Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

Inorganic Chemistry

Volumn 46, Issue 10, 2007, Pages 3810-3812

  Yamashita, Satoshi ^a   Shiga, Takuya ^a   Kurashina, Masashi ^a   Nihei, Masayuki ^a   Nojiri, Hiroyuki ^b,c   Sawa, Hiroshi ^c   Kakiuchi, Toru ^c   Oshio, Hiroki ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

^b TOHOKU UNIVERSITY   (Japan)

^c HIGH ENERGY ACCELERATOR RESEARCH ORGANIZATION KEK   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34249694160     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic062258h     Document Type: Article

References (29)

1. Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. 1999, 38, 2638.
2. (a) Bednorz, J. G.; Muller, K. A. Z. Phys. B 1986, 64, 189.
3. (b) Tokura, Y.; Nagaosa, N. Science 2000, 288, 462.
4. (c) Millis, A. J. Nature 1998, 392, 147.
5. (a) Christou, G. Acc. Chem. Res. 1989, 22, 328.
6. (b) Wieghardt, K. Angew. Chem., Int. Ed. Engl. 1994, 33, 725.
7. (c) Debus, R. J. Biochem. Biophys. Acta 1992, 1102, 269.
8. (d) Brudvig, G. W.; Thorp, H. H.; Crabtree, R. H. Acc. Chem. Res. 1991, 24, 311.
9. Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25 (11), 66.
10. (a) Bossek, U.; Weyhermüller, T.; Wieghardt, K.; Nuber, N.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387.
11. (b) Yocum, C. F.; Pecoraro, V. L. Curr. Opin. Chem. Biol. 1999, 3, 182.
12. (c) Ruettinger, W.; Yagi, M.; Wolf, K.; Bernasek, S.; Dismukes, G. C. J. Am. Chem. Soc. 2000, 122, 10353.
13. (d) Mukhopadhyay, S.; Staples, R. J.; Armstrong, W. H. Chem. Commun. 2002, 864.
14. (e) Bhaduri, S.; Pink, M.; Christou, G. Chem. Commun. 2002, 2352.
15. (a) Sun, Z.; Gantzel, P. K.; Hendrickson, D. N. Inorg. Chem. 1996, 35, 6640.
16. (b) King, P.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Inorg. Chem. 2004, 43, 7315.
17. (a) Parsons, S.; Smith, A. A.; Winpenny, R. E. P. Chem. Commun. 2000, 579.
18. (b) Eshel, M.; Bino A. Inorg. Chim. Acta 2002, 329, 45.
19. (c) Beattie, J. K.; Hambley, T. W.; Klepetko, J. A.; Masters, A. F.; Turner, P. Polyhedron 1997, 16, 2109.
20. Thorp, H. H. Inorg. Chem. 1992, 31, 1585.
21. Zhang, W. X.; Ma, C. Q.; Wang, X. N.; Yu, Z. G.; Lin, Q. J.; Jiang, D. H. Chin. J. Chem. 1995, 13, 497.
22. 52: C, 28.60; H, 3.67; N, 4.90. Found: C, 28.40; H, 3.38; N, 5.15.
23. int = 0.0226). Final R1 = 0.0570 and wR2 = 0.1697 using reflections with I > 2σ(I).
24. MEM analysis was performed with the Enigma program (Tanaka, H.; Tanaka, M.; Nishibori, E.; Kato, K.; Iishi, T.; Sakata, M. J. Appl. Crystallogr. 2002, 35, 282) at a resolution of 128 x 128 x 128 pixels, and the R factor of the final MEM charge density was 0.046.
25. Electron counting on each Mn ion was performed within the particular compartment of the space (Voronoi cell), which was defined as a region surrounded by perpendicular bisecting planes of bonds between Mn and neighboring O nuclei. Guerra, C. F.; Handgraaf, J.-W.; Baerends, E. J.; Bicelhaupt, F. M. J. Comput. Chem. 2004, 25, 189.
26. Koritsanszky, T. S.; Coppens, P. Chem. Rev. 2001, 101, 1583.
27. Mukherjee, S.; Weyhermüller, T.; Bothe, E.; Wieghardt, K.; Chaudhuri, P. Eur. J. Inorg. Chem. 2003, 863.
28. (a) Sawa, H.; Wakabayashi, Y.; Murata, Y.; Murata, M.; Komatsu, K. Angew. Chem., Int. Ed. 2005, 45, 1981.
29. (b) Kitaura, R.; Kitagawa, S.; Kubota, Y.; Kobayashi, T.; Kindo, K.; Mita, Y.; Matsuo, A.; Kobayash, M.; Chang, H.-C.; Ozawa, T.; Suzuki, M.; Sakata, M.; Takata, M. Science 2002, 298, 2385.