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Ph.D. thesis, University of Warwick, Coventry, UK
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D. Manara, C. Ronchi, M. Sheindlin, M. Lewis, and M. Brykin, J. Nucl. Mater. 342, 148 (2005); 0022-3115 D. Manara, " Melting Transition Measurements in Uranium Dioxide., " Ph.D. thesis, University of Warwick, Coventry, UK (2004).
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Melting Transition Measurements in Uranium Dioxide
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Manara, D.1
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34248517248
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The congruent-melting temperature of UO2, where solidus and liquidus lines intercept, is about 3120 K, corresponding to the congruent vaporization composition of UO1.98. The boiling temperature at this composition is 3815 K.
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The congruent-melting temperature of UO2, where solidus and liquidus lines intercept, is about 3120 K, corresponding to the congruent vaporization composition of UO1.98. The boiling temperature at this composition is 3815 K.
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6
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85042246906
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ASME, New York
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Tasman, H.A.1
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Observations and theoretical views on the high temperature behavior of UO2 agree in predicting, on the one hand, an approach of solid UO2 to the liquid state through a premelting transition at 2670 K due to oxygen sublattice disorder [A. S. Dworkin and A. Bredig, J. Phys. Chem. 0022-3654 10.1021/j100850a035 72, 1277 (1968); and M. T. Hutchings, J. Chem. Soc., Faraday Trans. 2 83, 1083 (1987)] and, on the other hand, a highly structured ionic liquid, where the intermolecular forces preserve some important ionic bonding aspects of the solid [C. Ronchi, I. L. Iosilevski, and E. Yakub, Equation of State of Uranium Dioxide (Springer, Berlin, 2005)].
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Observations and theoretical views on the high temperature behavior of UO2 agree in predicting, on the one hand, an approach of solid UO2 to the liquid state through a premelting transition at 2670 K due to oxygen sublattice disorder [A. S. Dworkin and A. Bredig, J. Phys. Chem. 0022-3654 10.1021/j100850a035 72, 1277 (1968); and M. T. Hutchings, J. Chem. Soc., Faraday Trans. 2 83, 1083 (1987)] and, on the other hand, a highly structured ionic liquid, where the intermolecular forces preserve some important ionic bonding aspects of the solid [C. Ronchi, I. L. Iosilevski, and E. Yakub, Equation of State of Uranium Dioxide (Springer, Berlin, 2005)].
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Observations and theoretical views on the high temperature behavior of UO2 agree in predicting, on the one hand, an approach of solid UO2 to the liquid state through a premelting transition at 2670 K due to oxygen sublattice disorder [A. S. Dworkin and A. Bredig, J. Phys. Chem. 0022-3654 10.1021/j100850a035 72, 1277 (1968); and M. T. Hutchings, J. Chem. Soc., Faraday Trans. 2 83, 1083 (1987)] and, on the other hand, a highly structured ionic liquid, where the intermolecular forces preserve some important ionic bonding aspects of the solid [C. Ronchi, I. L. Iosilevski, and E. Yakub, Equation of State of Uranium Dioxide (Springer, Berlin, 2005)].
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The only case of increase of α in the liquid is given by the 5a metalloids Bi and Sb, whereby the effect is here due to the electric conductivity increase in the liquid with respect to the solid state [R. P. Yurchak and L. P. Filippov, Teplofiz. Vys. Temp. 2, 696 (1964)].
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