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4q (based on M. Wilde et al., Surf. Sci. 1999, 27, 427-428 and references therein) to estimate the yield at 0°.
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22
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34249028763
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The relative desorption probability for CO on steps obtained in this way constitutes a lower limit because laser-induced motion of CO molecules from step to terrace sites is known to occur.19 Hence, for the step-covered surface, there is a small additional contribution from CO molecules that have not diffused back to the steps, after being driven to terrace sites by the initial laser shot. Moreover, desorption of molecules from the step sites via the terrace sites directly after excitation could also play a role. From the different angle dependence of the desorption probability for step and terrace sites Figure 1, it can be concluded that this process alone can not explain the data, but it certainly can not be excluded
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19 Hence, for the step-covered surface, there is a small additional contribution from CO molecules that have not diffused back to the steps, after being driven to terrace sites by the initial laser shot. Moreover, desorption of molecules from the step sites via the terrace sites directly after excitation could also play a role. From the different angle dependence of the desorption probability for step and terrace sites (Figure 1), it can be concluded that this process alone can not explain the data, but it certainly can not be excluded.
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34249028764
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For the strong coupling observed here, the reaction rate follows the electronic transient temperature quite closely, resulting in a relative large error in the coupling time
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For the strong coupling observed here, the reaction rate follows the electronic transient temperature quite closely, resulting in a relative large error in the coupling time.
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26
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34249063062
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The extracted electron coupling times for NO are smaller than the inverse mode frequency of the low-frequency modes. This is unphysical because energy transfer into the low-frequency modes cannot occur faster than the motion associated with the modes. Although the absolute values for the friction coefficient obtained with this simple one-dimensional friction model may have limited meaning, the relative difference between the step and terrace coefficient clearly indicates a ∼3-fold stronger coupling of the laser-heated electrons to the adsorbate at the steps relative to the terraces
-
The extracted electron coupling times for NO are smaller than the inverse mode frequency of the low-frequency modes. This is unphysical because energy transfer into the low-frequency modes cannot occur faster than the motion associated with the modes. Although the absolute values for the friction coefficient obtained with this simple one-dimensional friction model may have limited meaning, the relative difference between the step and terrace coefficient clearly indicates a ∼3-fold stronger coupling of the laser-heated electrons to the adsorbate at the steps relative to the terraces.
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27
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34249030685
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Although the adsorption structure is slightly different from dosing directly at 85 K,18 the first shot yield and depletion curve are indistinguishable
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18 the first shot yield and depletion curve are indistinguishable.
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