (1988) Chlorites from cobalt pyrite horizons, Upper Martelle Valley (Alto Adige, northern Italy). Neues Jahrbuch für Mineralogie Monatshefte, 1988, 547-558.
6. Brown, I.D. (1978) Bond valences. A simple structural model for inorganic chemistry. Chemical Society Reviews, 7, 359-376.
7. Brown, I.D. and Altermatt, D. (1985) Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database. Acta Crystallographica, Section B: Structural Science, 41, 244-247.
8. Crowley, M.S. and Roy, R. (1964) Crystalline solubility in the muscovite and phlogopite groups. American Mineralogist, 49, 348-362.
9. Dyar, M.D., Guidotti, C.V., Harper, G.D., McKibben, M.A., and Saccocia, P.J. (1992) Controls on ferric iron in chlorite. Geological Society of America Abstracts with Programs, 1992 Annual Meeting, 338 p.
10. Dyar, M.D., Agresti, D.G., Schaefer, M., Grant, C.A., and Sklute, E.C. (2006) Mössbauer spectroscopy of earth and planetary materials. Annual Reviews of Earth and Planetary Science, 34, 83-125.
11. Eggleton, R.A. and Bailey, S.W. (1967) Structural aspects of dioctahedral chlorite. American Mineralogist, 52, 673-689.
12. Foster, M.D. (1962) Interpretation of the composition and a classification of the chlorites. U.S. Geological Survey Professional Paper Report: P414-A, 1-15.
13. Guggenheim, S. (1984) The brittle micas. In S.W. Bailey, Ed., Micas, 13, p. 61-104. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
14. Guggenheim, S. (2005) Simulations of Debye-Scherrer and Gandolfi patterns using a Bruker SMART/APEX Diffractometer System. Broker AXS Application Note 373, 8p. Madison, Wisconsin; see also American Crystallographic Annual Meeting, Chicago, Illinois, July 2004, abstract, 182 p.
15. Guidotti, C.V. (1974) Transition from staurolite to sillimanite zone, Rangeley Quadrangle, Maine. Geological Society of America Bulletin, 85, 475-490.
16. Guidotti, C.V., Teichmann, F., and Henry, D.J. (1991) Chlorite-bearing polymetamorphic metapelites in the Rangely area, Maine: evidence for equilibrium assemblages. American Mineralogist, 76, 867-879.
17. 29Si NMR spectroscopy. Journal of Physics C: Solid State Physics, 18, 13-22.
18. Herrero, C.P., Sanz, J., and Serratosa, J.M. (1986) The electrostatic energy of micas as a function of Si, Al tetrahedral ordering. Journal of Physics C: Solid State Physics, 19, 4169-4181.
19. Hewitt, D.A. and Wones, D.R. (1975) Physical properties of some synthetic Fe-Mg-Al trioctahedral biotites. American Mineralogist, 60, 854-862.
20. Jenkins, D.M. and Chernosky, J.V., Jr. (1986) Phase equilibria and crystallochemical properties of Mg-chlorite. American Mineralogist, 71, 924-936.
21. Kepezhinskas, K.B. (1965) Composition of chlorites as determined from their physical properties. Doklady Akad Nauk. S.S.S.R., Earth Science Section, 164, 126-129.
22. Laird, J. (1988) Chlorites: metamorphic petrology. In S.W. Bailey, Ed., Hydrous Phyllosilicates, 19, p. 405-453. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
23. Likhanov, I.I. (1988a) Chloritoid, staurolite and gedrite of the high-alumina hornfelses of the Karatash pluton. International Geology Review, 30, 868-877.
24. Likhanov, I.I. (1988b) Evolution of chemical composition of metapelite minerals during low-grade contact metamorphism. International Geology Review, 30, 878-887.
25. Loewenstein, W. (1954) The distribution of aluminum in the tetrahedra of silicates and aluminates. American Mineralogist, 39, 92-96.
26. Long, G.J., Cranshaw, T.E., and Longworth, G. (1983) The ideal Mössbauer effect absorber thicknesses. Mössbauer Effect Reference Data Journal, 6, 42-49.
27. Lougear, A., Grodzicki, M., Bertoldi, C., Trautwein, A.X., Steiner, K., and Amthauer, G. (2000) Mössbauer and molecular orbital study of chlorites. Physics and Chemistry of Minerals, 27, 258-269.
28. MathWorks (1996) Matlab: The language of technical computing version 5. 86 p. MathWorks, Inc., Natick, Massachusetts.
29. Nelson, D.O. and Guggenheim, S. (1993) Inferred limitations to the oxidation of Fe in chlorite: a high temperature single-crystal X-ray study. American Mineralogist, 78, 1197-1207.
30. Pawley, A.R., Clark, S.M., and Chinnery, N.J. (2002) Equation of state measurements of chlorite, pyrophyllite, and talc. American Mineralogist, 87, 1172-1182.
31. 3+ coordination in chlorites: a structural study of ten chromium chlorites. American Mineralogist, 65, 112-122.
32. Rancourt, D.G. and Ping, J.Y. (1991) Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mössbauer spectroscopy. Nuclear Instruments & Methods in Physics Research Section B - Beam Interactions with Materials and Atoms, 58, 85-97.
33. 2+ quadrupole splitting distributions from Mössbauer spectroscopy along the (OH,F)-annite join. Physics and Chemistry of Minerals, 23, 63-71.
34. 1 for chlorite. American Mineralogist, 76, 1373-1379.
35. Roots, M. (1994) Molar volumes on the clinochlore-amesite binary: some new data. European Journal of Mineralogy, 6, 279-283.
36. Rule, A. C. and Bailey, S. W. (1987) Refinement of the crystal structure of a monoclinic ferroan clinochlore. Clay and Clay Minerals, 35, 129-138.
37. Rumble, D. (1971) Fe-Ti oxide minerals and the behavior of oxygen during regional metamorphism. Year Book, Carnegie Institution of Washington, 70, 157-165.
38. Rumble, D. (1978) Mineralogy, petrology, and oxygen isotope geochemistry of the Clough Formation, Black Mountain, Western New Hampshire. Journal of Petrology, 19, 317-340.
39. Rumble, D., Ferry, J.M., Spear, F.S., and Chamberlain, C.P. (1993) Petrologic and isotopic studies in metamorphic rocks of Eastern Vermont and Western New Hampshire. In J.T. Cheney and J.B. Brady, Eds., Guidebook, Field Trip for the Northeastern U.S., D-1-D-33. Geological Society of America, Washington, D.C.
40. Shirozu, H. (1958) X-ray powder patterns and cell dimensions of some chlorites in Japan, with a note on their interference colors. Journal of Mineralogy (Japan), 2, 209-223.
41. Shirozu, H. and Higashi, S. (1976) Structural investigations of sudoite and regularly interstratified sericite/sudoite. Mineralogical Journal (of Japan), 8, 158-170.
42. Swan, A.R.H. and Sandilands, M. (1995) Introduction to Geological Data Analysis. 446 p. Blackwell Science Inc., Malden, Massachusetts.
43. Systat (1999) Systat 9: Getting Started, 188 p. Systat Software, Inc., Chicago, Illinois.
44. Takéuchi, Y. and Sadanaga, R. (1966) Structural studies of brittle micas. (I) the structure of xanthophyllite refined. Mineralogical Journal, 4, 424-437.
45. Welch, M.D., Barras, J., and Klinowski, J. (1995) A multinuclear NMR study of clinochlore. American Mineralogist, 80, 441-447.
46. Wivel, C. and Mørup, S. (1981) Improved computational procedure for evaluation of overlapping hyperfine parameter distributions in Mössbauer spectra. Journal of Physics E: Scientific Instruments, 14, 605-610.