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Volumn 126, Issue 19, 2007, Pages

Nonlocal optical effects on the fluorescence and decay rates for admolecules at a metallic nanoparticle

Author keywords

[No Author keywords available]

Indexed keywords

HYDRODYNAMIC MODEL; MULTIPOLAR INTERACTIONS; NONLOCAL EFFECTS; RADIATIVE RATE;

EID: 34249081774     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2734549     Document Type: Article
Times cited : (42)

References (34)
  • 6
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    • The presence of an optimal distance in such processes involving two competing mechanisms has been well known for a long time since the 1980s. See, e.g., P. T. Leung and T. F. George, J. Chem. Phys. 85, 4729 (1986) and references therein.
    • (1986) J. Chem. Phys. , vol.85 , pp. 4729
    • Leung, P.T.1    George, T.F.2
  • 7
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    • 0039-6028 10.1016/0039-6028(85)90293-6
    • See, e.g., the earlier review articles by J. I. Gersten and A. Nitzan, Surf. Sci. 0039-6028 10.1016/0039-6028(85)90293-6 158, 165 (1985) and by M. Moskovits, Rev. Mod. Phys. 57, 783 (1985).
    • (1985) Surf. Sci. , vol.158 , pp. 165
    • Gersten, J.I.1    Nitzan, A.2
  • 8
    • 0000698565 scopus 로고
    • See, e.g., the earlier review articles by J. I. Gersten and A. Nitzan, Surf. Sci. 0039-6028 10.1016/0039-6028(85)90293-6 158, 165 (1985) and by M. Moskovits, Rev. Mod. Phys. 57, 783 (1985).
    • (1985) Rev. Mod. Phys. , vol.57 , pp. 783
    • Moskovits, M.1
  • 9
    • 36749119182 scopus 로고
    • J. Gersten and A. Nitzan, J. Chem. Phys. 75, 1139 (1981), and the mathematical appendix to this paper: AIP Document No. PAPS JCP SA-75-1139-32, Section B. See also their above reference in Ref..
    • (1981) J. Chem. Phys. , vol.75 , pp. 1139
    • Gersten, J.1    Nitzan, A.2
  • 18
    • 0003964324 scopus 로고    scopus 로고
    • 3rd ed. (Plenum, New York
    • See, e.g., G. D. Mahan, Many-Particle Physics, 3rd ed. (Plenum, New York, 2000), Sec. 5.5.
    • (2000) Many-Particle Physics
    • Mahan, G.D.1
  • 20
    • 4244142536 scopus 로고
    • 0163-1829 10.1103/PhysRevB.28.487
    • A similar study has been carried out even earlier by other researchers using a slightly different approach based on the Green dyadic formulation, see G. S. Agarwal and S. V. O'Neil, Phys. Rev. B 0163-1829 10.1103/PhysRevB.28.487 28, 487 (1983). The corresponding effects on the emission frequency of the molecule was also studied in P. T. Leung, and M. H. Hider, J. Chem. Phys. 98, 5019 (1993).
    • (1983) Phys. Rev. B , vol.28 , pp. 487
    • Agarwal, G.S.1    O'Neil, S.V.2
  • 21
    • 0000584350 scopus 로고
    • A similar study has been carried out even earlier by other researchers using a slightly different approach based on the Green dyadic formulation, see G. S. Agarwal and S. V. O'Neil, Phys. Rev. B 0163-1829 10.1103/PhysRevB.28.487 28, 487 (1983). The corresponding effects on the emission frequency of the molecule was also studied in P. T. Leung, and M. H. Hider, J. Chem. Phys. 98, 5019 (1993).
    • (1993) J. Chem. Phys. , vol.98 , pp. 5019
    • Leung, P.T.1    Hider, M.H.2
  • 22
    • 33745214336 scopus 로고    scopus 로고
    • Theory of fluorophore-metallic surface interactions
    • edited by C. D.Geddes and J.Lakowicz (Springer, New York
    • A very comprehensive review up to our previous work in Ref. was recently published by J. I. Gersten. The review entitled " Theory of fluorophore-metallic surface interactions. " can be found in Trends in Fluorescence Spectroscopy, edited by, C. D. Geddes, and, J. Lakowicz, (Springer, New York, 2005), pp. 197-222.
    • (2005) Trends in Fluorescence Spectroscopy , pp. 197-222
    • Gersten, J.I.1
  • 28
    • 84961985368 scopus 로고    scopus 로고
    • 0021-9606 10.1063/1.1558036
    • The comparison between the hydrodynamic (H) and the Lindhard-Mermin (LM) models as applied to total decay-rate calculations has been studied previously for planar metallic surfaces [see S. Corni and J. Tomasi, J. Chem. Phys. 0021-9606 10.1063/1.1558036 118, 6481 (2003)], and for core-shell particles [see R. Chang and P. T. Leung, Phys. Rev. B 0163-1829 10.1103/PhysRevB.73.125438 73, 125438 (2006); R. Chang and P. T. Leung, Phys. Rev. B 75, 079901 (E) (2007)]. While a significant difference between the two models has been observed in the former case, very close results between the two models were obtained in the latter case for a molecule at 1 nm from a metallic nanoshell. The LM model is in principle more accurate than the H model since the latter is simply the lowest order (in wave vector) approximation of the former, and it excludes electron-hole pair excitations in the metal. A detailed comparison between the two models as applied to calculations of each of the fluorescence, radiative, and nonradiative rates will be of interest and will be left for a future endeavor.
    • (2003) J. Chem. Phys. , vol.118 , pp. 6481
    • Corni, S.1    Tomasi, J.2
  • 29
    • 33645418246 scopus 로고    scopus 로고
    • 0163-1829 10.1103/PhysRevB.73.125438
    • The comparison between the hydrodynamic (H) and the Lindhard-Mermin (LM) models as applied to total decay-rate calculations has been studied previously for planar metallic surfaces [see S. Corni and J. Tomasi, J. Chem. Phys. 0021-9606 10.1063/1.1558036 118, 6481 (2003)], and for core-shell particles [see R. Chang and P. T. Leung, Phys. Rev. B 0163-1829 10.1103/PhysRevB.73.125438 73, 125438 (2006); R. Chang and P. T. Leung, Phys. Rev. B 75, 079901 (E) (2007)]. While a significant difference between the two models has been observed in the former case, very close results between the two models were obtained in the latter case for a molecule at 1 nm from a metallic nanoshell. The LM model is in principle more accurate than the H model since the latter is simply the lowest order (in wave vector) approximation of the former, and it excludes electron-hole pair excitations in the metal. A detailed comparison between the two models as applied to calculations of each of the fluorescence, radiative, and nonradiative rates will be of interest and will be left for a future endeavor.
    • (2006) Phys. Rev. B , vol.73 , pp. 125438
    • Chang, R.1    Leung, P.T.2
  • 30
    • 33846881776 scopus 로고    scopus 로고
    • The comparison between the hydrodynamic (H) and the Lindhard-Mermin (LM) models as applied to total decay-rate calculations has been studied previously for planar metallic surfaces [see S. Corni and J. Tomasi, J. Chem. Phys. 0021-9606 10.1063/1.1558036 118, 6481 (2003)], and for core-shell particles [see R. Chang and P. T. Leung, Phys. Rev. B 0163-1829 10.1103/PhysRevB.73.125438 73, 125438 (2006); R. Chang and P. T. Leung, Phys. Rev. B 75, 079901 (E) (2007)]. While a significant difference between the two models has been observed in the former case, very close results between the two models were obtained in the latter case for a molecule at 1 nm from a metallic nanoshell. The LM model is in principle more accurate than the H model since the latter is simply the lowest order (in wave vector) approximation of the former, and it excludes electron-hole pair excitations in the metal. A detailed comparison between the two models as applied to calculations of each of the fluorescence, radiative, and nonradiative rates will be of interest and will be left for a future endeavor.
    • (2007) Phys. Rev. B , vol.75 , pp. 079901
    • Chang, R.1    Leung, P.T.2
  • 32


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