메뉴 건너뛰기




Volumn 12, Issue 1, 2007, Pages 3-8

Adsorption and grafting on colloidal interfaces studied by scattering techniques

Author keywords

Adsorption isotherm; Dynamic Light Scattering; Layer profile; PEO; Polymer; Small Angle Neutron Scattering; Small Angle X ray Scattering; Surfactant layer

Indexed keywords

ADSORPTION; DYNAMIC LIGHT SCATTERING; GRAFTING (CHEMICAL); NEUTRON SCATTERING; POLYELECTROLYTES; POLYMERS; SURFACE ACTIVE AGENTS; X RAY ANALYSIS;

EID: 34248595487     PISSN: 13590294     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cocis.2006.11.001     Document Type: Review
Times cited : (28)

References (58)
  • 1
    • 34248527776 scopus 로고    scopus 로고
    • Lu JL. Curr Opin Colloid Interface Sci submitted for publication.
  • 3
    • 34248536394 scopus 로고    scopus 로고
    • Lindner P, Zemb Th, editors. Neutrons, X-ray and light: scattering methods applied to soft condensed matter. An excellent textbook covering many aspects of scattering used in soft condensed matter studies. North Holland Delta Series, Elsevier; 2002.
  • 4
    • 0036876481 scopus 로고    scopus 로고
    • SANS from adsorbed polymer layers
    • This paper reviews the scattering from adsorbed layers in general. All equations are extensively discussed, with a special focus on the determination of the polymer volume fraction profile and the polymer fluctuation term.
    • King S., Griffith P., Hone J., and Cosgrove T. SANS from adsorbed polymer layers. Macromol Symp 190 (2002) 33-42. This paper reviews the scattering from adsorbed layers in general. All equations are extensively discussed, with a special focus on the determination of the polymer volume fraction profile and the polymer fluctuation term.
    • (2002) Macromol Symp , vol.190 , pp. 33-42
    • King, S.1    Griffith, P.2    Hone, J.3    Cosgrove, T.4
  • 5
    • 28044444322 scopus 로고    scopus 로고
    • Small-angle neutron scattering on a core-shell colloidal system: a contrast variation study
    • - 2. Scattering at higher concentrations is described with Percus-Yevick structure factor for polydisperse mixtures.
    • - 2. Scattering at higher concentrations is described with Percus-Yevick structure factor for polydisperse mixtures.
    • (2005) Langmuir , vol.21 , pp. 10835-10845
    • Zackrisson, M.1    Stradner, A.2    Schurtenberger, P.3    Bergenholtz, J.4
  • 6
    • 33746799271 scopus 로고    scopus 로고
    • Colloidal dispersions of octadecyl grafted silica spheres in toluene: a global analysis of small angle neutron scattering contrast variation and concentration dependence measurements
    • A contrast-variation study of the scattering of silica spheres with a hydrophobic layer in an organic solvent is presented. The intensity is described by a core-shell model combined with a structure factor for adhesive particles, which fits all contrast situations simultaneously.
    • Kohlbrecher J., Buitenhuis J., Meier G., and Lettinga M.P. Colloidal dispersions of octadecyl grafted silica spheres in toluene: a global analysis of small angle neutron scattering contrast variation and concentration dependence measurements. J Chem Phys 125 (2006) 044715. A contrast-variation study of the scattering of silica spheres with a hydrophobic layer in an organic solvent is presented. The intensity is described by a core-shell model combined with a structure factor for adhesive particles, which fits all contrast situations simultaneously.
    • (2006) J Chem Phys , vol.125 , pp. 044715
    • Kohlbrecher, J.1    Buitenhuis, J.2    Meier, G.3    Lettinga, M.P.4
  • 7
    • 33746589950 scopus 로고    scopus 로고
    • Small-angle neutron scattering study of concentrated colloidal dispersions: the electrostatic/steric composite interactions between colloidal particles
    • Qiu D., Cosgrove T., and Howe A. Small-angle neutron scattering study of concentrated colloidal dispersions: the electrostatic/steric composite interactions between colloidal particles. Langmuir 22 (2006) 6060-6067
    • (2006) Langmuir , vol.22 , pp. 6060-6067
    • Qiu, D.1    Cosgrove, T.2    Howe, A.3
  • 8
    • 27544463778 scopus 로고    scopus 로고
    • Small-angle neutron scattering study of concentrated colloidal dispersions: the interparticle interactions between sterically stabilized particles
    • Qiu D., Dreiss C.A., Cosgrove T., and Howe A. Small-angle neutron scattering study of concentrated colloidal dispersions: the interparticle interactions between sterically stabilized particles. Langmuir 21 (2005) 9964-9969
    • (2005) Langmuir , vol.21 , pp. 9964-9969
    • Qiu, D.1    Dreiss, C.A.2    Cosgrove, T.3    Howe, A.4
  • 9
    • 0141606984 scopus 로고    scopus 로고
    • Formation of micelle-decorated colloidal silica by adsorption of nonionic surfactant
    • The adsorption of a non-ionic surfactant (TX-100) on colloidal silica is studied by SANS, using solvent contrast variation. The adsorbed layer is described by a model of impenetrable micelles attached to the silica bead.
    • Despert G., and Oberdisse J. Formation of micelle-decorated colloidal silica by adsorption of nonionic surfactant. Langmuir 19 (2003) 7604-7610. The adsorption of a non-ionic surfactant (TX-100) on colloidal silica is studied by SANS, using solvent contrast variation. The adsorbed layer is described by a model of impenetrable micelles attached to the silica bead.
    • (2003) Langmuir , vol.19 , pp. 7604-7610
    • Despert, G.1    Oberdisse, J.2
  • 10
    • 0034719542 scopus 로고    scopus 로고
    • Adsorption of mixed surfactants at the oil/water interface
    • 6 onto hexadecane droplets in water is studied by SANS. A core-shell model is used to describe the form factor of the emulsion droplets, and coexisting micelles are modelled as interacting core-shell particles. A model-independent analysis using I(q → 0) is used to extract information on layer composition. The results are shown to disagree with straightforward regular solution theory.
    • 6 onto hexadecane droplets in water is studied by SANS. A core-shell model is used to describe the form factor of the emulsion droplets, and coexisting micelles are modelled as interacting core-shell particles. A model-independent analysis using I(q → 0) is used to extract information on layer composition. The results are shown to disagree with straightforward regular solution theory.
    • (2000) J Phys Chem B , vol.104 , pp. 606-614
    • Staples, E.1    Penfold, J.2    Tucker, I.3
  • 11
    • 3042639895 scopus 로고    scopus 로고
    • Structure of polymer-stabilized magnetic fluids: small-angle neutrons scattering and mean-field lattice modelling
    • The layer of PAA with grafted PPO and PEO blocks bound to magnetic nanoparticles is studied by SANS. Core-shell modelling including the magnetic scattering of the core is used to determine the layer density and thickness, for different PPO/PEO ratios.
    • Moeser G.D., Green W.H., Laibinis P.E., Linse P., and Hatton T.A. Structure of polymer-stabilized magnetic fluids: small-angle neutrons scattering and mean-field lattice modelling. Langmuir 20 (2004) 5223-5234. The layer of PAA with grafted PPO and PEO blocks bound to magnetic nanoparticles is studied by SANS. Core-shell modelling including the magnetic scattering of the core is used to determine the layer density and thickness, for different PPO/PEO ratios.
    • (2004) Langmuir , vol.20 , pp. 5223-5234
    • Moeser, G.D.1    Green, W.H.2    Laibinis, P.E.3    Linse, P.4    Hatton, T.A.5
  • 12
    • 10444286958 scopus 로고    scopus 로고
    • Laser-light scattering study of internal motions of polymer chains grafted on spherical latex particles
    • - 1 polymer density in the brush. The time correlation function reveals interesting dynamics at small scales, presumably due to internal motions.
    • - 1 polymer density in the brush. The time correlation function reveals interesting dynamics at small scales, presumably due to internal motions.
    • (2004) J Phys Chem B , vol.108 , pp. 18479-18484
    • Yang, C.1    Kizhakkedathu, J.N.2    Brooks, D.E.3    Jin, F.4    Wu, C.5
  • 13
    • 84956232834 scopus 로고
    • Neutron scattering by adsorbed polymer layers
    • Auvray G., and de Gennes P.G. Neutron scattering by adsorbed polymer layers. Europhys Lett 2 (1986) 647-650
    • (1986) Europhys Lett , vol.2 , pp. 647-650
    • Auvray, G.1    de Gennes, P.G.2
  • 14
    • 0037022498 scopus 로고    scopus 로고
    • Structure of physically adsorbed polymer layers measured by small-angle neutron scattering using contrast variation methods
    • Combined on- and off-contrast SANS experiments in order to determine the (exponential) profile Φ(z) and the weak fluctuation term of PEO-layers on polystyrene latex. The fluctuation term is obtained by subtraction of layer intensities obtained via the two routes discussed in the text.
    • Hone J.H.E., Cosgrove T., Saphiannikova M., Obey T.M., Marshall J.C., and Crowley T.L. Structure of physically adsorbed polymer layers measured by small-angle neutron scattering using contrast variation methods. Langmuir 18 (2002) 855-864. Combined on- and off-contrast SANS experiments in order to determine the (exponential) profile Φ(z) and the weak fluctuation term of PEO-layers on polystyrene latex. The fluctuation term is obtained by subtraction of layer intensities obtained via the two routes discussed in the text.
    • (2002) Langmuir , vol.18 , pp. 855-864
    • Hone, J.H.E.1    Cosgrove, T.2    Saphiannikova, M.3    Obey, T.M.4    Marshall, J.C.5    Crowley, T.L.6
  • 15
    • 2942624246 scopus 로고    scopus 로고
    • Detailed modelling of the volume fraction profile of adsorbed layers using small-angle neutron scattering
    • - 2. It is therefore more important (but nonetheless very small) at high q.
    • - 2. It is therefore more important (but nonetheless very small) at high q.
    • (2004) Langmuir , vol.20 , pp. 4480-4488
    • Marshall, J.C.1    Cosgrove, T.2    Leermakers, F.3    Obey, T.M.4    Dreiss, C.A.5
  • 16
    • 33747178168 scopus 로고    scopus 로고
    • Effect of electrolyte on adsorbed polymer layers: poly(ethylene oxide)-silica system
    • Flood C., Cosgrove T., Howell I., and Revell P. Effect of electrolyte on adsorbed polymer layers: poly(ethylene oxide)-silica system. Langmuir 22 (2006) 6923-6930
    • (2006) Langmuir , vol.22 , pp. 6923-6930
    • Flood, C.1    Cosgrove, T.2    Howell, I.3    Revell, P.4
  • 17
    • 0033745062 scopus 로고    scopus 로고
    • Analysis of surfactants adsorbed onto the surface of latex particles by small-angle X-ray scattering
    • The layer structure of hydrophilic PEO attached onto latex by hydrophobic stickers is studied. The PS-latex is virtually matched by the solvent, and the intensity curves show a nice evolution the side maxima, which shift to smaller-q and raise in intensity as the layer scattering increases. Moments of the density profile are used to characterize the layer, and both an exponential and a parabolic density profile fit the data.
    • Seelenmeyer S., and Ballauff M. Analysis of surfactants adsorbed onto the surface of latex particles by small-angle X-ray scattering. Langmuir 16 (2000) 4094-4099. The layer structure of hydrophilic PEO attached onto latex by hydrophobic stickers is studied. The PS-latex is virtually matched by the solvent, and the intensity curves show a nice evolution the side maxima, which shift to smaller-q and raise in intensity as the layer scattering increases. Moments of the density profile are used to characterize the layer, and both an exponential and a parabolic density profile fit the data.
    • (2000) Langmuir , vol.16 , pp. 4094-4099
    • Seelenmeyer, S.1    Ballauff, M.2
  • 19
    • 12444307551 scopus 로고    scopus 로고
    • Polyoxyalkylene block copolymers adsorbed in hydrocarbon and fluorocarbon oil-in-water emulsions
    • The volume profiles of three copolymers (F68, F127, tetronic/poloxamine 908) adsorbed onto emulsion droplets are determined by SANS, using two methods, inversion and fitting, to Φ(z). Considerable similarity in the adsorbed layer structure is found for hydrocarbon and fluorocarbon emulsions.
    • King S., Washington C., and Heenan R. Polyoxyalkylene block copolymers adsorbed in hydrocarbon and fluorocarbon oil-in-water emulsions. Phys Chem Chem Phys 7 (2005) 143-149. The volume profiles of three copolymers (F68, F127, tetronic/poloxamine 908) adsorbed onto emulsion droplets are determined by SANS, using two methods, inversion and fitting, to Φ(z). Considerable similarity in the adsorbed layer structure is found for hydrocarbon and fluorocarbon emulsions.
    • (2005) Phys Chem Chem Phys , vol.7 , pp. 143-149
    • King, S.1    Washington, C.2    Heenan, R.3
  • 20
    • 0033902720 scopus 로고    scopus 로고
    • Polymer bristles: adsorption of low molecular weight poly(oxyethylene)-poly(oxybutylene) diblock copolymers on a perfluorocarbon emulsion
    • Washington C., King S.M., Attwood D., Booth C., Mai S.M., and Yang Y.W. Polymer bristles: adsorption of low molecular weight poly(oxyethylene)-poly(oxybutylene) diblock copolymers on a perfluorocarbon emulsion. Macromolecules 33 (2000) 1289-1297
    • (2000) Macromolecules , vol.33 , pp. 1289-1297
    • Washington, C.1    King, S.M.2    Attwood, D.3    Booth, C.4    Mai, S.M.5    Yang, Y.W.6
  • 21
    • 0035581390 scopus 로고    scopus 로고
    • Diblock copolymers adsorbed at a water-oil interface
    • Adsorbed layers of polybutadiene-PEO block copolymers on water-in-oil droplets are studied by DLS and by force-distance profiles based on magnetic control via included ferrofluid particles.
    • Omarjee P., Hoerner P., Riess G., Cabuil V., and Mondain-Monval O. Diblock copolymers adsorbed at a water-oil interface. Eur Phys J E Soft matter 4 (2001) 45-50. Adsorbed layers of polybutadiene-PEO block copolymers on water-in-oil droplets are studied by DLS and by force-distance profiles based on magnetic control via included ferrofluid particles.
    • (2001) Eur Phys J E Soft matter , vol.4 , pp. 45-50
    • Omarjee, P.1    Hoerner, P.2    Riess, G.3    Cabuil, V.4    Mondain-Monval, O.5
  • 22
    • 0036999543 scopus 로고    scopus 로고
    • Efficiency boosting and optional viscosity tuning in microemulsions studied by SANS
    • The boosting effect of PPO-PEO diblock copolymers consists in an important shift of the emulsification efficiency in bicontinuous microemulsions. In this study, the partial scattering functions between the copolymer and the surfactant film, the oil and the film, and the oil and the polymer are determined by contrast variation.
    • Frielinghaus H., Byelov D., Allgaier J., Richter D., Jakobs B., Sottmann T., et al. Efficiency boosting and optional viscosity tuning in microemulsions studied by SANS. Appl Phys A 74 (2002) 408-410. The boosting effect of PPO-PEO diblock copolymers consists in an important shift of the emulsification efficiency in bicontinuous microemulsions. In this study, the partial scattering functions between the copolymer and the surfactant film, the oil and the film, and the oil and the polymer are determined by contrast variation.
    • (2002) Appl Phys A , vol.74 , pp. 408-410
    • Frielinghaus, H.1    Byelov, D.2    Allgaier, J.3    Richter, D.4    Jakobs, B.5    Sottmann, T.6
  • 23
  • 24
    • 0032684377 scopus 로고    scopus 로고
    • Amphiphilic block copolymers as efficiency boosters for microemulsions
    • Jakobs B., Sottmann T., Strey R., Allgaier J., Willner L., and Richter D. Amphiphilic block copolymers as efficiency boosters for microemulsions. Langmuir 15 (1999) 6707-6711
    • (1999) Langmuir , vol.15 , pp. 6707-6711
    • Jakobs, B.1    Sottmann, T.2    Strey, R.3    Allgaier, J.4    Willner, L.5    Richter, D.6
  • 25
    • 0037168357 scopus 로고    scopus 로고
    • Temperature-dependent adsorption of pluronic F127 block copolymers onto carbon black particles dispersed in aqueous media
    • The adsorption of PEO-PPO-PEO (F127) block copolymers onto carbon black is studied by DLS and SANS. The hydrodynamic thickness of the adsorbed layers is found to increase with polymer concentration. Neutron scattering with contrast matching is used to verify that neither carbon black nor the micelles are modified by the other component.
    • Lin Y., and Alexandridis P. Temperature-dependent adsorption of pluronic F127 block copolymers onto carbon black particles dispersed in aqueous media. J Phys Chem B 106 (2002) 10834-10844. The adsorption of PEO-PPO-PEO (F127) block copolymers onto carbon black is studied by DLS and SANS. The hydrodynamic thickness of the adsorbed layers is found to increase with polymer concentration. Neutron scattering with contrast matching is used to verify that neither carbon black nor the micelles are modified by the other component.
    • (2002) J Phys Chem B , vol.106 , pp. 10834-10844
    • Lin, Y.1    Alexandridis, P.2
  • 26
    • 0347928630 scopus 로고    scopus 로고
    • Adsorption of a polymeric siloxane surfactant on carbon black particles dispersed in mixtures of water with polar organic solvents
    • Lin Y., Smith T.W., and Alexandridis P. Adsorption of a polymeric siloxane surfactant on carbon black particles dispersed in mixtures of water with polar organic solvents. J Colloid Interface Sci 255 (2002) 1-9
    • (2002) J Colloid Interface Sci , vol.255 , pp. 1-9
    • Lin, Y.1    Smith, T.W.2    Alexandridis, P.3
  • 27
    • 0037031461 scopus 로고    scopus 로고
    • Adsorption of a rake-type siloxane surfactant onto carbon black nanoparticles dispersed in aqueous media
    • Lin Y., Smith T.W., and Alexandridis P. Adsorption of a rake-type siloxane surfactant onto carbon black nanoparticles dispersed in aqueous media. Langmuir 18 (2002) 6147-6158
    • (2002) Langmuir , vol.18 , pp. 6147-6158
    • Lin, Y.1    Smith, T.W.2    Alexandridis, P.3
  • 28
    • 1842582608 scopus 로고    scopus 로고
    • A small-angle neutron scattering study of adsorbed poly(ethylene oxide) on laponite
    • The adsorption of PEO between 20 and 276 k on clay particles is studied by NMR solvent relaxtion and by SANS. Core-shell modelling is used to obtain adsorbed mass. The layer thickness is found to be very thin and smaller on the face than on the edge of the clay (16 Å on the face, 35 Å on the edge).
    • Nelson A., and Cosgrove T. A small-angle neutron scattering study of adsorbed poly(ethylene oxide) on laponite. Langmuir 20 (2004) 2298-2304. The adsorption of PEO between 20 and 276 k on clay particles is studied by NMR solvent relaxtion and by SANS. Core-shell modelling is used to obtain adsorbed mass. The layer thickness is found to be very thin and smaller on the face than on the edge of the clay (16 Å on the face, 35 Å on the edge).
    • (2004) Langmuir , vol.20 , pp. 2298-2304
    • Nelson, A.1    Cosgrove, T.2
  • 29
    • 10044287281 scopus 로고    scopus 로고
    • Dynamic light scattering studies of poly(ethylene oxide) adsorbed on laponite: layer conformation and its effect on particle stability
    • Nelson A., and Cosgrove T. Dynamic light scattering studies of poly(ethylene oxide) adsorbed on laponite: layer conformation and its effect on particle stability. Langmuir 20 (2004) 10382-10388
    • (2004) Langmuir , vol.20 , pp. 10382-10388
    • Nelson, A.1    Cosgrove, T.2
  • 30
    • 26444574934 scopus 로고    scopus 로고
    • Small-angle neutron scattering study of adsorbed pluronic tri-block copolymers on laponite
    • Nelson A., and Cosgrove T. Small-angle neutron scattering study of adsorbed pluronic tri-block copolymers on laponite. Langmuir 21 (2005) 9176-9182
    • (2005) Langmuir , vol.21 , pp. 9176-9182
    • Nelson, A.1    Cosgrove, T.2
  • 31
    • 0037059173 scopus 로고    scopus 로고
    • Small-angle neutron scattering of gelatin/sodium dodecyl sulfate complexes at the polystyrene/water interface
    • Marshall J.C., Cosgrove T., and Jack K. Small-angle neutron scattering of gelatin/sodium dodecyl sulfate complexes at the polystyrene/water interface. Langmuir 18 (2002) 9668-9675
    • (2002) Langmuir , vol.18 , pp. 9668-9675
    • Marshall, J.C.1    Cosgrove, T.2    Jack, K.3
  • 32
    • 6444239399 scopus 로고    scopus 로고
    • Formation of a supramolecular gel between α-cyclodextrin and free and adsorbed PEO on the surface of colloidal silica: effect of temperature, solvent, and particle size
    • Dreiss C.A., Cosgrove T., Newby F.N., and Sabadini E. Formation of a supramolecular gel between α-cyclodextrin and free and adsorbed PEO on the surface of colloidal silica: effect of temperature, solvent, and particle size. Langmuir 20 (2004) 9124-9129
    • (2004) Langmuir , vol.20 , pp. 9124-9129
    • Dreiss, C.A.1    Cosgrove, T.2    Newby, F.N.3    Sabadini, E.4
  • 33
    • 17444394006 scopus 로고    scopus 로고
    • SANS study of the interactions among DNA, a cationic surfactant, and polystyrene latex particles
    • Cárdenas M., Dreiss C.A., Nylander T., Chan C.P., Cosgrove T., and Lindman B. SANS study of the interactions among DNA, a cationic surfactant, and polystyrene latex particles. Langmuir 21 (2005) 3578-3583
    • (2005) Langmuir , vol.21 , pp. 3578-3583
    • Cárdenas, M.1    Dreiss, C.A.2    Nylander, T.3    Chan, C.P.4    Cosgrove, T.5    Lindman, B.6
  • 34
    • 0034188126 scopus 로고    scopus 로고
    • Adsorption and desorption of unmodified and hydrophobically modified ethyl(hydroxyethyl)cellulose on polystyrene latex particles in the presence of ionic surfactants using dynamic light scattering
    • Lauten R.A., Kjøniksen A.L., and Nyström B. Adsorption and desorption of unmodified and hydrophobically modified ethyl(hydroxyethyl)cellulose on polystyrene latex particles in the presence of ionic surfactants using dynamic light scattering. Langmuir 16 (2000) 4478-4484
    • (2000) Langmuir , vol.16 , pp. 4478-4484
    • Lauten, R.A.1    Kjøniksen, A.L.2    Nyström, B.3
  • 35
    • 41349112473 scopus 로고    scopus 로고
    • Interaction of proteins with spherical polyelectrolyte brushes in solution as studied by small-angle X-ray scattering
    • The adsorption of Bovine Serum Albumin (BSA) and Bovine Pancreastic Ribonuclease A (RNase A) on strong and weak polyelectrolytes grafted onto latex particles is measured by SAXS. The scattered intensity is modelled by a geometrical model of beads on the surface of the latex, cf. [9•,57•].
    • Rosenfeldt S., Wittemann A., Ballauff M., Breininger E., Bolze J., and Dingenouts N. Interaction of proteins with spherical polyelectrolyte brushes in solution as studied by small-angle X-ray scattering. Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics 70 (2004) 061403. The adsorption of Bovine Serum Albumin (BSA) and Bovine Pancreastic Ribonuclease A (RNase A) on strong and weak polyelectrolytes grafted onto latex particles is measured by SAXS. The scattered intensity is modelled by a geometrical model of beads on the surface of the latex, cf. [9•,57•].
    • (2004) Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics , vol.70 , pp. 061403
    • Rosenfeldt, S.1    Wittemann, A.2    Ballauff, M.3    Breininger, E.4    Bolze, J.5    Dingenouts, N.6
  • 36
    • 15244342781 scopus 로고    scopus 로고
    • Interactions of hairy latex particles with cationic copolymers
    • Borget P., Lafuma F., and Bonnet-Gonnet C. Interactions of hairy latex particles with cationic copolymers. J Colloid Interface Sci 284 (2005) 560-570
    • (2005) J Colloid Interface Sci , vol.284 , pp. 560-570
    • Borget, P.1    Lafuma, F.2    Bonnet-Gonnet, C.3
  • 37
    • 0037109791 scopus 로고    scopus 로고
    • SANS studies of polyelectrolyte multilayers on colloidal templates
    • The adsorption of a polyelectrolyte multiplayer on index-matched polystyrene latex is studied by SANS using a core-shell model. This allows to deduce the average thickness of a polyelectrolyte layer (16 Å), and the amount of water inside the layers.
    • Estrela-Lopis I., Leporatti S., Moya S., Brandt A., Donath E., and Möhwald H. SANS studies of polyelectrolyte multilayers on colloidal templates. Langmuir 18 (2002) 7861-7866. The adsorption of a polyelectrolyte multiplayer on index-matched polystyrene latex is studied by SANS using a core-shell model. This allows to deduce the average thickness of a polyelectrolyte layer (16 Å), and the amount of water inside the layers.
    • (2002) Langmuir , vol.18 , pp. 7861-7866
    • Estrela-Lopis, I.1    Leporatti, S.2    Moya, S.3    Brandt, A.4    Donath, E.5    Möhwald, H.6
  • 38
    • 33646138009 scopus 로고    scopus 로고
    • Adsorption of novel thermosensitive graft-copolymers: core-shell particles prepared by polyelectrolyte multiplayer self-assembly
    • Rusu M., Kuckling D., Möhwald H., and Schönhoff M. Adsorption of novel thermosensitive graft-copolymers: core-shell particles prepared by polyelectrolyte multiplayer self-assembly. J Colloid Interface Sci 298 (2006) 124-131
    • (2006) J Colloid Interface Sci , vol.298 , pp. 124-131
    • Rusu, M.1    Kuckling, D.2    Möhwald, H.3    Schönhoff, M.4
  • 39
    • 28944446114 scopus 로고    scopus 로고
    • Alternate multi-layered adsorption of macro-cations and -anions on the colloidal spheres. Influence of the deionisation of the complexation mixtures with coexistence of the ion-exchange resins
    • Okubo T., Suda M., and Tsuchida A. Alternate multi-layered adsorption of macro-cations and -anions on the colloidal spheres. Influence of the deionisation of the complexation mixtures with coexistence of the ion-exchange resins. Colloid Polym Sci 284 (2005) 284-292
    • (2005) Colloid Polym Sci , vol.284 , pp. 284-292
    • Okubo, T.1    Suda, M.2    Tsuchida, A.3
  • 40
    • 14844349822 scopus 로고    scopus 로고
    • 'Graft from' polymerization on colloidal silica particles: elaboration of alkoxyamine grafted surface by in situ trapping of carbon radicals
    • Inoubli R., Dagréou S., Khoukh A., Roby F., Peyrelasse J., and Billon L. 'Graft from' polymerization on colloidal silica particles: elaboration of alkoxyamine grafted surface by in situ trapping of carbon radicals. Polymer 46 (2005) 2486-2496
    • (2005) Polymer , vol.46 , pp. 2486-2496
    • Inoubli, R.1    Dagréou, S.2    Khoukh, A.3    Roby, F.4    Peyrelasse, J.5    Billon, L.6
  • 41
    • 33744933704 scopus 로고    scopus 로고
    • Preparation of acrylate polymer/silica nanocomposite particles with high silica encapsulation efficiency via miniemulsion polymerisation
    • Qi D.M., Bao Y.Z., Weng Z.X., and Huang Z.M. Preparation of acrylate polymer/silica nanocomposite particles with high silica encapsulation efficiency via miniemulsion polymerisation. Polymer 47 (2006) 4622-4629
    • (2006) Polymer , vol.47 , pp. 4622-4629
    • Qi, D.M.1    Bao, Y.Z.2    Weng, Z.X.3    Huang, Z.M.4
  • 42
    • 14644423900 scopus 로고    scopus 로고
    • Nitroxide-mediated polymerization of styrene initiated from the surface of silica nanoparticles. In situ generation and grafting of alkoxyamine initiators
    • Poly(styrene) chains are grown from the surface of silica particles ('grafting from'), with a thorough characterization and control of the chemical reaction. This allows the measurement the hydrodynamic thickness of the layer as a function of polymer molar mass.
    • Bartholome C., Beyou E., Bourgeat-Lami E., Chaumont P., Lefebvre F., and Zydowicz N. Nitroxide-mediated polymerization of styrene initiated from the surface of silica nanoparticles. In situ generation and grafting of alkoxyamine initiators. Macromolecules 38 (2005) 1099-1106. Poly(styrene) chains are grown from the surface of silica particles ('grafting from'), with a thorough characterization and control of the chemical reaction. This allows the measurement the hydrodynamic thickness of the layer as a function of polymer molar mass.
    • (2005) Macromolecules , vol.38 , pp. 1099-1106
    • Bartholome, C.1    Beyou, E.2    Bourgeat-Lami, E.3    Chaumont, P.4    Lefebvre, F.5    Zydowicz, N.6
  • 43
    • 33645520366 scopus 로고    scopus 로고
    • Thermosensitive hairy hybrid nanoparticles synthesized by surface-initiated atom transfer radical polymerisation
    • Li D., Jones G.L., Dunlap J.R., Hua F., and Zhao B. Thermosensitive hairy hybrid nanoparticles synthesized by surface-initiated atom transfer radical polymerisation. Langmuir 22 (2006) 3344-3351
    • (2006) Langmuir , vol.22 , pp. 3344-3351
    • Li, D.1    Jones, G.L.2    Dunlap, J.R.3    Hua, F.4    Zhao, B.5
  • 44
    • 28144458499 scopus 로고    scopus 로고
    • Fabrication of hybrid nanoparticles with thermoresponsive coronas via a self-assembling approach
    • Zhang Y., Luo S., and Liu S. Fabrication of hybrid nanoparticles with thermoresponsive coronas via a self-assembling approach. Macromolecules 38 (2005) 9813-9820
    • (2005) Macromolecules , vol.38 , pp. 9813-9820
    • Zhang, Y.1    Luo, S.2    Liu, S.3
  • 45
    • 33746344659 scopus 로고    scopus 로고
    • Double-responsive polymer brushes on the surface of colloid particles
    • Zhang M., Liu L., Zhao H., Yang Y., Fu G., and He B. Double-responsive polymer brushes on the surface of colloid particles. J Colloid Interface Sci 301 (2006) 85-91
    • (2006) J Colloid Interface Sci , vol.301 , pp. 85-91
    • Zhang, M.1    Liu, L.2    Zhao, H.3    Yang, Y.4    Fu, G.5    He, B.6
  • 46
    • 29144501426 scopus 로고    scopus 로고
    • Double hydrophilic block copolymer monolayer protected hybrid gold nanoparticles and their shell cross-linking
    • Luo S., Xu J., Zhang Y., Liu S., and Wu C. Double hydrophilic block copolymer monolayer protected hybrid gold nanoparticles and their shell cross-linking. J Phys Chem B 109 (2005) 22159-22166
    • (2005) J Phys Chem B , vol.109 , pp. 22159-22166
    • Luo, S.1    Xu, J.2    Zhang, Y.3    Liu, S.4    Wu, C.5
  • 47
    • 26844516048 scopus 로고    scopus 로고
    • Microstructure and rheological properties of pH-responsive core-shell particles
    • Tan B.H., Tam K.C., Lam Y.C., and Tan C.B. Microstructure and rheological properties of pH-responsive core-shell particles. Polymer 46 (2005) 10066-10076
    • (2005) Polymer , vol.46 , pp. 10066-10076
    • Tan, B.H.1    Tam, K.C.2    Lam, Y.C.3    Tan, C.B.4
  • 48
    • 33751005818 scopus 로고    scopus 로고
    • Detailed structural observation of nanografting chemistry with neutron scattering
    • Carrot G., El Harrak A., Oberdisse J., Jestin J., and Boué F. Detailed structural observation of nanografting chemistry with neutron scattering. Soft Matter 2 (2006) 1043-1047
    • (2006) Soft Matter , vol.2 , pp. 1043-1047
    • Carrot, G.1    El Harrak, A.2    Oberdisse, J.3    Jestin, J.4    Boué, F.5
  • 49
    • 4444294348 scopus 로고    scopus 로고
    • Surface-atom transfer radical polymerization from silica nanoparticles with controlled colloidal stability
    • El Harrak A., Carrot G., Oberdisse J., Eychenne-Baron Ch., and Boué F. Surface-atom transfer radical polymerization from silica nanoparticles with controlled colloidal stability. Macromolecules 37 (2004) 6376-6384
    • (2004) Macromolecules , vol.37 , pp. 6376-6384
    • El Harrak, A.1    Carrot, G.2    Oberdisse, J.3    Eychenne-Baron, Ch.4    Boué, F.5
  • 50
    • 12444261327 scopus 로고    scopus 로고
    • Atom transfer radical polymerization from silica nanoparticles using the "grafting from" method and structural study via small-angle neutron scattering
    • El Harrak A., Carrot G., Oberdisse J., Jestin J., and Boué F. Atom transfer radical polymerization from silica nanoparticles using the "grafting from" method and structural study via small-angle neutron scattering. Polymer 46 (2005) 1095-1104
    • (2005) Polymer , vol.46 , pp. 1095-1104
    • El Harrak, A.1    Carrot, G.2    Oberdisse, J.3    Jestin, J.4    Boué, F.5
  • 51
    • 0037469324 scopus 로고    scopus 로고
    • A small-angle neutron and X-ray contrast variation scattering study of the structure of block copolymer micelles: corona shape and excluded volume interactions
    • SANS and SAXS data of poly(styrene)-poly(isoprene) block copolymers in decane are reported in this article. The PS-core is covered by a PI layer, which is made visible by using deuterated material. Detailed modelling based either on non-interacting gaussian chains or on scattering functions based on Monte-Carlo simulations for self-avoiding chains is used to extract micellar parameters. Further work on this subject by the same group is cited in the references.
    • Pedersen J.S., Carsten Svaneborg C., Almdal K., Hamley I.W., and Young R.N. A small-angle neutron and X-ray contrast variation scattering study of the structure of block copolymer micelles: corona shape and excluded volume interactions. Macromolecules 36 (2003) 416-433. SANS and SAXS data of poly(styrene)-poly(isoprene) block copolymers in decane are reported in this article. The PS-core is covered by a PI layer, which is made visible by using deuterated material. Detailed modelling based either on non-interacting gaussian chains or on scattering functions based on Monte-Carlo simulations for self-avoiding chains is used to extract micellar parameters. Further work on this subject by the same group is cited in the references.
    • (2003) Macromolecules , vol.36 , pp. 416-433
    • Pedersen, J.S.1    Carsten Svaneborg, C.2    Almdal, K.3    Hamley, I.W.4    Young, R.N.5
  • 53
    • 0038399996 scopus 로고    scopus 로고
    • Compositions of mixed surfactant layers in microemulsions determined by small-angle neutron scattering
    • Bumajdad A., Eastoe J., Nave S., Steytler D.C., Heenan R.K., and Grillo I. Compositions of mixed surfactant layers in microemulsions determined by small-angle neutron scattering. Langmuir 19 (2003) 2560-2567
    • (2003) Langmuir , vol.19 , pp. 2560-2567
    • Bumajdad, A.1    Eastoe, J.2    Nave, S.3    Steytler, D.C.4    Heenan, R.K.5    Grillo, I.6
  • 54
    • 0002672272 scopus 로고    scopus 로고
    • SANS structural determination of a nonionic surfactant layer adsorbed on clay particles
    • Grillo I., Levitz P., and Zemb T. SANS structural determination of a nonionic surfactant layer adsorbed on clay particles. Eur Phys J B Cond Matter Phys 10 (1999) 29-34
    • (1999) Eur Phys J B Cond Matter Phys , vol.10 , pp. 29-34
    • Grillo, I.1    Levitz, P.2    Zemb, T.3
  • 55
    • 2042437072 scopus 로고    scopus 로고
    • Small angle neutron scattering and model predictions for micelle-decorated silica beads
    • Oberdisse J. Small angle neutron scattering and model predictions for micelle-decorated silica beads. Phys Chem Chem Phys 6 7 (2004) 1557-1561
    • (2004) Phys Chem Chem Phys , vol.6 , Issue.7 , pp. 1557-1561
    • Oberdisse, J.1
  • 56
    • 0000307151 scopus 로고
    • Temperature-dependence of the adsorption of hexaethylene glycol monododecyl ether on silica sols
    • Cummins P.G., Staples E., and Penfold J. Temperature-dependence of the adsorption of hexaethylene glycol monododecyl ether on silica sols. J Phys Chem 95 (1991) 5902-5905
    • (1991) J Phys Chem , vol.95 , pp. 5902-5905
    • Cummins, P.G.1    Staples, E.2    Penfold, J.3
  • 57
    • 16244416879 scopus 로고    scopus 로고
    • Adsorption of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers at the silica-water interface
    • The behaviour of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers at the silica-water interface inside porous silica is studied. A simple layered structure in the silica pores is ruled out, as none of the profiles explains a scattering peak at intermediate q, which can be described by a quite involved scattering model for adsorbed micelles. The model reproduces the peak by inter-micellar interactions within the layer, and is consistent with the adsorption isotherm (cooperative adsorption and plateau value).
    • Vangeyte P., Leyh B., Rojas O.J., Claesson P.M., Heinrich M., Auvray L., et al. Adsorption of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers at the silica-water interface. Langmuir 21 (2005) 2930-2940. The behaviour of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers at the silica-water interface inside porous silica is studied. A simple layered structure in the silica pores is ruled out, as none of the profiles explains a scattering peak at intermediate q, which can be described by a quite involved scattering model for adsorbed micelles. The model reproduces the peak by inter-micellar interactions within the layer, and is consistent with the adsorption isotherm (cooperative adsorption and plateau value).
    • (2005) Langmuir , vol.21 , pp. 2930-2940
    • Vangeyte, P.1    Leyh, B.2    Rojas, O.J.3    Claesson, P.M.4    Heinrich, M.5    Auvray, L.6
  • 58
    • 33748299357 scopus 로고    scopus 로고
    • Concomitant adsorption of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers and sodium dodecyl sulfate at the silica-water interface
    • Vangeyte P., Leyh B., De Clercq C., Auvray L., Misselyn-Bauduin A.M., and Jérôme R. Concomitant adsorption of poly(ethylene oxide)-b-poly(ε-caprolactone) copolymers and sodium dodecyl sulfate at the silica-water interface. Langmuir 21 (2005) 7710-7716
    • (2005) Langmuir , vol.21 , pp. 7710-7716
    • Vangeyte, P.1    Leyh, B.2    De Clercq, C.3    Auvray, L.4    Misselyn-Bauduin, A.M.5    Jérôme, R.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.