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Selective Si/B exchange has been demonstrated previously for the borylation of silylated polystyrene with BBr3, a Qin, Y, Cheng, G, Sundararaman, A, Jäkle, F. J. Am. Chem. Soc. 2002, 124, 12672-12673
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34248516463
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3 leads to borylation at the 5,5′-positions.
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3 leads to borylation at the 5,5′-positions.
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29
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34248514555
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The head-to-head connection of the dihexylbithiophene moieties in the polymers limits extensive delocalization; thus, the quaterthiophene model systems quite accurately reflect the electronic structures of the polymers
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The head-to-head connection of the dihexylbithiophene moieties in the polymers limits extensive delocalization; thus, the quaterthiophene model systems quite accurately reflect the electronic structures of the polymers.
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30
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34248516462
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Despite the charge-transfer character involving states with strong contributions from the boron p-orbitals, PT-BMes2 shows almost no solvatochromism
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2 shows almost no solvatochromism.
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31
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34248528702
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The absorption and emission spectra are essentially independent of the temperature (+50 to -30°C).
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The absorption and emission spectra are essentially independent of the temperature (+50 to -30°C).
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32
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34248558672
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3 from DFT calculations.
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3 from DFT calculations.
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33
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0035856672
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See ref 6 and for example: a
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