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An example of the raw data acquired by this setup is given in ref 16
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An example of the raw data acquired by this setup is given in ref 16.
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Although the STM measurements are a convolution of both topography and conductance, the measured apparent height difference seems more likely to be due to the difference between AD and C12 molecules than the difference in conductance between AD and reorganized, cleaved sulfur atoms. However, it should be mentioned that the displacement of an AD molecule may be accompanied by the removal of one (or more) substrate atoms. One-atom-deep substrate vacancy islands are often observed with the adsorption of thiol molecules onto gold surfaces.58-61 Additionally, Au atoms at room temperature have been reported as mobile species both on bare surfaces and on surfaces with a SAM present.60,62,63 It is not possible to determine whether the displacement process displaces an AD molecule only, or an AD-Au complex with the analytical methods used here
-
60,62,63 It is not possible to determine whether the displacement process displaces an AD molecule only, or an AD-Au complex with the analytical methods used here.
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p of the two distinct cathodic peaks, indicating that there were strong intermolecular interactions between the domains of these two more similar molecules.
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We assume that the intermolecular interaction energy gain of the displacement of AD is between the interaction strength of C12 and no intermolecular interactions. The intermolecular interaction energy gain is calculated to be 17.9 kcal/mol assuming intermolecular interactions are equivalent to C12 23.67 kcal/mol, and 40.3 kcal/mol is calculated assuming there are no intermolecular interactions
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