Catalytic effects of metals on thermal decomposition of sodium chlorate for emergency oxygen generators

Industrial and Engineering Chemistry Research

Volumn 46, Issue 10, 2007, Pages 3073-3077

  Shafirovich, Evgeny ^a   Zhou, Changjun ^b   Ekambaram, Sambandan ^a   Varma, Arvind ^a   Kshirsagar, Girish ^c   Ellison, John E ^c  

^a PURDUE UNIVERSITY   (United States)

^b University of Notre Dame   (United States)

^c B/E Aerospace Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

OXYGEN FLOW RATE; OXYGEN GENERATORS; SELF-SUSTAINED COMBUSTION;

BINARY MIXTURES; CATALYST ACTIVITY; COMBUSTION; COMPUTATION THEORY; PYROLYSIS; THERMOANALYSIS;

SODIUM COMPOUNDS;

BINARY MIXTURES; CATALYST ACTIVITY; COMBUSTION; COMPUTATION THEORY; PYROLYSIS; SODIUM COMPOUNDS; THERMOANALYSIS;

EID: 34249088557     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie060585r     Document Type: Article

References (12)

1. Markowitz, M. M.; Boryta, D. A.; Stewart, H., Jr. The differential thermal analysis of perchlorates. VI. Transient perchlorate formation during the pyrolysis of the alkali metal chlorates. J. Phys. Chem. 1964, 68, 2282-2289.
2. Wydeven. T. J. Catalytic decomposition of sodium chlorate. Catalysis 1970, 19, 162-171.
3. Morishima, S.; Iwakura, H.; Kakutu. N.; Ueno, A.; Kishi, K.; Kato, J. Catalytic performances of metal oxides for thermal decomposition of sodium chlorate. Nippon Kagaku Kaishi 1991, 9, 1172-1176.
4. Zhang, Y.; Kshirsagar, G.; Elliso,. J. E.; Cannon, J. C. Effects of metal oxides on the thermal decomposition of sodium chlorate. Thermochim. Acta 1993, 228, 147-154.
5. 2. Russ. J. Inorg. Chem. 2003, 48, 459-463.
6. Zhang, Y. Cannon, J. Oxygen-generating compositions. U.S. Patent 5,783,105, July 21. 1998.
7. Shafirovich, E.; Mukasyan, A. S.; Varma, A.; Kshirsagar, G.; Zhang, Y.; Cannon, J. C. Mechanism of combustion in low-exothermic mixtures of sodium chlorate and metal fuel. Combust. Flame 2002, 128, 133-144.
8. Shafirovich, E.; Zhou, C.; Mukasyan, A. S.; Varma, A.; Kshirsagar, G.; Zhang, Y.; Cannon, J. C. Combustion fluctuations in low-exothermic condensed systems for emergency oxygen generation. Combust. Flame 2003, 135, 557-561.
9. Diakov. V.; Shafirovich, E.; Varma, A. A numerical study of combustion stability in emergency oxygen generators. AIChE J. 2006, 52, 1495-1501.
10. Sasnovskaya, V. D.; Razumova, A. P. Thermal transformations in systems of sodium perchlorate and sodium chlorate with magnesium. Russ. J. Inorg. Chem. 2000, 45, 1018-1023.
11. Kshirsagar, G.; Cannon, J.; Zhang, Y. Oxygen generating compositions. U.S. Patent 6,030,583, Feb 29, 2000.
12. Shiryaev, A. A. Thermodynamics of SHS processes: Advanced approach. Int. J. Self-Propag. High-Temp. Synth. 1995, 4, 351-362.