Separation of Co(II) and Li(I) by supported liquid membrane using Cyanex 272 as mobile carrier

Journal of Membrane Science

Volumn 297, Issue 1-2, 2007, Pages 253-261

  Swain, Basudev ^a,b   Jeong, Jinki ^a   Lee, Jae chun ^a   Lee, Gae Ho ^b  

^a Korea Institute of Geosceince and Mineral Resources   (South Korea)

^b Chungnam National University   (South Korea)

Author keywords

Co(II); Cyanex 272; Li(I); Liquid membrane; Permeation

Indexed keywords

LIQUID-LIQUID EXTRACTION; SEPARATION FACTORS; SULFATE MEDIA;

CONCENTRATION (PROCESS); EXTRACTION; HYDROPHOBICITY; LIQUID MEMBRANES; LITHIUM; PH EFFECTS;

COBALT;

BIS (2,4,4 TRIMETHYLPENTYL)PHOSPHINIC ACID; COBALT; LITHIUM; PHOSPHINIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

COBALT; CONCENTRATION (PROCESS); EXTRACTION; HYDROPHOBICITY; LIQUID MEMBRANES; LITHIUM; PH EFFECTS;

ARTICLE; CHEMICAL STRUCTURE; EQUILIBRIUM CONSTANT; INTERMETHOD COMPARISON; LIQUID LIQUID EXTRACTION; LIQUID MEMBRANE; MEMBRANE PERMEABILITY; PH; PRIORITY JOURNAL; ROTATION; SEPARATION TECHNIQUE; SOLVENT EXTRACTION;

EID: 34248576670     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2007.03.051     Document Type: Article

References (30)

1. Swain B., Jeong J., Lee J.C., and Lee G.H. Separation of cobalt and lithium from mixed sulfate solution using Na-Cyanex 272. Hydrometallurgy 84 3-4 (2006) 130
2. Sohn J.S., Yang D.H., Shin S.M., Kim N.H., and Sohn. Recovery of cobalt in sulfuric acid leaching solution using oxalic acid. In: Rhee K.I., and Oh J.K. (Eds). Proceedings of the International Symposium on Green Technology for Resources and Material Recycling. November 24-27, Seoul, Korea (2004) 316
3. P.V.D. Bossche, The current legislative development in the EUwaste policy: Challenge or opportunities for metal industry, published by cobalt development institute, January 2006, 06/1, 1, http://www.thecdi.com/cdi/images/news_pdf/Cobalt_News_January_2006.pdf.
4. Winston Ho W.S., and Sirkar K.K. New Membrane Process Under Development, Membrane Handbook (1992), Van Nostrand Reinhold, New York pp. 727-760
5. Yang X.J., Fane A.G., and Soldenhoff K. Comparison of liquid membrane processes for metal separations: permeability, stability, and selectivity. Ind. Eng. Chem. Res. 42 2 (2003) 392
6. Swain B., Sarangi K., and Das R.P. Effect of different anions on separation of copper and zinc by supported liquid membrane using TOPS-99 as mobile carrier. J. Membr. Sci. 243 1-2 (2004) 189
7. Swain B., Sarangi K., and Das R.P. Effect of different anions on separation of cadmium and zinc by supported liquid membrane using TOPS-99 as mobile carrier. J. Membr. Sci. 277 1-2 (2006) 240
8. Swain B., Sarangi K., and Das R.P. Separation of cadmium and zinc by supported liquid membrane using TOPS-99 as mobile carrier. Sep. Sci. Technol. 39 9 (2004) 2171
9. Yang Q., Chung T.S., Xiao Y., and Wang K. The development of chemically modified P84 Co-polyimide membranes as supported liquid membrane matrix for Cu(II) removal with prolonged stability. Chem. Eng. Sci. 62 6 (2007) 1721
10. Lee J.C., Jeong J., Chung K.S., and Kobayashi M. Active facilitated transport and separation of Co in Co-Ni sulfate solution by hollow fiber supported liquid membrane containing HEH(EHP). Sep. Sci. Technol. 39 7 (2004) 1519
11. Jeong J., Lee J.C., and Kim W.B. Modeling on the counteractive facilitated transport of Co in Co-Ni mixtures by hollow-fiber supported liquid membrane. Sep. Sci. Technol. 38 3 (2003) 499-517
12. Youn I.J., Lee Y.T., Jeong J., and Lee W.H. Analysis of Co-Ni separation by a supported liquid membrane containing HEH(EHP). J. Membr. Sci. 125 2 (1997) 231
13. Juang R.S. Modelling of the competitive permeation of cobalt and nickel in a di(2-ethylhexyl)phosphoric acid supported liquid membrane process. J. Membr. Sci. 85 2 (1993) 157
14. Alguacil F.J., and Alonso M. Separation of zinc(II) from cobalt(II) solutions using supported liquid membrane with DP-8R (di(2-ethylhexyl) phosphoric acid) as a carrier. Sep. Purif. Technol. 41 2 (2005) 179
15. Alguacil F.J. Facilitated transport and separation of manganese and cobalt by a supported liquid membrane using DP-8R as a mobile carrier. Hydrometallurgy 65 1 (2002) 9
16. Lee J.C., Jeong J., Kim B.S., Kim M.S., and Kobayashi M. Separation of copper and zinc ions by hollow fiber supported liquid membrane containing LiX84 and PC-88A. Mater. Trans. 45 6 (2004) 1915
17. ®921. J. Membr. Sci. 252 1-2 (2005) 237
18. Bansal B., Chen X.D., and Hossain M.M. Transport of lithium through a supported liquid membrane of LIX54 and TOPO in kerosene. Chem. Eng. Process. 44 (2005) 1327
19. Suzuki E., Sakoguchi A., and Nakashio F. Extraction kinetic of lithium with a mixture of a β-Diketone and a neutral organophosphorous compound and the molecular dynamics of the lithium complex formation at the heptane-water interface. Solvent Extract. Res. Dev., Japan 10 (2003) 171
20. Zhang P., Yokoyama T., Itabashi O., Suzuki T.M., and Inoue K. Hydrometallurgical process for recovery of metal values from spent lithium-ion secondary batteries. Hydrometallurgy 47 (1998) 259
21. Nan J., Han D., and Zuo X. Recovery of metal values from spent lithium-ion batteries with chemical deposition and solvent extraction. J. Power Sources 152 (2005) 278
22. B. Swain, J. Jeong, J.C. Lee, G.H. Lee, Separation of cobalt and lithium from mixed sulfate solution using organophosphorous extractant Na-cyanex 272, The 17th International Solvent Extraction Conference, ISEC 2005, September 19-23, Beijing, People's Republic of China, CD publication ISBN 7-900692-02-9, 2005, p. 605.
23. Swain B., Jeong J., Lee J.C., and Lee G.H. Recovery of valuable metals from waste of cathode active materials of lithium ion battery industry. Proceeding of The Korean Society for Geosystem Engineering. April 15-16, Korea institute of Geosciences and Engineering, Daejoen, Korea (2005) 259
24. Swain B., Jeong J., Kim M.S., Lee J.C., and Sohn J.S. Recovery of cobalt from waste cathode active material generated in manufacturing lithium ion batteries by hydrometallurgical process. J. Korean Instit. Resour. Recycling 14 6 (2005) 28-36
25. Yoo K.K., Swain B., Jeong J., Lee J.C., and Kim M.S. Recovering cobalt from waste cathode active materials in lithium ion batteries. In: Önal G., Acarkan N., Çelik M.S., Arslan F., Ateşok G., Güney A., Sirkeci A.A., Yüce A.E., and Perek K.T. (Eds). Conference Proceeding of The XXIII, International Mineral Processing Congress, vol. 2. Istanbul, Turkey, 3-8 September (2006) 1452-1457
26. W. Gerhartz, B. Elvers, M. Ravenscroft, J.F. Rounsaville, Gail Schulz, Ullmann's Encyclopedia of Industrial Chemistry, Volume B3, fifth ed., 6-44-6-50.
27. Swain B., Jeong J., Lee J.-C., and Lee G.-H. Extraction of Co(II) by supported liquid membrane and solvent extraction using Cyanex 272 as an extractant: a comparison study. J. Membr. Sci. 288 1/2 (2007) 139
28. Bohrer M.P. Diffusional boundary layer resistance for membrane transport. Ind. Eng. Chem. Fundam. 22 (1983) 72
29. Kaufmann T.G., and Leonard E.F. Mechanism of interfacial mass transfer in membrane transport. AIChE J. 14 (1968) 421
30. Crank J. The Mathematics of Diffusion. second ed. (1980), Oxford University Press, USA March 13, pp. 94-95