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Volumn 692, Issue 14, 2007, Pages 2855-2860

Re-examination of the photochemical reaction of octaisopropylcyclotetragermane

Author keywords

Biradical; Cyclic oligogermanes; Germylene; Laser flash photolysis; Photochemistry

Indexed keywords

FREE RADICALS; LASER APPLICATIONS; RING OPENING POLYMERIZATION;

EID: 34249739192     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.03.017     Document Type: Article
Times cited : (2)

References (27)
  • 1
    • 0003644229 scopus 로고
    • Wilkinson G., Stone F.G.A., and Abel E.W. (Eds), Pergamon Press, Oxford, New York, Toronto, Sydney, Frankfurt (Chapter 9.4)
    • West R. In: Wilkinson G., Stone F.G.A., and Abel E.W. (Eds). Comprehensive Organometallic Chemistry vol. 2 (1982), Pergamon Press, Oxford, New York, Toronto, Sydney, Frankfurt (Chapter 9.4)
    • (1982) Comprehensive Organometallic Chemistry , vol.2
    • West, R.1
  • 3
    • 0001060404 scopus 로고
    • and references cited therein
    • West R. J. Organomet. Chem. 300 (1986) 327 and references cited therein
    • (1986) J. Organomet. Chem. , vol.300 , pp. 327
    • West, R.1
  • 18
    • 34249680276 scopus 로고    scopus 로고
    • note
    • An absorption peak at 390 nm was also observed and assigned to tetraisopropyldigermene 4. Since the results of laser flash photolysis show that digermene 4 is not formed by the primary photochemical process, it may be generated from the secondary reactions of 3.
  • 20
    • 34249683819 scopus 로고    scopus 로고
    • note
    • 1H NMR and HRGC-MS.
  • 21
    • 34249726188 scopus 로고    scopus 로고
    • 4) was synthesized by a method similar to that used to prepare dichlorooctaisopropyltetrasilane.
  • 23
    • 34249651921 scopus 로고    scopus 로고
    • note
    • 2.
  • 27
    • 34249672870 scopus 로고    scopus 로고
    • note
    • Although higher electronic transitions for the band at 310 nm can be calculated by TD-DFT, accuracy of the results is generally disputable.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.