Hydrogenation of hydrogen peroxide over palladium/carbon in aqueous acidic medium containing different halide anions under static/flowing hydrogen

Industrial and Engineering Chemistry Research

Volumn 46, Issue 10, 2007, Pages 3237-3242

  Choudhary, Vasant R ^a   Samanta, Chanchal ^a   Jana, Prabhas ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ATMOSPHERIC PRESSURE; CONCENTRATION (PROCESS); HYDROGEN PEROXIDE; NEGATIVE IONS; SOLUTIONS;

CATALYST POISON; ZERO-ORDER REACTION;

HYDROGENATION;

ACTIVATION ENERGY; ATMOSPHERIC PRESSURE; CONCENTRATION (PROCESS); HYDROGEN PEROXIDE; HYDROGENATION; NEGATIVE IONS; SOLUTIONS;

EID: 34249099882     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0608408     Document Type: Article

References (13)

1. Pospelova, T. A.; Kobozev, N. I. Palladium-Catalysed Synthesis of Hydrogen Peroxide from the Elements. III. Active Centres for the Catalytic Decomposition of Hydrogen Peroxide on Palladium. Russ. J. Phys. Chem. 1961, 35, 584.
2. Choudhary, V. R.; Gaikwad, A. G.; Sansare, S. D. Nonhazardous Direct Oxidation of Hydrogen to Hydrogen Peroxide Using a Novel Membrane Catalyst. Angew. Chem., Int. Ed. 2001, 40, 1776.
3. 3 Catalysts in Stirred Slurry Reactor at Ambient Conditions. J. Mol. Catal. A: Chem. 2002, 181, 143.
4. Choudhary, V. R.; Gaikwad, A. G.; Sansare, S. D. Activation of Supported Pd Metal Catalysts for Selective Oxidation of Hydrogen to Hydrogen Peroxide. Catal. Lett. 2002, 83, 235.
5. 2 over Oxidized and Reduced Pd-Containing Zeolite Catalysts in Acidic Medium. Catal. Lett. 2002, 84, 81.
6. 2 over Supported Pd Catalysts due to Their Bromination. Chem. Commun. (Cambridge) 2004, 2054.
7. 2 over Supported Pd Catalysts in an Aqueous Medium. J. Catal. 2006, 238, 28.
8. 2O2 over Pd-Based Catalysts: Influence of Oxidation State, Support and Metal Additives. Appl. Catal., A 2006, 308, 128.
9. Choudhary, V. R.; Gaikwad, A. G. Kinetics of Hydrogen Peroxide Decomposition in Aqueous Sulfuric Acid over Palladium/Carbon: Effect of Acid Concentration. React. Kinet. Catal. Lett. 2003, 80, 27.
10. 4/Ethanol System. J. Catal. 2006, 239, 237.
11. 2 Catalyzed by Palladium in an Aqueous Medium. J. Catal. 2004, 225, 249.
12. 2 Using Pd and Au Catalysts. Phys. Chem. Chem. Phys. 2003, 5, 1917.
13. Choudhary, V. R.; Parande, M. G.; Brahme, P. H. A Simple Apparatus for Measuring Solubility of Gases at High Pressures. Ind. Eng. Chem. Fundam. 1982, 21, 472.