Static dielectric constants of acetonitrile/water mixtures at different temperatures and debye-hückel A and a0B parameters for activity coefficients

Journal of Chemical and Engineering Data

Volumn 52, Issue 3, 2007, Pages 1103-1107

  Gagliardi, Leonardo G ^a   Castells, Cecilia B ^b   Ràfols, Clara ^a   Rosés, Martí ^a   Bosch, Elisabeth ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

^b UNIVERSIDAD NACIONAL DE LA PLATA   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; ACTIVITY COEFFICIENTS; DENSITY MEASUREMENT (SPECIFIC GRAVITY); PERMITTIVITY; PH EFFECTS; THERMAL EFFECTS; WATER;

ACIDITY CONSTANTS; IONIC EQUILIBRIA; STATIC DIELECTRIC CONSTANTS;

BINARY MIXTURES;

EID: 34249801241     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je700055p     Document Type: Article

References (39)

1. CRC Handbook of Chemistry and Physics, 82 ed.; CRC Press: Boca Raton, FL, 2001-2002.
2. Riddick, J. A.; Hunger, W. B.; Sakano, T. K. Organic Solvents. Physical Properties and Methods of Purification, 4th ed.; John Wiley & Sons: New York, 1986.
3. Moreau, C.; Douhéret, G. Thermodynamic and Physical Behaviour of Acetonitrile + Water Mixtures. J. Chem. Thermodyn. 1976, 8, 403-410.
4. Mussini, T.; Longhi, P.; Rondinini, S.; Covington, A. K. Reference Values Standard for pH Measurements in 5, 15, and 30% (w/w) Acetonitrile/Water Solvent Mixtures at Temperatures from 288.15 to 308.15 K. Anal. Chim. Acta 1985, 174, 331-337.
5. Rondinini, S.; Nesse, A. Standard pH Values for Potassium Hydrogen Phtalate Reference Buffer Solutions in Acetonitrile-Water Mixtures up to 70 wt % at Various Temperatures. Electrochim. Acta 1987, 32, 1499-1505.
6. Bates, R. O. Determination of pH. Theory and Practice, 2nd ed.; John Wiley & Sons: New York, 1973.
7. Lengyel, T.; Inczedy, J.; Ure, A. M. Compendium of Analytical Nomenclature. Definitive Rules 1997, 3rd ed.; IUPAC: Oxford, 1997.
8. Buck, R. P.; Rondinini, S.; Covington, A. K.; Baucke, F. G. K.; Brett, C. M. A.; Camoes, M. F.; Milton, M. J. T.; Mussini, T.; Naumann, R.; Pratt, K. W.; Spitzer, P.; Wilson, G. S. Measurement of pH. Definition, Standards, and Procedures (IUPAC Recommendations 2002). Pure Appl. Chem. 2003, 74, 2169-2200.
9. Malmberg, C. G.; Maryott, A. A. Dielectric constant of water from 0° to 100°. J. Res. Natl. Bur. Stand. 1956, 56, 1-8.
10. Owen, B. B.; Miller, R. C.; Milner, C. E.; Cogan, H. L. The dielectric constant of water as a function of temperature and pressure. J. Phys. Chem. 1961, 65, 2065-2070.
11. Cunningham, G. P.; Vidulich, G. A.; Kay, R. L. Several properties of acetonitrile-water, acetonitrile-methanol, and ethylene carbonate-water systems. J. Chem. Eng. Data 1967, 12, 336-337.
12. D'Aprano, A.; Fuoss, R. M. Electrolyte-solvent interactions. XX. Picric acid in mixtures of acetonitrile and basic solvents. J. Phys. Chem. 1969, 73, 400-406.
13. Moreau, C.; Douhéret, G. Thermodynamic Behaviour of Water-Acetonitrile Mixtures. Excess Volume and Viscosities. Thermochim. Acta 1975, 13, 385-392.
14. Akima, H. A Method of Bivariate Interpolation and Smooth Surface Fitting for Irregularly Distributed Data Points. ACM Trans. Math. Software 1978, 4, 148-159.
15. Akima, H. Algorithm 526. ACM Trans. Math. Software 1978, 4, 160-164.
16. Preusser, A. Computing contours by successive solution of quintic polynomial equations. ACM Trans. Math. Software 1984, 10, 462-472.
17. Akima, H. Algorithm 761: Scattered-Data Surface Fitting that Has the Accuracy of a Cubic Polynomial. ACM Trans. Math. Software 1996, 22, 362-371.
18. Renka, R. J.; Brown, R. Remark on Algorithm 761. ACM Trans. Math. Software 1998, 24, 383-385.
19. Marquardt, D. W. An Algorithm for Least Squares Estimation Properties. J. Soc. Ind. Appl. Math. 1969, 11, 431-441.
20. Marsh, K. N. International Union of Pure and Applied Chemistry: Recomended Reference Materials for the Realization of Physlcochemical 'Properties; Blackwell Scientific Publications: Oxford, UK, 1987.
21. Handa, Y. P.; Benson, G. C. Thermodynamics of Aqueous Mixtures of Nonelectrolytes. VI. Excess Volumes of Water-Acetonitrile Mixtures from 15 to 35 °C. J. Solution Chem. 1981, 10, 291-300.
22. Wode, H.; Seidel, W. Precise Viscosity Measurements of Binary Liquid Mixtures of Acetonitrile- Water and 1,3-Dimethyl-2-imidazolidinone-Water. Ber. Bunsen-Ges. Phys. Chem. 1994, 98, 927-934.
23. Srinivasan, K. R.; Kay, R. L. The Pressure Dependence of Dielectric Constant and Density of Acetonitrile at Three Temperatures. J. Solution Chem 1977, 6, 357-367.
24. Barthel, J. B. K.; Buchner, R.; Gill, J. B.; Kleebauer, M. Dielectric spectra of some common solvents in the microwave region. Dipolar aprotic solvents and amides. Chem. Phys. Lett. 1990, 167, 62-66.
25. Helambe, S. N.; Lokhande, M. P.; Kumbharkhane, A. C.; Mehrotra, S. C.; Doraiswamy, S. Dielectric study of aqueous solution of acetonitriles. Pramana 1995, 44, 405-410.
26. Jellema, R.; Bulthuis, J.; Zwan, Gvd. Dielectric Relaxation of Acetonitrile-Water Mixtures. J. Mol. Liq. 1997, 73-74, 179-193.
27. Niazi, M. S. K.; Ali, J. Solvent Effect on the Dissociation of Benzoic and Nitrobenzoic Acids in Acetonitrile-Water Mixtures at 298°C. Bull. Chem. Soc. Jpn. 1990, 63, 3619-3624.
28. Helambe, S. N.; Chaudhari, A.; Mehrotra, S. C. Temperature-dependent dielectric study of n-nitriles in methanol using time-domain reflectometry. J. Mol. Liq. 2000, 84, 235-244.
29. Decroocq, D. La constante Diélecrique Statique des Mélanges Liquides. Bull. Soc. Chim. Fr. 1964, 1, 127-136.
30. Ohtmer, D. F.; Josefowitz, S. Composition of vapors from boiling binary solutions. Ind. Eng. Chem. 1947, 39, 1175-1177.
31. Mato, P.; Hernández, J. L. Viscosidad de Mezclas Líquidas Binarias II. Anal. Quim. 1969, 65, 9-18.
32. Grant-Taylor, D. F.; Macdonald, D. D. Thermal Pressure and Energy-Volume Coefficients for the Acetonitrile + Water System. Can. J. Chem 1976, 54, 2813-2819.
33. Rondinini, S.; Confalonieri, C.; Longhi, P.; Mussini, T. Standard Electromotive Force of the Silver Chloride-Quinhydrone Cell in Acetonitrile-Water Solvent Mixtures at Various Temperatures. Electrochim. Acta 1985, 30, 981-983.
34. Sakurai, M. Partial molar volumes for acetonitrile + water. J, Chem. Eng. Data 1992, 37, 358-362.
35. Van Meurs, N.; Somsen, G. Excess and Apparent Molar Volumes of Mixtures of Water and Acetonitrile between 0 and 25°C. J. Solution Chem. 1993, 22, 427-436.
36. Aminavhavi, T. M.; Gopalakrishna, B. Density, viscosity, refractive index, and speed of sound in aqueous mixtures of N,N-dimethylformamide, dimethyl sulfoxide, N,N-dimethylacetamide, acetonitrile, ethylene glycol, diethylene glycol, 1,4-dioxane, tetrahydrofuran, 2-methoxyethanol, and 2-ethoxyethanol at 298.15 K. J. Chem. Eng. Data 1995, 40, 856-861.
37. Hickey, K.; Waghorne, W. E. Viscosities and volumes of diulte solutions of formamide in water + acetonitrile and for formamide and N,N-dimethylformamide in methanol + aceotnitrile mixed solvents: viscosity B-coefficients, activation free energies for viscous flow, and partial molar volumes. J. Chem. Eng. Data 2001, 46, 851-857.
38. Kienitz, H.; Marsh, K. N. Recommended reference materials for realization of physicochemical properties. Pure Appl. Chem. 1981, 53, 1847-1862.
39. Ellison, W. J.; Lamkauchi, K.; Moreau, J.-M. Water: A dielectric reference. J. Mol. Liq. 1996, 68, 171-279.